Airbum reaction and carboxy reaction result in the excess consumption of carbon anode in aluminum electrolysis.To reduce the excess carbon consumption, carbon anode was doped with aluminum-containing additives, such as Al, Al4C3,AlF3 and Al2O3. Their reactivity in air and CO2 was determined with an isothermal-gravimetric method to study the effect of aluminum-containing additives on the reactivity in air and CO2 of carbon anode. Results shown that the airburn reactivity at 450℃ and carboxy reactivity at 970 ℃ of carbon anode both decreased with Al-containing additives adding, while shown a minimutn with the amount of Al4C3, AlF3 and Al2O3 increasing. However, all Al-containing additives increase the airbum reactivity at 550℃ of carbon anodes. Coke yield measurement and XRD examination with aluminum containing additives doped pitch cokes revealed that the effect of Al-containing additives on the airbum reactivity and carboxy reactivity of carbon anode would result from chemical factors and structural factors.
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