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采用电化学测试技术研究了人体医用金属材料工 业纯钛和Ti6Al4V合金在人工模拟体液中 的腐蚀行为。 结果表明, 阳极极化后两种合金均未发现点蚀, 工业纯钛的维钝电流密度 小于 Ti6Al4V合金, 前者的阳极极化性能优于后者。 Ti6Al4V合金缝隙试样在阳极电位超过+2  000  m V(vs SCE)后, 电流开始急剧增大, 发生了缝隙腐蚀; 通过电子探针分析发现, 在缝隙内 Al和V 两种元素发生活性溶解。 工业纯钛在电位达到+4  000  mV(vs SCE)时仍没有 发生缝隙腐蚀。

The corrosion behavior of surgery medical mate rials commercially pure Ti (ab ridged as CPTi ) and Ti6Al4V alloy in Ringer's artificial body fluid was st udied with electrochemical methods. The results show that no pittin g corrosion is found on these two alloys. The passivation current density o f CP Ti is lower than that of Ti6Al4V, which indicates that the former's anodic po la rization capacity is better than the latter's. With the polarization potential o ver than 2  000  mV(vs SCE), the crevice corrosion happens on Ti6A l4V allo y sample. However that is not found on CPTi sample when the potential is 4  000  mV(vs SCE) . The EPMA analy sis of Ti6Al4V alloy crevice corrosive sample shows that Al and V a ctively dissolve, then migrate and electrically deposit.

参考文献

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