材料保护, 2012, 45(3): 56-58.
海底海泥区域管线钢腐蚀行为的研究现状及展望
李延伟 1, , 李言涛 2, , 王路遥 3, , 李晓 {"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以高乙酸乙烯酯(VA)含量的乙烯-乙酸乙烯酯橡胶(EVM)为主基体、1,4-双叔丁基过氧异丙基苯(BIPB)为交联剂、偶氮二甲酰胺(AC)为发泡剂,通过模压法制备了EVM及其与蒙脱土的纳米复合发泡材料;系统研究了蒙脱土的种类和含量对EVM复合发泡材料硫化发泡性能、力学和耐热性能的影响.结果表明,加入经过有机改性后的蒙脱土能有效提高材料的发泡倍率和耐热性能,并可降低材料的密度;纳米蒙脱土能够延长胶料的正硫化时间,加入1 phr的有机改性蒙脱土(OMMT)后,胶料的正硫化时间延长了1 min;纳米蒙脱土的加入提高了EVM发泡材料的力学性能和压缩永久变形率,且在OMMT含量为6 phr时复合材料的拉伸强度、撕裂强度和冲击回弹率达到最大值.","authors":[{"authorName":"熊祖江","id":"a06cfbf2-353c-4788-bbdc-0189b9f122af","originalAuthorName":"熊祖江"},{"authorName":"钟宁庆","id":"3290eb5f-ca68-493e-a0af-b29e035764e5","originalAuthorName":"钟宁庆"},{"authorName":"王旭","id":"4a9a9621-16ce-4aa9-9685-382a92db54ee","originalAuthorName":"王旭"}],"doi":"","fpage":"155","id":"bf0fc3c3-ffd6-46ae-97ba-fd710e09223e","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"9c8d8230-08ee-4e64-9d1e-71a360751268","keyword":"乙烯-乙酸乙烯酯橡胶","originalKeyword":"乙烯-乙酸乙烯酯橡胶"},{"id":"8cf0d647-a0d4-4cac-92fa-8e6200ab8d0c","keyword":"有机改性蒙脱土","originalKeyword":"有机改性蒙脱土"},{"id":"535f07d5-2152-4cac-9068-7c8048784505","keyword":"复合发泡材料","originalKeyword":"复合发泡材料"}],"language":"zh","publisherId":"gfzclkxygc201506030","title":"乙烯-乙酸乙烯酯橡胶/纳米蒙脱土复合发泡材料的制备和性能","volume":"31","year":"2015"},{"abstractinfo":"乙烯-醋酸乙烯酯橡胶(EVM)是一种重要的合成橡胶.文中介绍了不饱和羧酸盐增强EVM、EVM增韧改性尼龙1010和EVM/三元共聚尼龙共混物的研究工作.原位合成的不饱和羧酸盐能够显著改善EVM硫化胶的力学性能,是制备高性能和功能化EVM硫化胶的有效方法.EVM能够有效地增韧尼龙1010,EVM中醋酸乙烯酯的含量和EVM的门尼黏度是影响增韧效果的关键因素.采用三元共聚尼龙与EVM动态硫化,可以制备具有良好力学性能的热塑性弹性体.将EVM与塑料共混可以制备一系列具有良好力学性能和不同硬度的EVM共混物,这对于EVM材料的开发和应用具有重要的意义.","authors":[{"authorName":"吴文敬","id":"57a3588a-8a5b-43b6-8d19-47c461a57e26","originalAuthorName":"吴文敬"},{"authorName":"任文坛","id":"efd77b38-a5ea-4101-9e94-4772e0292f49","originalAuthorName":"任文坛"},{"authorName":"禹海洋","id":"9420b4ba-a9f5-4854-94a1-a996d73a37a4","originalAuthorName":"禹海洋"},{"authorName":"杜爱华","id":"d3f62c1d-1670-4319-baba-9e15b2e5fc76","originalAuthorName":"杜爱华"},{"authorName":"张勇","id":"15604f54-0c55-43f7-8619-4c07c996862f","originalAuthorName":"张勇"},{"authorName":"张隐西","id":"c3c38271-f9bf-4c59-b13d-2b97d82f3504","originalAuthorName":"张隐西"}],"doi":"","fpage":"186","id":"98e8e98c-ec91-44de-9229-a99ec8674b84","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"5c29cf67-56d7-4bcb-af68-bb0b76d15506","keyword":"乙烯-醋酸乙烯酯橡胶","originalKeyword":"乙烯-醋酸乙烯酯橡胶"},{"id":"f7b43781-44ca-4ad9-84f8-1930d4c556bd","keyword":"不饱和羧酸盐","originalKeyword":"不饱和羧酸盐"},{"id":"857d89e4-9bc6-4e7f-a3f4-293e565ef467","keyword":"尼龙","originalKeyword":"尼龙"},{"id":"b677be5e-15ee-4622-9a68-49a424fc2705","keyword":"共混物","originalKeyword":"共混物"},{"id":"939e5acd-2fde-4bca-bef1-cba07dd0a0a6","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"gfzclkxygc201402034","title":"乙烯-醋酸乙烯酯橡胶的共混改性","volume":"30","year":"2014"},{"abstractinfo":"研究了双膦配体对铑催化的乙酸乙烯酯氢甲酰化反应的促进作用,结果表明,在优化反应条件下,以双膦化合物2,2'-二(二苯膦甲基)-1,1'-联苯(BISBI)为配体时,铑催化乙酸乙烯酯氢甲酰化反应的TOF(转化频率)值达到4000 h-1,生成2-乙酰氧基丙醛的选择性＞99％.当在较温和的条件下Rh/BISBI催化乙酸乙烯酯氢甲酰化反应较长时间时TON(转化数)值达到9200,成醛率超过90％,2-乙酰氧基丙醛选择性仍保持＞99％.","authors":[{"authorName":"梁浩然","id":"2d5ef792-5d78-4f6d-ac0d-e7cbffcedc78","originalAuthorName":"梁浩然"},{"authorName":"张林","id":"b5a6d3ae-bdc7-4540-bc85-a87827a709e2","originalAuthorName":"张林"},{"authorName":"郑学丽","id":"ee116c1c-08c7-4439-8e58-3eaca2bf8294","originalAuthorName":"郑学丽"},{"authorName":"付海燕","id":"8de5ec54-2890-4757-a6ed-1f7ef5a85f2c","originalAuthorName":"付海燕"},{"authorName":"袁茂林","id":"2a52e2f1-73c1-4da3-acf4-e2407d39f66a","originalAuthorName":"袁茂林"},{"authorName":"李瑞祥","id":"93bbdb78-ec9e-4a8f-940b-974ebe10db96","originalAuthorName":"李瑞祥"},{"authorName":"陈华","id":"a13f6dec-7e26-4ef1-acbd-e40be62eea6a","originalAuthorName":"陈华"}],"doi":"10.1016/S1872-2067(11)60384-7","fpage":"977","id":"78db629d-fbc1-4764-b08a-5a1197de5916","issue":"6","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"5604d9ca-f0a5-4edc-8c6a-f86532857e28","keyword":"乙酸乙烯酯","originalKeyword":"乙酸乙烯酯"},{"id":"85a86537-668a-44bb-8265-c41a1a910d41","keyword":"氢甲酰化","originalKeyword":"氢甲酰化"},{"id":"cc8df315-3b38-42b0-b020-d532a571230f","keyword":"区域选择性","originalKeyword":"区域选择性"},{"id":"4e76ec8b-3a28-4c62-b179-b50a4794d06d","keyword":"双膦配体","originalKeyword":"双膦配体"},{"id":"8e3a02c5-2b96-433a-85af-6e1b4d1fbab2","keyword":"2-乙酰氧基丙醛","originalKeyword":"2-乙酰氧基丙醛"}],"language":"zh","publisherId":"cuihuaxb201206009","title":"双膦配体修饰铑催化乙酸乙烯酯氢甲酰化反应","volume":"33","year":"2012"},{"abstractinfo":"本文采用端羧基丁腈橡胶和丁腈橡胶进行增韧甲基丙烯酸型环氧乙烯基酯树脂,并对其性能进行了表征.","authors":[{"authorName":"陆士平","id":"fb4284db-4224-4e62-b908-98bd5dfdb295","originalAuthorName":"陆士平"},{"authorName":"王天堂","id":"4f459564-5a3c-4136-8a47-2a383f2ca507","originalAuthorName":"王天堂"},{"authorName":"沈伟","id":"c8cb1009-1961-4ed7-b390-354bdf0080b4","originalAuthorName":"沈伟"}],"doi":"10.3969/j.issn.1003-0999.2002.06.008","fpage":"27","id":"c8557d08-bf43-4941-b074-c946a14dbebd","issue":"6","journal":{"abbrevTitle":"BLGFHCL","coverImgSrc":"journal/img/cover/BLGFHCL.jpg","id":"6","issnPpub":"1003-0999","publisherId":"BLGFHCL","title":"玻璃钢/复合材料"},"keywords":[{"id":"eab1a976-050d-485e-8240-742fcaf06221","keyword":"橡胶","originalKeyword":"橡胶"},{"id":"d9354645-3864-42ca-9bfc-7c80ea9c614a","keyword":"增韧","originalKeyword":"增韧"},{"id":"1da99b76-9e7a-46d7-86a3-bc76ce85c4d1","keyword":"乙烯基酯树脂","originalKeyword":"乙烯基酯树脂"}],"language":"zh","publisherId":"blgfhcl200206008","title":"丁腈橡胶增韧乙烯基酯树脂的性能研究","volume":"","year":"2002"},{"abstractinfo":"采用乳液原位插层聚合方法首先创制了聚(丙烯腈-乙酸乙烯酯)/黄粘土纳米复合材料.通过红外光谱(IR),X射线荧光(XRF),X射线衍射(XRD),能谱,扫描电镜(SEM),差热分析(DSC)等方法对该纳米复合材料分析表征,研究结果表明采用单体原位插层聚合法制备纳米复合材料的乳液聚合方法成功制备了直径在纳米级的聚(丙烯腈-乙酸乙烯酯)/黄粘土纳米颗粒.","authors":[{"authorName":"祖丽华","id":"f370cb56-17f8-4fd2-b0f0-729eb1c344ff","originalAuthorName":"祖丽华"},{"authorName":"李青山","id":"0ce334bf-502c-4c7b-8000-3907fd61f47f","originalAuthorName":"李青山"},{"authorName":"胡玉洁","id":"d571826e-32f5-4437-88f5-7f14d1b763ae","originalAuthorName":"胡玉洁"}],"doi":"10.3969/j.issn.1001-4381.2007.z1.032","fpage":"136","id":"5ca4bd13-61b5-4b1e-8a43-095811f7f2b0","issue":"z1","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"4d44473a-13ac-4508-a18f-058dca9fbc2b","keyword":"共聚物","originalKeyword":"共聚物"},{"id":"8642ddb9-95b9-4185-9cc1-6f31e131c24d","keyword":"丙烯腈","originalKeyword":"丙烯腈"},{"id":"164a6d8b-c9da-462e-8c13-b9d110757269","keyword":"乙酸乙烯酯","originalKeyword":"乙酸乙烯酯"},{"id":"a2c30c73-518d-4e8a-ad03-e99a0c5d8324","keyword":"乳液原位插层聚合","originalKeyword":"乳液原位插层聚合"},{"id":"adc19b9f-e8fb-4980-b64f-9c8b5a955aa3","keyword":"黄粘土","originalKeyword":"黄粘土"},{"id":"3e0b32b8-ec28-4d95-8278-79ba506aa738","keyword":"纳米复合材料","originalKeyword":"纳米复合材料"}],"language":"zh","publisherId":"clgc2007z1032","title":"聚(丙烯腈-乙酸乙烯酯)/黄粘土纳米复合材料研究","volume":"","year":"2007"},{"abstractinfo":"以丙烯酸为调聚单体、偶氮二异丁腈为引发剂、甲醇为溶剂进行乙酸乙烯酯溶液聚合.通过聚合转化率和凝胶渗透色谱的测定,研究了聚合过程和所制备聚合物的分子量及其分布,以及丙烯酸对聚合物分子量分布的影响;进一步探讨了反应装置的安装及结构对聚合反应的影响.结果表明,适当引入丙烯酸,当丙烯酸/乙酸乙烯酯的摩尔比为3/100,并采用密封冷凝搅拌装置,反应5 h,既可确保较高聚合转化率,又可获得窄分子量分布的聚合产物.","authors":[{"authorName":"冯海柯","id":"4d82fdee-3bf3-4faf-96dc-d65731c5a7ad","originalAuthorName":"冯海柯"},{"authorName":"贺媛","id":"9ef13694-8218-490f-a420-1166e21cddee","originalAuthorName":"贺媛"},{"authorName":"淡宜","id":"5d40d7bf-9d48-4e41-932d-297ffc5f5358","originalAuthorName":"淡宜"}],"doi":"","fpage":"19","id":"749b73ac-4dad-49eb-9e05-4a07196b198b","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"e6580fe4-2f92-4ae4-81ac-45600a95450d","keyword":"乙酸乙烯酯","originalKeyword":"乙酸乙烯酯"},{"id":"60a99abc-9e5c-4b4e-a77e-df4079d75315","keyword":"丙烯酸","originalKeyword":"丙烯酸"},{"id":"02f12e9f-9929-4393-8318-87b942c5be39","keyword":"分子量分布","originalKeyword":"分子量分布"},{"id":"531baf36-d4f2-4370-a02c-8ee94ad0f324","keyword":"搅拌装置","originalKeyword":"搅拌装置"}],"language":"zh","publisherId":"gfzclkxygc200802005","title":"窄分子量分布的乙酸乙烯酯聚合物的制备","volume":"24","year":"2008"},{"abstractinfo":"为了合成含电气石功能聚合物，采用甲基丙烯酸酐对电气石进行表面改性，在电气石表面引入双键，制备了甲基丙烯酸电气石酯，而后与乙酸乙烯酯进行共聚反应，合成了甲基丙烯酸电气石酯-乙酸乙烯酯共聚物。通过IR、XRD、SEM等手段对其进行结构和形貌表征，结果表明，电气石粉体成功引入到共聚物中，具有优良的分散性和储存稳定性。且甲基丙烯酸电气石酯-乙酸乙烯酯共聚物成膜后具有良好的力学性能和优异的负离子释放量、远红外辐射性等性能。","authors":[{"authorName":"李梦灿","id":"269226f4-ad05-4627-b887-68f540973496","originalAuthorName":"李梦灿"},{"authorName":"胡应模","id":"5a6361da-bd14-473c-ad1c-a028cda63946","originalAuthorName":"胡应模"},{"authorName":"李云华","id":"5559949b-385e-4c04-b428-cf6ed705b22f","originalAuthorName":"李云华"},{"authorName":"候春燕","id":"dd502dc7-96a4-436a-9ead-e7c4512b5a7d","originalAuthorName":"候春燕"},{"authorName":"刘权","id":"ee716df4-deeb-4c2b-9622-7cf358024128","originalAuthorName":"刘权"},{"authorName":"刘雨航","id":"1d7f59d3-3e50-46d4-b720-3049812ef934","originalAuthorName":"刘雨航"}],"doi":"10.3969/j.issn.1001-9731.2016.12.040","fpage":"12230","id":"4abf9a16-c1e3-4971-a5f4-5ab05c02e678","issue":"12","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"4bd9c275-f7f8-4b58-8d75-c3beaa4bf829","keyword":"电气石","originalKeyword":"电气石"},{"id":"c2f91e28-4cae-4462-a040-5bb61267a963","keyword":"表面改性","originalKeyword":"表面改性"},{"id":"5505fc6b-d2e7-4800-87e0-a149db41baed","keyword":"功能聚合物","originalKeyword":"功能聚合物"},{"id":"9d6d2f16-c75d-490b-b44e-25184c41848c","keyword":"负离子","originalKeyword":"负离子"},{"id":"c8a0b5ef-4f46-4131-9cf9-68f3dc6f884a","keyword":"远红外辐射","originalKeyword":"远红外辐射"}],"language":"zh","publisherId":"gncl201612040","title":"甲基丙烯酸电气石酯-乙酸乙烯酯共聚物的制备与表征?","volume":"47","year":"2016"},{"abstractinfo":"通过对橡胶表面进行处理并涂刷柔性过渡层,研究橡胶与乙烯基树脂复合材料的界面粘接性能.结果表明,橡胶表面经过化学处理后,出现大量细小微裂纹,使得橡胶与乙烯基酯复合材料的界面粘接强度得到大幅度提高;在经过化学处理后的橡胶表面涂刷柔性能渡层,二者界面剥离强度提高到2.90 kN/m,粘合强度达到2.30 MPa.","authors":[{"authorName":"彭运松","id":"a97e09a1-d847-4a8a-93a0-f63191537e24","originalAuthorName":"彭运松"},{"authorName":"郭万涛","id":"22ce782f-8412-4219-854c-86eff8508307","originalAuthorName":"郭万涛"},{"authorName":"陶红波","id":"5cc8dd5c-2c40-454b-b624-52be29636255","originalAuthorName":"陶红波"},{"authorName":"杨勇","id":"4e35a188-cdd3-4f02-a61d-d7308a4696ef","originalAuthorName":"杨勇"}],"doi":"","fpage":"29","id":"2195c312-417b-4779-9535-6a056f2345c9","issue":"2","journal":{"abbrevTitle":"CLKFYYY","coverImgSrc":"journal/img/cover/CLKFYYY.jpg","id":"10","issnPpub":"1003-1545","publisherId":"CLKFYYY","title":"材料开发与应用"},"keywords":[{"id":"aae9d230-905c-4906-959c-c932c1a78833","keyword":"乙烯基复合材料","originalKeyword":"乙烯基复合材料"},{"id":"58cc5e1c-348a-4476-b2da-3bc815b017f8","keyword":"橡胶","originalKeyword":"橡胶"},{"id":"2ec7567b-324a-40ff-a6c2-621334da4366","keyword":"界面性能","originalKeyword":"界面性能"}],"language":"zh","publisherId":"clkfyyy201702006","title":"乙烯基酯复合材料/橡胶界面性能研究","volume":"32","year":"2017"},{"abstractinfo":"以N,N-二甲基甲酰胺(DMF)为溶剂,采用静电纺丝法制备了聚乙酸乙烯酯(PVAc)纤维.用场发射扫描电镜观察了PVAc纤维的形貌,研究了PVAc溶液质量分数、纺丝电压、收集距离等对纤维形貌及平均直径的影响.研究结果表明,PVAc溶液质量分数和纺丝电压对纤维的形貌有显著影响,随着PVAc溶液质量分数和纺丝电压的增大,纤维的平均直径增大;收集距离对纤维形貌的影响较小.尝试采用静电纺丝法制备了炭黑和PVAc的复合纤维,以增强纤维的导电性,成为导电碳纤维,但炭黑会显著降低PVAc的成纤性,因为它会吸附溶剂DMF,使溶剂在电纺过程中不易挥发,射流不能固化成纤维.","authors":[{"authorName":"黄睿","id":"e01c9c0b-aff2-4116-b198-a31e60160517","originalAuthorName":"黄睿"},{"authorName":"朱静","id":"3eedb9a3-f4de-41be-8fbc-0255fcd41df0","originalAuthorName":"朱静"}],"doi":"","fpage":"1","id":"41884f7e-7e09-4963-8d3a-9351947f2a81","issue":"12","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"6c959954-09c0-4edb-a29d-7397deca2d20","keyword":"聚乙酸乙烯酯","originalKeyword":"聚乙酸乙烯酯"},{"id":"ae149f1a-a4c0-40ef-b0b8-715309f7b34e","keyword":"静电纺丝","originalKeyword":"静电纺丝"},{"id":"c8894421-cda8-4c52-af8f-1be1e0485ad7","keyword":"纤维","originalKeyword":"纤维"},{"id":"10065bef-519e-452a-b9c5-549ba6a77503","keyword":"形貌","originalKeyword":"形貌"}],"language":"zh","publisherId":"cldb201012001","title":"静电纺丝参数对聚乙酸乙烯酯纤维形貌的影响","volume":"24","year":"2010"},{"abstractinfo":"采用SET-LRP方法进行了乙酸乙烯酯(VAc)的活性聚合.通过聚合转化率、聚合物相对平均分子量及分子量分布、聚合物核磁共振氢谱分析,研究了额外失活剂(CuCl2)、温度、溶剂等因素对聚合反应的影响.研究结果表明,失活剂CuⅡ在使反应可控性得到增加的同时却降低了反应的转化率；反应速率不会随反应温度的升高持续增加,超过某一临界温度后反应速率反而随温度的升高而降低；与二甲基亚砜(DMSO)为溶剂相比,甲醇(CH3OH)为溶剂时,得到的聚合物的相对平均分子量较高,但分子量分布较宽.","authors":[{"authorName":"陈冲","id":"f97c19d5-a8b2-4d5a-81d4-7459bfc6b808","originalAuthorName":"陈冲"},{"authorName":"任伍杨","id":"35a250f6-f81a-4893-894f-90021066cb00","originalAuthorName":"任伍杨"},{"authorName":"江龙","id":"d239c92a-1a47-41a9-8c69-a2ec2fe6520f","originalAuthorName":"江龙"},{"authorName":"淡宜","id":"b1f4645d-6b11-4e12-b1a4-48cad9181844","originalAuthorName":"淡宜"}],"doi":"","fpage":"44","id":"96c292a1-0ce5-48d3-93f7-1761b7d24391","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7f21de40-6398-410f-90aa-c2a9bca58e10","keyword":"单电子转移活性自由基聚合","originalKeyword":"单电子转移活性自由基聚合"},{"id":"f72f706e-d239-4676-863c-40b18eb007bc","keyword":"乙酸乙烯酯","originalKeyword":"乙酸乙烯酯"},{"id":"26740d01-bdd1-426c-bd69-fef13354c71d","keyword":"失活剂","originalKeyword":"失活剂"},{"id":"6c972f5a-2e6c-4f66-ad3b-6124ddacd834","keyword":"温度","originalKeyword":"温度"},{"id":"7e45ec4a-e3f4-4f6b-ba59-4325480e5ff4","keyword":"溶剂","originalKeyword":"溶剂"}],"language":"zh","publisherId":"gfzclkxygc201301011","title":"乙酸乙烯酯的单电子转移活性自由基聚合","volume":"29","year":"2013"}],"totalpage":1663,"totalrecord":16630}