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合成了由2-呋喃甲醛修饰的中氮茚类化合物(5),研究了多种金属离子对其荧光光谱的影响。结果表明其对Pb2+具有良好的荧光识别性。紫外光谱则表明二者之间发生了明显的化学反应。

The compound 5 of 2-furaldehyde-indolizine was synthesized. Its structure was characterized by using IR, UV and t H NMR. The fluorescent and the influence of different transitional metal ions such as Co2+ ,Ca2+ , Zn2+ ,Cu2+,K+ ,Ni2+ ,Mn2+ ,Pb2+ on thiscompound were studied systematically. The results showed this compound exhibited a highly selective fluorescence quenching effect by Pb2+ ions, while other metal ions almost no quenching happened. The UV absorption spectra increased with the addition of Pb2+ into the solution of 2-fural- dehyde-indolizine suggesting that chemical reaction occurred between the Pb2+ and this compound. This com- pound is promising to be the probe for the Pb2+.

参考文献

[1] Burdette SC.;Frederickson CJ.;Bu WM.;Lippard SJ. .ZP4, an improved neuronal Zn2+ sensor of the Zinpyr family[J].Journal of the American Chemical Society,2003(7):1778-1787.
[2] De Silva A P;Nimal Gunaratne Q N;Gunnlauggson T et al.[J].Chemical Reviews,1997,97:1515-1566.
[3] Bora U;Saikia A;Boruah R C .[J].Orgaic Letters,2003,5:435-438.
[4] Fang Xiang;Wu Yongming;Deng Juan et al.[J].Tetrahedron,2004,60:5487-5493.
[5] 王炳祥,胡家欣,胡跃飞,胡宏纹.由吡啶叶立德和Mannich碱一步合成1-酰基中氮茚衍生物[J].高等学校化学学报,1999(03):418-420.
[6] 王炳祥,沈永淼,沈健,李邨,胡宏纹.中氮茚腈类化合物的合成及其荧光性质的研究[J].化学学报,2004(17):1649-1652.
[7] 沈永淼,王炳祥,冯玉英,沈珠英,沈健,李邨,胡宏纹.氨基苯基类中氮茚化合物的合成及作为质子探针的研究[J].高等学校化学学报,2006(04):651-653.
[8] Wang B X;Zhang X C;Hu Y F et al.[J].Journal of the Chemical Society,Perkin Transactions,1999,1:1571-1575.
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