CoAs3结构的Skutterudite化合物具有复杂的能带结构,较大的空穴迁移率.通过适当的掺杂,可使Skutterudite化合物的笼状孔隙形成部分填充,使填隙原子处于"跳动"状态,从而产生对声子散射作用,降低Skutterudite化合物的热导率.
参考文献
| [1] | Sharp J W;Jones E C;Williams R K .Thermoelectric properties of CoSb3 and related alloys[J].Journal of Applied Physics,1995,78(02):1013. |
| [2] | Nolas GS.;Slack GA.;Cohn JL. .Effect of partial void filling on the lattice thermal conductivity of skudderudites[J].Physical Review.B.Condensed Matter,1998(1):164-170. |
| [3] | Singh David J;Pickett Warren E .Skutterudite antimonides quasilinear bands and unusual transprot[J].Physical Review B,1994,50(15):11235. |
| [4] | Morelli Donald T;Meisner Gregory P .Low temperature properties of the filled Skutterudite CeFe4Sb12[J].Journal of Applied Physics,1995,77(08):3777. |
| [5] | Mandrus D.;Darling TW.;Hundley MF.;Peterson EJ.;Thompson JD.;Migliori A. .ELECTRONIC TRANSPORT IN LIGHTLY DOPED COSB3[J].Physical Review.B.Condensed Matter,1995(7):4926-4931. |
| [6] | Morelli D T;Caillat T;Fleurial J-P et al.Low temperature transport properties of p-type CoSb3[J].Physical Review B,1995,51(15):9622. |
| [7] | Caillat T.;Fleurial JP.;Borshchevsky A. .PROPERTIES OF SINGLE CRYSTALLINE SEMICONDUCTING COSB3[J].Journal of Applied Physics,1996(8):4442-4449. |
| [8] | Caillat T.;Borshchevsky A.;Fleurial JP.;Kulleck J. .PREPARATION AND THERMOELECTRIC PROPERTIES OF THE SKUTTERUDITE-RELATED PHASE RU0.5PD0.5SB3[J].Journal of Applied Physics,1996(11):8419-8426. |
| [9] | SALES B C;Mandrus D;Williams R K .Filled Skutterudite antimonides :a new calss of thermoelectric materials[J].Science,1996,272:1325. |
| [10] | Kasper J S;Hagenmuller P;Pouchard M et al.Clathrate structure of silicon Na8Si40 (x ＜ 11 )[J].Science,1965(150):1713. |
| [11] | Iversen Bo B;Palmgvist Anders E C;Cox David E et al.Why are clathrates good candidates for thermoelectric materials[J].Journal of Solid State Chemistry,2000,149:455. |
| [12] | Nolas G S;Slack G A;Cohn J L.The next generation of thermoelectric materials[A].,1998:294. |
| [13] | Chapon L;Ravot D;Tedence J C.Skutterudite based new thermoelectric compounds[A].,1999:13. |
| [14] | Yoshiyuki Kawaharada;Ken Kurosaki;Masayoshi Uno .Thermoelectric properties of CoSb_3[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2001(1/2):193-197. |
| [15] | Singh David J;Fornari M;Feldman J L.First principles studies of novel thermoelectric materials[A].,1999:448. |
| [16] | Kakuei Matsubara.Perspectives of new materials research for thermoelectric applications[A].,1998 |
| [17] | Watcharapasorn A;DeMattei R C;Feigelson R S.Thermoelectric properties of some phosphorus-based Skutterudite compounds[A].,1999:462. |
| [18] | G. S. Nolas;M. Kaeser;R. T. Littleton IV .High figure of merit in partially filled ytterbium skutterudite materials[J].Applied physics letters,2000(12):1855-1857. |
| [19] | Hirotsugu Takizawa;Keiichi Miura;Masayuki Ito et al.Atom insertion into the CoSb3 Skutterudite host lattice under high pressure[J].Journal of Alloys and Compounds,1999,282:79. |
| [20] | Ackermann J;Wold A .The perparation and characterization of the cobalt Skutterudites CoP3 CoAs3 and CoSb3[J].Journal of Physics and Chemistry of Solids,1977,38:1013. |
| [21] | Jeitschko W;Braun D .LaFe4P12 with filled CoAs3-type structure and isotypic lanthanoid-transition metal polyphosphides[J].ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE,1977,33:3401. |
| [22] | Slack G A;Tsoukala V G .Some properties of semiconducting IrSb3[J].Journal of Applied Physics,1994,70(03):1665. |
| [23] | Keppens V;Mandrus D;Sales B C et al.Localized vibrational modes in metallic solids[J].Nature,1998,395:876. |
| [24] | Gao M;Rowe D M .A serious limitation to the phonon glass electron crystal (PGEC) approach to improved thermoelectric materials[J].Journal of Materials Science Letters,1999(18):1305. |
| [25] | Chapon L;Ravot D;Tedenac J C .Nickel-substituted skutterudites: synthesis structural and electrical properties[J].Journal of Alloys and Compounds,1999,282:58. |
| [26] | Dilley N R;Bauer E D;Maple M B et al.Thermoelectric and optical properties of the filled skutterudite YbFe4Sb1[J].Phvs Rev B,2000,61(07):4608. |
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