α-磷酸氢锆α-Zr(HPO4)2·H2O是一类典型的层状结构的多功能材料,本文首次报道了非芳香杂环化合物六氢吡啶对α-ZrP的插层反应.用元素分析,红外光谱(IR)、X射线粉末衍射(XRD)和TG-DSC热分析对α-ZrP的插层复合物α-ZrP-HHP进行了表征.研究表明,六氢吡啶的插入使层间距增大0.59nm,插入的六氢吡啶客体分子在主体底物中形成双层分子,一个α-ZrP分子刚好接受一个六氢吡啶分子.
α-zirconium hydrogen phosphate(α-ZrP) is layered and multi-functional materials. The intercalation reaction of nonaromatic heterocyclic compound hexahydropyridine (abbreviated HHP) into α-ZrP was reported for the first time. The intercalation complex α-ZrP-HHP was characterized with element analysis, IR, XRD and TG-DSC thermo-analysis. The interlayer distance of α-ZrP-HHP was 0.59nm larger than that of α-ZrP. The HHP is arranged as Bi-molecule layer within the interlayer space of α-ZrP, and a α-ZrP molecule accepts a HHP molecule.
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