分别采用过渡元素掺杂和不同聚合物(聚丙烯晴和聚噻吩)包覆的方法对锂离子电池用正极材料LiMn2O4进行改性,研究了改性前后LiMn2O4的电化学性能.结果表明采用掺杂改性和聚合物包覆改性都可以提高LiMn2O4的电化学性能,减缓容量衰减.但单纯用一种方法改性效果都不理想,而将两种方法结合起来使用则不仅能有效地阻止电池在室温下的容量衰减(在前60个循环中,改性前电池的放电容量从119.1mAh/g下降到99.6mAh/g,平均每个循环的容量衰减率为0.27%,经Cr元素掺杂再用聚丙烯腈包覆后电池的放电容量从94.6mAh/g下降到91.8mAh/g,平均每个循环的容量衰减率为0.05%),而且使电池在高温下(60oC)也有很好的循环性能.
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