少层(1～5层)大面积均匀石墨烯的可控制备,是实现石墨烯在逻辑器件和透明导电电极中使用的关键.本工作使用常压化学气相沉积(CVD)方法,在铜镍合金基底上生长出少数层大面积均匀石墨烯.通过调节铜镍合金的厚度以及控制生长过程中的温度、时间、碳源浓度,本工作实现了层数可控石墨烯的制备.光学显微术、拉曼光谱、紫外可见吸收光谱、高分辨率透射电镜表征结果表明:制备出的石墨烯是大面积均匀的高质量少层石墨烯.
参考文献
| [1] | Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].SCIENCE,2004,306(5296):666-669. |
| [2] | Castro Neto, AH;Guinea, F;Peres, NMR;Novoselov, KS;Geim, AK .The electronic properties of graphene[J].Reviews of Modern Physics,2009(1):109-162. |
| [3] | Mayorov, A.S.;Gorbachev, R.V.;Morozov, S.V.;Britnell, L.;Jalil, R.;Ponomarenko, L.A.;Blake, P.;Novoselov, K.S.;Watanabe, K.;Taniguchi, T.;Geim, A.K. .Micrometer-scale ballistic transport in encapsulated graphene at room temperature[J].Nano letters,2011(6):2396-2399. |
| [4] | Changgu Lee;Xiaoding Wei;Jeffrey W. Kysar;James Hone .Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J].Science,2008(5887):385-388. |
| [5] | Alexander A. Balandin .Thermal properties of graphene and nanostructured carbon materials[J].Nature materials,2011(8):569-581. |
| [6] | Nair RR;Blake P;Grigorenko AN;Novoselov KS;Booth TJ;Stauber T;Peres NM;Geim AK .Fine structure constant defines visual transparency of graphene.[J].Science,2008(5881):1308-1308. |
| [7] | Yanqing Wu;Yu-ming Lin;Ageeth A. Bol;Keith A. Jenkins;Fengnian Xia;Damon B. Farmer;Yu Zhu;Phaedon Avouris .High-frequency, scaled graphene transistors on diamond-like carbon[J].Nature,2011(Apr.7 TN.7341):74-78. |
| [8] | Noejung Park;Suklyun Hong;Gyubong Kim .Computational Study of Hydrogen Storage Characteristics of Covalent-Bonded Graphenes[J].Journal of the American Chemical Society,2007(29):8999-9003. |
| [9] | Heo C;Yoo J;Lee S;Jo A;Jung S;Yoo H;Lee YH;Suh M .The control of neural cell-to-cell interactions through non-contact electrical field stimulation using graphene electrodes.[J].Biomaterials,2011(1):19-27. |
| [10] | Bonaccorso, F.;Sun, Z.;Hasan, T.;Ferrari, A.C. .Graphene photonics and optoelectronics[J].Nature photonics,2010(9):611-622. |
| [11] | Novoselov K S;Falko V I;Colombo L et al.A roadmap for graphene[J].NATURE,2012,490:192-200. |
| [12] | Berger, C;Song, ZM;Li, XB;Wu, XS;Brown, N;Naud, C;Mayo, D;Li, TB;Hass, J;Marchenkov, AN .Electronic confinement and coherence in patterned epitaxial graphene[J].Science,2006(5777):1191-1196. |
| [13] | Li X S;Cai W W;An J H et al.Large-area synthesis of highquality and uniform graphene films on copper foils[J].SCIENCE,2009,324(5932):1312-1314. |
| [14] | Bae, S.;Kim, H.;Lee, Y.;Xu, X.;Park, J.-S.;Zheng, Y.;Balakrishnan, J.;Lei, T.;Ri Kim, H.;Song, Y.I.;Kim, Y.-J.;Kim, K.S.;?zyilmaz, B.;Ahn, J.-H.;Hong, B.H.;Iijima, S. .Roll-to-roll production of 30-inch graphene films for transparent electrodes[J].Nature nanotechnology,2010(8):574-578. |
| [15] | Keun Soo Kim;Yue Zhao;Houk Jang;Sang Yoon Lee;Jong Min Kim;Kwang S. Kim;Jong-Hyun Ann;Philip Kim;Jae-Young Choi;Byung Hee Hong .Large-scale Pattern Growth Of Graphene Films For Stretchable Transparent Electrodes[J].Nature,2009(7230):706-710. |
| [16] | An H;Lce W-J;Jung J .Graphene synthsis on Fe foil using thermal CVD[J].APPLIED PHYSICS,2011,11:S81-S85. |
| [17] | Ramón, M.E.;Gupta, A.;Corbet, C.;Ferrer, D.A.;Movva, H.C.P.;Carpenter, G.;Colombo, L.;Bourianoff, G.;Doczy, M.;Akinwande, D.;Tutuc, E.;Banerjee, S.K. .CMOS-compatible synthesis of large-area, high-mobility graphene by chemical vapor deposition of acetylene on cobalt thin films[J].ACS nano,2011(9):7198-7204. |
| [18] | Gao, T.;Xie, S.;Gao, Y.;Liu, M.;Chen, Y.;Zhang, Y.;Liu, Z. .Growth and atomic-scale characterizations of graphene on multifaceted textured Pt foils prepared by chemical vapor deposition[J].ACS nano,2011(11):9194-9201. |
| [19] | Vo-Van C;Kimouche A;Reserbat-Plantey A et al.Epitaxial graphene prepared by chemical vapor deposition on single crystal thin iridium films on sapphire[J].Applied Physics Letters,2011,98(181903) |
| [20] | Oznuluer T;Pince E;Polat E O;Balci O,Salihoglu O,Kocabas C .Synthesis of graphene on gold[J].Applied Physics Letters,2011,98(183101) |
| [21] | Wang G;Zhang M;Zhu Y et al.Direct growth of graphene film on germanium substrate[J].Scientific Reports,2013,3:2465. |
| [22] | Li, X.;Magnuson, C.W.;Venugopal, A.;Tromp, R.M.;Hannon, J.B.;Vogel, E.M.;Colombo, L.;Ruoff, R.S. .Large-area graphene single crystals grown by low-pressure chemical vapor deposition of methane on copper[J].Journal of the American Chemical Society,2011(9):2816-2819. |
| [23] | Li X;Cai W;Colombo L;Ruoff R S .Evolution of graphene on Ni and Cu by carbon isotope labeling[J].Nano Letters,2009,9:4268-4272. |
| [24] | Yu Q K;Lian J;Sujitra S;Li H Chen Y P Pei S S .[J].Applied Physics Letters,2008,93:113103. |
| [25] | Liu, N.;Fu, L.;Dai, B.;Yan, K.;Liu, X.;Zhao, R.;Zhang, Y.;Liu, Z. .Universal segregation growth approach to wafer-size graphene from non-noble metals[J].Nano letters,2011(1):297-303. |
| [26] | Gong Y P;Zhang X M;Liu G D et al.Layer-controlled and wafer-scale synthesis of uniform and high-quality graphene films on a polycrystalline nickel catalyst[J].Advanced Functional Materials,2012,22:3153-3159. |
| [27] | Zhang Y;Lewis G;Fumiaki N I et al.Comparison of graphene growth on single-crystalline and polycrystalline Ni by chemical vapor deposition[J].J Phys Chem Lett,2010,1(20):3101-3107. |
| [28] | Lewis, A.M.;Derby, B.;Kinloch, I.A. .Influence of gas phase equilibria on the chemical vapor deposition of graphene[J].ACS nano,2013(4):3104-3117. |
| [29] | Vlassiouk, I.;Regmi, M.;Fulvio, P.;Dai, S.;Datskos, P.;Eres, G.;Smirnov, S. .Role of hydrogen in chemical vapor deposition growth of large single-crystal graphene[J].ACS nano,2011(7):6069-6076. |
| [30] | Zhang, Y.;Li, Z.;Kim, P.;Zhang, L.;Zhou, C. .Anisotropic hydrogen etching of chemical vapor deposited graphene[J].ACS nano,2012(1):126-132. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%