欢迎登录材料期刊网

材料期刊网

高级检索

采用多羟基一步法,以一缩二乙二醇(DEG)为反应溶剂,合成了水相高分散且具有高光催化活性的纳米ZnO颗粒.与以水、乙醇为溶剂制备的ZnO相比,该ZnO颗粒在pH≥6.5的蒸馏水中能分散稳定且保持3天,良好的分散稳定性归因于其表面修饰的CH2-OH与-COOH电离产生的静电斥力.纳米ZnO的光催化性能通过模拟太阳光下降解甲基橙(MO)溶液来评价,结果表明:以DEG为溶剂制备的ZnO光催化活性最高,且空穴及羟基自由基是光催化降解MO的活性物种.

参考文献

[1] A. S. Shaporev;V. K. Ivanov;A. E. Baranchikov .Hydrothermal Synthesis and Photocatalytic Activity of Highly Dispersed ZnO Powders[J].Russian Journal of Inorganic Chemistry,2006(10):1523-1527.
[2] S.J. Chung;J.P. Leonard;I. Nettleship .Characterization of ZnO nanoparticle suspension in water: Effectiveness of ultrasonic dispersion[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2009(1/2):75-80.
[3] Guo Gao;Wentao Shi;Lan Xiang .Controllable Synthesis of Highly Dispersed ZnO Nanoparticles and Nanorods[J].Journal of the Electrochemical Society,2009(9):155-159.
[4] 张园,张志刚,袁媛,刘昌胜.纳米氧化镁水悬浮液稳定性的研究[J].硅酸盐通报,2006(03):33-37,57.
[5] 高宇,李莉,张秀丽,王丽丽,张文治,黄贤丹.微波辐射对纳米ZnO材料物理性质与光催化活性的影响[J].高等学校化学学报,2013(11):2629-2634.
[6] Shi, K.;Zhang, P.F.;Wei, H.Y.;Jiao, C.M.;Li, C.M.;Liu, X.L.;Yang, S.Y.;Zhu, Q.S.;Wang, Z.G. .Energy band alignment of MgO (111)/ZnO (0002) heterojunction determined by X-ray photoelectron spectroscopy[J].Solid State Communications,2012(11):938-940.
[7] R.Y.Hong;J.H.Li;LL.Chen .Synthesis,surface modification and photocatalytic property of ZnO nanoparticles[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2009(3):426-432.
[8] Rajesh Kumar;Rajesh Kumar Singh;Jai Singh.Synthesis, characterization and optical properties of graphene sheets-ZnO multipod nanocomposites[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2012:129-134.
[9] Hengzhi Chen;Zhengkui Guo;Lingling Jia.Preparation and surface modification of highly dispersed nano-ZnO with stearic acid activated by N.N'-carbonyldiimidazole[J].Materials Letters,2012:167-170.
[10] Ruoyu Hong;Tingting Pan;Jianzhong Qian;Hongzhong Li .Synthesis and surface modification of ZnO nanoparticles[J].Chemical engineering journal,2006(2/3):71-81.
[11] Rui Song;Ying Liu;Linghao He .Synthesis and characterization of mercaptoacetic acid-modified ZnO nanoparticles[J].Solid state sciences,2008(11):1563-1567.
[12] K. S. Suganthi;K. S. Rajan .Temperature induced changes in ZnO-water nanofluid: Zeta potential, size distribution and viscosity profiles[J].International Journal of Heat and Mass Transfer,2012(25/26):7969-7980.
[13] 孙宜华,熊惟皓,李晨辉.ZnO-Al2O3混合粉体水基悬浮液性能的研究[J].无机材料学报,2009(02):413-416.
[14] Buong Woei Chieng;Yuet Ying Loo.Synthesis of ZnO nanoparticles by modified polyol method[J].Materials Letters,2012:78-82.
[15] 林华香,邓韦华,龙金林,王绪绪.原位FTIR技术考察金红石TiO2的表面羟基及其对甲苯的光催化氧化作用[J].光谱学与光谱分析,2014(05):1229-1233.
[16] J.M. Monteagudo;A. Duran;I. San Martin.Ultrasound-assisted homogeneous photocatalytic degradation of Reactive Blue 4 in aqueous solution[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2014:59-67.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%