以含氧乙基结构的烯类单体(Macromer)和丙烯酰胺(AM)为原料,制备了具有温度敏感性的疏水缔合水溶性共聚物P(AM-Macromer).研究了P(AM-Macromer)溶液与不同表面活性剂的相互作用.结果表明,P(AM-Macromer)在水溶液中与表面活性剂存在明显相互作用,复合效应与聚合物浓度、表面活性剂结构及浓度有关.在较高浓度聚合物溶液中,少量表面活性剂的加入能显著提高溶液的黏度;在低浓度聚合物溶液中,表面活性剂的加入使溶液表观黏度下降.表面活性剂对共聚物P(AM-Macromer)溶液黏度的影响强弱顺序为:SDBSCTABOP-10.
参考文献
| [1] | Zhang JH.;Tang J.;Zhang JY. .A modified method to detect surface rheological behavior of mixed partially hydrolyzed polyacrylamide (HPAM)/surfactant systems[J].Journal of Applied Polymer Science,2000(4):704-706. |
| [2] | KJONIKEN A L;NILSSON S .[J].Macromolecules,2000,33:877-886. |
| [3] | Sesta B.;Segre AL.;Proietti N.;Daprano A. .INFLUENCE OF THE POLYMER MOLECULAR WEIGHT ON THE SURFACTANT-POLYMER INTERACTIONS - LIPFN-PVP AND SDS-PVP SYSTEMS[J].Langmuir: The ACS Journal of Surfaces and Colloids,1997(25):6612-6617. |
| [4] | LOH W .[J].Journal of Physical Chemistry B,2004,108:3196-3201. |
| [5] | KATHRYN M .[J].Journal of Applied Polymer Science,2004,92:658-668. |
| [6] | SUGIHARA S J .[J].Journal of Polymer Science Part A:Polymer Chemistry,2003,41:3300-3312. |
| [7] | Ye L.;Huang RH.;Hoffman H. .Surfactant interactions with P(AM-AA-BPAM) hydrophobically modified polyelectrolytes[J].Journal of Applied Polymer Science,2003(10):2664-2671. |
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