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  4. 新型材料用于固定联吡啶钌电致化学发光的研究进展

材料导报, 2011, 25(3): 51-63.

新型材料用于固定联吡啶钌电致化学发光的研究进展

王宇峰 1, , 宋娟 2, , 关建宁 3, , 李鑫 4, , 仲慧 5,

1.南京工业大学理学院,南京210009

2.南京工业大学理学院,南京210009

3.南京工业大学理学院,南京210009

4.淮阴师范学院化学化工学院江苏省低纤维材料化学重点建设实验室,淮安223300

5.南京工业大学理学院,南京210009;淮阴师范学院化学化工学院江苏省低纤维材料化学重点建设实验室,淮安223300

基金项目:   江苏省高校自然科学重大基础研究项目(07KJA15012)   国家自然科学基金(20975043)  

关键词： 电致发光 , 联吡啶钌 , 修饰电极

Research Progress of New Materials Applied in Ru(bpy)32+ Immobilized Electrochemiluminescence System

固定联吡啶钌电致化学发光体系因其灵敏度高、可以连续测试、装置简单等优点被广泛应用于分子生物学、化学、药学等领域.各种新材料的运用克服了原有方法稳定性差、重现性差等缺点,拓宽了固定化联吡啶钌电致化学发光的应用范围.介绍了近几年来一些用于固定联吡啶钌新的材料、固定方法及其相关的应用.

参考文献

[1] Mark M.Richtert .Electrochemiluminescence(ECL)[J].Chemical Reviews,2004(6):3003-3036.
[2] 丁收年,徐静娟,陈洪渊.Ru（bpy）32+电致化学发光技术的若干进展[J].中国科技论文在线,2007(08):595-606.
[3] Wu XP;Huang FX;Duan JP;Chen GN .Electrochemiluminescent behavior of melatonin and its important derivatives in the presence of Ru(bpy)(3)(2+)[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2005(5):1279-1285.
[4] Massimo Z;Paoio P;Franco M .A single calibration graph for the direct determination of ascorbic and dehydroascorbic acids by electrogenerated luminescence based on Ru(bpy)3 2+ in aqueous solution[J].Analytical Chemistry,2000,72:4943.
[5] Vincenzo B;Juris A;Venturi M et al.Luminescent and redox-active polynuclear transition metal complexes balzani[J].Chemical Reviews,1996,96:759.
[6] Juris A;Balzani V;Barigelletti F et al.Ru (Ⅱ)polypyridine complexes photophysics,photochemistry,electrochemistry,and chemiluminescence[J].Chemical Reviews,1988,84:85.
[7] Wei H;Wang E .Solid-state electrochemiluminescence of tris(2,2 '-bipyridyl) ruthenium[J].TrAC: Trends in Analytical Chemistry,2008(5):447-459.
[8] Li H J;Han S;Hu L Z et al.Progress in Ru(bpy)32+ dectrogenerated chemiluminescence[J].Chinese Journal of Analytical Chemistry,2009,37(11):1557.
[9] Chang M M;Saji T;Bard A J .Electrogenerated chemiluminescence.30.Electrochemical oxidation of oxalate ion in the presence of luminescers in acetonitrile solutions[J].Journal of the American Chemical Society,1977,99:5399.
[10] Ege D;Backer W G;Bard A J .Electrogenerated chemiluminescent determination of tris(2,2'-bipyridine) ruthenium ion (Ru(bpy)32+) at low levels[J].Analytical Chemistry,1984,56:2413.
[11] Rubinstein I;Bard A J .Aqueous ecl systems based on tris (2,2'-bipyridine) ruthenium (2 +) and oxalate or organic acids[J].Journal of the American Chemical Society,1981,103:512.
[12] Leland J K;Powell M J .Electrogenerated chemiluminescence:An oxidative-reduction type ECL reaction sequence using tripropyl amine[J].Journal of the Electrochemical Society,1990,137:3127.
[13] Zu Y B;Bard A J .The role of direct coreactant oxidation in the ruthenium Tris (2,2') bipyridyl/tripropylamine system and the effect of halide ions on the emission intensity[J].Ansi Chem,2000,72:3223.
[14] Miao WJ.;Choi JP.;Bard AJ. .Electrogenerated chemiluminescence 69: The tris(2,2 '-bipyridine)ruthenium(II), (Ru(bpy)(3)(2+))/tri-n-propylamine (TPrA) system revisited - A new route involving TPrA(center dot+) cation radicals[J].Journal of the American Chemical Society,2002(48):14478-14485.
[15] Liu, LL;Bao, JC;Fang, M;Li, LF;Dai, ZH .Electrogenerated chemiluminescence for the sensitive detection of leucine using Ru(bpy)(3)(2+) immobilized on dendritic Pd nanoparticle[J].Sensors and Actuators, B. Chemical,2009(2):527-531.
[16] Li H;Chen J;Han S et al.Eleetroehemilumineseence from tris (2,2'-bipyridyl) ruthenium (Ⅱ) -graphene-Nafion modified electrode[J].TALANTA,2009,79:165.
[17] Choi HN.;Cho SH.;Lee WY. .Electrogenerated chemiluminescence from tris(2,2 '-bipyridyl)ruthenium(II) immobilized in titania-perfluorosulfonated lonomer composite films[J].Analytical chemistry,2003(16):4250-4256.
[18] Zhihui Guo;Shaojun Dong .Electrogenerated Chemiluminescence from Ru(Bpy)_(3)~(2+) Ion-Exchanged in Carbon Nanotube/Perfluorosulfonated Ionomer Composite Films[J].Analytical chemistry,2004(10):2683-2688.
[19] 聂海瑜.碳纳米管的应用研究进展[J].化学工业与工程技术,2004(05):34-38.
[20] 郭志慧,唐隆健,章竹君.碳纳米管/Nafion-吡啶钌修饰电极电化学发光法测定激动素[J].分析化学,2009(01):13-18.
[21] 李利军,陈昌东,蔡卓,李斯光,钟亮,程昊.多壁碳纳米管/壳聚糖-联吡啶钌复合物修饰的石墨电极上电化学发光行为的研究及分析应用[J].分析试验室,2009(08):5-9.
[22] Xia Y;Ruo Y;Chai Y et al.Electrochemiluminescence sensor based on multiwalled carbon nanotubes doped polyvinyl butyral film containing Ru(bpy) as chemiluminescence reagent[J].Electroanalysis,2009,21(14):1636.
[23] 董绍俊;车广礼;谢远武.化学修饰电极[M].北京:科学出版社,1995:310.
[24] Oyama N .Catalysis of electrode processes by multiplycharged metal complexes electrostatically bound to polyelectrolyte coatings on graphite electrodes,and the use of polymer-coated rotating disk electrodes in diagnosing kinetic and conduction mechanisms[J].Analytical Chemistry,1980,52(08):1192.
[25] Li B Z;Jing L;Xu Y H .Solid-state electrochemiluminescence sensor based on the Nafion/poly(sodium 4-styrene sulfonate) composite film[J].TALANTA,2009,79:454.
[26] 宋红杰,章竹君.Nano-TiO2/Nafion-吡啶钌复合物膜修饰的玻碳电极上电化学发光测定盐酸西替利嗪[J].分析试验室,2007(02):1-5.
[27] Xing B;Yin X B .Electroehemiluminescence from hydrophilie thin film Ru(bpy)32+-modified electrode prepared using natural halloysite nanotubes and polyacrylamide gel[J].Biosensors and Bioelectronics,2009,24:2939.
[28] Mao, L;Yuan, R;Chai, YQ;Zhuo, Y;Yang, X;Yuan, SR .Multi-walled carbon nanotubes and Ru(bpy)(3)(2+)/nano-Au nano-sphere as efficient matrixes for a novel solid-state electrochemiluminescence sensor[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2010(5):1692-1697.
[29] Qian L;Yang X R .One-step immobilization of tris(2,2'-bipyridyl) ruthenium(Ⅱ) via vapor-surface sol-gel deposition towards solid-state electrochemiluminescence detection[J].Analytica Chimica Acta,2008,609:210.
[30] Xu J;Yu J G;Zhou M H .Fabrication of Ru(bpy)32+-titahate nanotube nanocomposite and its application as sensitive solid-state electrochemiluminescence sensor material[J].Journal of Physics and Chemistry of Solids,2010,71:527.
[31] Wen Yun;Ying Xu;Ping Dong .Solid-state electrochemiluminescence sensor through the electrodeposition of Ru(bpy)_3~(2+)/AuNPs/chitosan composite film onto electrode[J].Analytica chimica acta,2009(1):58-62.
[32] Xu, M.;Zhao, R.;Wang, J.;Chen, G. .Fabrication of a new electrochemiluminescent sensing interface based on zinc oxide nanorod[J].Electroanalysis,2010(3):320-324.
[33] 刘洋,杨秀荣.有序介孔材料SBA-15吸附Ru（bpy）2+3修饰电极的电化学发光研究[J].高等学校化学学报,2007(04):640-644.
[34] Li, YL;Zhu, H;Yang, XR .[Ru(bpy)(3)](2+) nanocomposites containing heteropolyacids: Simple preparation and stable solid-state electrochemiluminescence detection application[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2009(2):870-874.
[35] Bi LH;Zhou WH;Wang HY;Dong SJ .Preparation of nanoparticles of bipyridineruthenium and silicotungstate and application as electrochemiluminescence sensor[J].Electroanalysis,2008(9):996-1001.
[36] Ya L L;Fan Y;Yang X R .Electrochemiluminescence detection based on ruthenium({]) tris(bipyridine) immobilised in sulfonic-functionalised titania nanoparticles by ion exchange strategy[J].Analyst,2009,134:2100.
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