Preparation, Photo and Electroluminescence Properties of Novel Rare Earth Aromatic Carboxylates

稀土学报(英文版), 2002, 20(4): 264-267.

林秦 ^1, , 符连社 ^2, , 梁玉军 ^3, , 郑佑轩 ^4, , 林君 ^5, , 张洪杰 ^6,

1.Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

2.Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

3.Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

4.Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

5.Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

6.Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

基金项目: 国家重点基础研究发展计划(973计划)(29731010,29971030) 国家杰出青年科学基金(29225102)

Preparation, Photo and Electroluminescence Properties of Novel Rare Earth Aromatic Carboxylates

Keywords： rare earths

Novel soluble rare earth aromatic carboxylates were prepared. The triplet energy level of organic ligand was measured. The photoluminescence properties of the Tb3+ and Eu3+ aromatic carboxylates and lifetimes were investigated, which indicated that these rare earth complexes have high quantum efficiency. Because of their excellent solubility, polymer-doping rare earth carboxylates were fabricated as thin films by spin-coating method and their luminescence properties were studied. Some rare earth organic light-emitting diodes were successfully fabricated which performed high pure color. The maximum luminance of the device of ITO/PVK/PVK∶Tb(AS)3Phen∶PBD/PBD/Al is 32 cd*m-2 at 28 V.

参考文献

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Preparation, Photo and Electroluminescence Properties of Novel Rare Earth Aromatic Carboxylates

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