Ln(η6-C6H6)(AlCl4)3对苯烷基化反应的催化作用

中国稀土学报, 2000, 18(4): 379-381.

1.苏州大学化学化工学院,江苏,苏州,215006

2.苏州大学化学化工学院,江苏,苏州,215006

3.苏州大学化学化工学院,江苏,苏州,215006

基金项目: 国家自然科学基金中国科学院资助项目(29872031)

Catalytic Action of Ln(η6-C6H6)(AlCl4)3 in Alkylation of Benzene

研究了中性芳烃稀土配合物Ln(η6-C6H6)(AlCl4)3 (Ln＝La, Nd) 对苯烷基化反应的催化作用. Ln(η6-C6H6)(AlCl4)3可在温和条件下催化苯与己烯反应给出正己基苯和仲己基苯. 探讨了不同催化剂及反应条件对此反应的影响.

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