将环氧改性有机硅(EA)与Al粉按质量比(3:2)形成EA/40%A1低红外发射率复合涂层,研究了固化温度对EA/40%Al复合涂层耐腐蚀性能的影响及其机理.利用扫描电镜观察涂层的形貌,并通过动电位极化技术及耐腐蚀实验对涂层的耐腐蚀性能进行了表征.结果表明,在保证低发射率前提下,固化温度为200℃时,涂层的耐盐雾、耐人工加速老化和耐湿热腐蚀性能时间均能达到2000 h,基本满足工程应用要求.固化温度为200℃时,涂层的固化度最合适,涂层交联最佳,使得树脂基体与颜填料结合紧密,涂层致密,耐腐蚀性能最佳.
参考文献
[1] | YOU Yucong,DU Shiguo,SHI Dongmei,Application and research of the infrared camouflage coatings,Modern Paint and Finishing,16(7),50(2006)(游毓聪,杜仕国,施冬梅,红外隐身涂料黏合剂的应用与研究,特种涂料与涂装特刊,16(7),50(2006)) |
[2] | Zueco J,Alhama F,Inverse estimation of temperature dependent emissivity of solid metals,Journal of Quantitative Spectroscopy and Radiative Transfer,101(1),73(2006) |
[3] | ZHANG Weidong,FENG Xiaoyun,MENG Xiulan,Status and development of foreign study on new stealthy materials,Aerospace Materials & Technology,30(3),1(2000)(张卫东,冯小云,孟秀兰,国外隐身材料研究进展,宇航材料工艺,30(3),1(2000)) |
[4] | ARONSON J R,Modeling the infrared reflectance and emittance of paints and coating,AD-A110824,(1982) |
[5] | XU Wenlan,LUO Ningsheng,ZHANG Min,Thermal radiation of inhomogeneous coating,Journal of Infrared and Millimeter Waves,9(5),384(1982)(徐文兰,罗宁胜,张珉,非均匀涂层的热辐射,红外与毫米波学报,9(5),384(1982)) |
[6] | XIE Guohua,ZHANG Zuoguang,WU Ruibin,Matching performance among visible and near infrared coating,low infrared emitting coating and microwave absorbing coating,Journal of Wu Han University of Technology,Materials Science,20(4),55(2005) |
[7] | WANG Bo,SUN Xiaoquan,WANG Zirong,Study on stealth effect evaluation of infrared coating,Chinese Journal of Quantum Electronics,21(4),538(2004)(王博,孙晓泉,王自荣,涂层光电隐身效果评估方法研究,量了电子学报,21(4),538(2004)) |
[8] | WANG Tingwei,CHENG Congliang,ZHANG Qitu,Study on low infrared emissivity of coating in 8~14 μm,Optical Technique,31(4),598(2005)(王庭慰,程从亮,张其土,8-14 μm波长低红外发射率涂料的研究,光学技术,31(4),598(2005)) |
[9] | J Jones,HONG Qi,WEI Haibin,Stealth Technology-The Art of Black Magic,(Beijing,Aviation Industry Press,1991) p.52(琼斯 J,洪旗,魏海滨,译,隐身技术(北京,航空工业出版社,1991)P.52) |
[10] | YU Huijuan,XU Guoyue,SHAO Chunming,Study on low infrared emissivity coatings with EPDM adhesive at spectral range of 8~14 祄,Infrared Technology,30(3),154(2008)(余慧娟,徐国跃,邵春明.EPDM基涂层在8~14μm波段红外低发射率的研究,红外技术,30(3),154(2008)) |
[11] | CUI Zhiming,YANG Yajiang,Effect of solidification degree of epoxy resin on properties of powder coating,China Plastics Industry,29(3),37(2001)(崔志明,杨亚江,环氧树脂固化度对粉末涂层性能的影响,塑料工业,29(3),37(2001)) |
[12] | ZHANG Baohua,YE Jundan,CHEN Bin,Influence of curing temperature on performance of epoxy thermosets,China Plastics Industry,37(9),64(2009)(张宝华,叶俊丹,陈斌,固化温度对环氧树脂同化物性能的影响,塑料工业,37(9),64(2009)) |
[13] | HONG Xuhui,LI Yafeng,Study on the thermal properties of cyanate ester modified epoxy resin,Thermosetting Resin,24(5),14 (2009)(洪旭辉,李亚锋,氰酸酯改性环氧树脂耐热性研究,热固性树脂,24(5),14(2009)) |
[14] | SHAO Chunming,XU Guoyue,YU Huijuan,Modified EPDM used as infrared stealthy coating,Aerospace Materials & Technology,(3),62(2008)(邵春明,徐国跃,余慧娟,改性三元乙丙橡胶用于红外隐身涂层的研究,宇航材料工艺,(3),62(2008)) |
[15] | YU Huijuan,XU Guoyue,SHEN Xuan,Study on preparation and optimization of low infrared emission coating in 8~14μm,Ordnance Material Science and Engineering,31(6),49(2008)(余慧娟,徐国跃,沈轩,8~14μm波段低发射率涂料的制备与优化研究,兵器材料科学与工程,31(6),49(2008)) |
[16] | K.H.Wu,C.M.Chao,T.F.Yeh,Thermal stability and corrosion resistance of polysiloxane coatings on 2024-3 and 6061-T6 aluminum alloy,Surface & Coatings Technology,201(12),5782(2007) |
[17] | Pu-Sheng Chuang,Hung-Yi Tsi,Jing-Dong Chow,Wen-Chin Tsen,Yao-Chi Shu,Shin-Cheng Jang,Thermal degradation of poly(siloxane-urethane) copolymers,Polymer Degradation and Stability,10(93),1753(2008) |
[18] | Jwlwna D J,Milutin N G,The thermogravimetric analysis of some polysiloxanes,Polymer Degradation and Stability,61,87(1998) |
[19] | YANG Lixia,ZHANG Sanping,LiN An,A study on water vapor permeating rate of organic coating and corrosion of coating-metal interace,Materials Protection,34(10),28(2001)(杨丽霞,张三平,林安,有机涂层渗水率及金属界面腐蚀的研究进展,材料保护,34(10),28(2001)) |
[20] | YU Huijuan,XU Guoyue,SHEN Xingmei,YAN Xiaoxing HUANG Rong,LI Fenglei,Preparation of leafing Cu anc its application in low infrared emissivity coatings,Journal of Alloys and Compounds,484(1),395(2009) |
[21] | LUO Suzhen,ZHENG Yugui,LI Jin,Characteristics oi electrochemical impedance spectroscopy of medium permeation in fusion bonded epoxy powder coatings,Corrsion Science and Technology Protection,13(4),199(2001)(骆素珍,郑玉贵,李劲,环氧粉末涂层中介质传输的交流阻抗谱特征,腐蚀科学与防护技术,13(4),199(2001)) |
[22] | YANG Guang,HUANG Pengcheng,UV treatment of blended epoxy resin and its surface chemical reaction,Journal of Beijing University of Aeronautics and Astronautics,34(6),618(2008)(杨光,黄鹏程,环氧共混树脂的光固化及其表面化学反应,北京航空航天大学学报,34(6),618(2008)) |
[23] | XU Yongxiang,YAN Chuanwei,DING Jie,UV photo-degradation of coatings,Journal of Chinese Society For Corrosion and Protection,24(3),168(2004)(徐永祥,严川伟,丁杰,紫外光对涂层的老化作用,中国腐蚀与防护学报,24(3),168(2004)) |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%