合成了一种具有非穿插结构的孔性配位聚合物[Cu3(BTB)2(H2O)3]·9DMF·2H2O(BTB=1,3,5-三(4-羧基苯基)苯,DMF=N,N-二甲基甲酰胺),并对其进行了元素分析、红外光谱、粉末X射线衍射以及单晶X射线衍射表征.研究了影响其穿插与否的外界因素,结果表明,以DMF为溶剂的主要成分时,易得到非穿插结构,DMF可能在结构形成中起着模板剂的作用.另外,还对两种异构体进行了结构比较,对非穿插结构进行了热稳定性分析.
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