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聚噻吩因其良好的溶解性、高电导率和环境稳定性成为导电高分子研究的热门领域之一.综述了聚噻吩及其衍生物基复合材料的研究进展及其制备方法(原位聚合法、电化学法、插层法、界面聚合法、乳液法和共混法等),介绍了聚噻吩类复合材料在电容器、电致变色和电磁方面的应用前景及现状,指出了聚噻吩及其衍生物基复合材料研究中普遍存在的易脱掺杂、电导率不高和性能不稳定等问题.

参考文献

[1] Liu Ziran;Zhou Jingran;Xue Hailin .Polyaniline/TiO2 solar cells[J].Synthetic Metals,2006,156(9-10):721.
[2] Tai HL;Jiang YD;Xie GZ;Yu JS;Chen X;Ying ZH .Influence of polymerization temperature on NH3 response of PANI/TiO2 thin film gas sensor[J].Sensors and Actuators, B. Chemical,2008(1):319-326.
[3] Zou M J;Yoshio M;Gopukumar S et al.Synthesis of high-voltage ,(4.5 V) cycling doped LiCoO2 for use in lithium rechargeable cells[J].Chemistry of Materials,2003,15(25):4699.
[4] Chen Weixing;Zhang Suyan;Ma Aijie et al.The synthesis and characterization of thiophene derivative polymers[J].Advances in Materials Research,2011,284-286(04):1846.
[5] Yu YH.;Jen CC.;Huang HY.;Wu PC.;Huang CC.;Yeh JM. .Preparation and properties of heterocyclically conjugated poly(3-hexylthiophene)-clay nanocomposite materials[J].Journal of Applied Polymer Science,2004(6):3438-3446.
[6] Ballav N;Biswas M .A conductive composite of polythiophene with 13X-zeolite[J].Mater Sei Eng B,2006,129(1-3):270.
[7] C. Jerome;V. Geskin;R. Lazzaroni;J. L. Bredas;A. Thibaut;C. Calberg;I. Bodart;M. Mertens;L. Martinot;D. Rodrigue;J. Riga;R. Jerome .Full-Electrochemical Preparation of Conducting/Insulating Binary Polymer Films[J].Chemistry of Materials,2001(5):1656-1664.
[8] Viney Saini;Zhongrui Li;Shawn Bourdo .Electrical, Optical, and Morphological Properties of P3HT-MWNT Nanocomposites Prepared by in Situ Polymerization[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(19):8023-8029.
[9] 敏世雄,王芳,李国良,韩玉琦,冯雷.聚噻吩敏化TiO_2复合材料的制备和光催化性能[J].精细化工,2009(12):1154-1158.
[10] 廖川平.电化学聚合[J].化学通报,2000(02):37.
[11] Fu Chaopeng;Zhou Haihui;Liu Rui et al.Supercapacitor based on electropolymerized polythiophene and multi-walled carbon nanotubes composites[J].Materials Chemistry and Physics,2012,132(2-3):596.
[12] Jun Luo;Hai-jun Niu;Wen-jun Wu .Enhancement of the efficiency of dye-sensitized solar cell with multi-wall carbon nanotubes/polythiophene composite counter electrodes prepared by electrodeposition[J].Solid state sciences,2012(1):145-149.
[13] Ballav N;Biswas M .A conducting nanocomposite via intercalative polymerization of thiophene in montmorillonite clay[J].Synthetic Metals,2004,142(1-3):309.
[14] Murugan A V .Electrochemical properties of microwave irradiated synthesis of poly (3,4-ethylenedioxythiophene) /V2O5 nanocomposites as cathode materials for rechargeable lithium batteries[J].Electrochimica Acta,2005,50(24):4627.
[15] 王红敏,梁旦,韩菲菲,唐国强,徐学诚.聚噻吩/多壁碳纳米管复合材料结构与导电机理的研究[J].化学学报,2008(20):2279-2284.
[16] 陈黎,张校刚,原长洲,陈胜尧.聚乙撑二氧噻吩/二氧化锰纳米复合物的界面聚合制备及其电化学性能[J].物理化学学报,2009(02):304-308.
[17] Singh K;Ohlan A;Saini P;Dhawan SK .Poly(3,4-ethylenedioxythiophene) gamma-Fe2O3 polymer composite-super paramagnetic behavior and variable range hopping 1D conduction mechanism-synthesis and characterization[J].Polymers for advanced technologies,2008(3):229-236.
[18] Beck W J E;Wienk M M;Janssen R A J .Hybrid solar cells from regioregular polythiohene and ZnO nanoparticles[J].Advanced Functional Materials,2006,16(08):1112.
[19] 王红敏,晋圣松,唐国强,韩菲菲,梁旦,徐学诚.聚噻吩/多壁碳纳米管复合材料的导电性能[J].化学学报,2007(24):2923-2928.
[20] Briseno, AL;Holcombe, TW;Boukai, AI;Garnett, EC;Shelton, SW;Frechet, JJM;Yang, PD .Oligo- and Polythiophene/ZnO Hybrid Nanowire Solar Cells[J].Nano letters,2010(1):334-340.
[21] 李生英,高锦章,何丽君,王永红,杨武,杨燕茹.PTh/ZnO复合纳米粉的固相合成及其光谱特性[J].无机化学学报,2007(02):291-294.
[22] 徐守斌,江龙,杨海刚,宋远卿,淡宜.光诱导聚合制备聚噻吩/二氧化钛复合粒子的结构及光催化性能[J].催化学报,2011(04):536-545.
[23] Uygun, A.;Oksuz, L.;Yavuz, A.G.;Gule, A.;Sen, S. .Characteristics of nanocomposite films deposited by atmospheric pressure uniform RF glow plasma[J].Current applied physics: the official journal of the Korean Physical Society,2011(2):250-254.
[24] Uygun A;Yavuz A G;Sen S et al.Polythiophene/SiO2 nanocomposites prepared in the presence of surfactants and their application to glucose biosensing[J].Synthetic Metals,2009,159(19):2022.
[25] 桂阳海,崔瑞立,莫元妙,牛连杰.聚噻吩/WO3复合纳米材料的制备及气敏性能[J].电子元件与材料,2010(05):32-34,40.
[26] 哈恩华,黄大庆,哈恩平,王智勇,丁鹤雁.聚乙撑二氧噻吩/碳纳米管复合物的合成与表征[J].航空材料学报,2007(05):62-65.
[27] 黄智敏,王玉华,邓安民.导电高分子与丙烯酸酯的接枝共聚反应研究[J].广州化工,2009(03):94-95,103.
[28] Erdogan M K;Karakisla M;Sacak M .Preparation,characterization and electromagnetic shielding effectiveness of conductive polythiophene/poly(ethylene terephthalate) composite fibers[J].Journal of Macromolecular Science,2012,49(06):473.
[29] Lakshmi, K.;John, H.;Joseph, R.;Mathew, K.T.;George, K.E. .Microwave properties of selected thermoplastic conducting composites[J].Journal of Applied Polymer Science,2012(6):5254-5259.
[30] 杜永,蔡克峰.聚噻吩及其衍生物、聚噻吩基复合材料的导电性能研究进展[J].材料导报,2010(21):69-73.
[31] 朱云峰,潘柯良,淡宜.PT/TiO2复合粒子光催化降解有机污染物的性能[J].高分子材料科学与工程,2008(07):102-105.
[32] Yuasa M;Oyaizu K;Murata H et al.Fabrication of electrodes for highly sensitive detection of a superoxide anion radical by electropolymerization of thienylporphyrins in the presence of thiophene and application to active oxygen sensors[J].Soc Polym Sci,2006,63(06):427.
[33] 高峰阁,田艳红.聚噻吩/活性炭复合材料作为超级电容器电极材料的电性能[J].高分子材料科学与工程,2011(02):152-155.
[34] Karthikeyan G;Sahoo S;Nayak G C et al.Investigations on doping of poly(3-methyl-thiophene) composites for supercapacitor applications[J].Macromolecular Research,2012,20(02):351.
[35] 涂亮亮,贾春阳,翁小龙,邓龙江,唐武.导电聚合物电致变色材料[J].化学进展,2010(10):2053-2059.
[36] Kang, JH;Oh, YJ;Paek, SM;Hwang, SJ;Choy, JH .Electrochromic device of PEDOT-PANI hybrid system for fast response and high optical contrast[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2009(12):2040-2044.
[37] Ma LJ;Li YX;Yu XF;Yang QB;Noh CH .Using room temperature ionic liquid to fabricate PEDOT/TiO2 nanocomposite electrode-based electrochromic devices with enhanced long-term stability[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2008(10):1253-1259.
[38] 李鹏,官建国,张清杰,袁润章.导电聚合物/磁性纳米复合材料的制备及其结构与性能[J].华东理工大学学报(自然科学版),2006(10):1246-1252.
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