Pd(Oac)2/[mmim]I催化体系胺氨化羰化合成氨基甲酸酯、脲和 2-(噁)唑啉酮

催化学报 , 2008, 29(7): 638-642.

Pd(Oac)2/[mmim]I催化体系胺氨化羰化合成氨基甲酸酯、脲和 2-(噁)唑啉酮

彭新高 ^1, , 李福伟 ^2, , 胡霄雪 ^3, , 夏春谷 ^4, , ^5,

1.中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州,730000

2.中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州,730000

3.中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州,730000

4.中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州,730000

5.中国科学院上海有机化学研究所有机金属国家重点实验室,上海,200032

基金项目: 国家自然科学基金(20533080;20625308)

关键词：钯 , 离子液体 , 胺 , 氧化羰化 , 氨基甲酸酯 , 脲 , 2-噁唑啉酮

A Pd(OAc)2/[mmim]I Catalyst System for Oxidative Carbonylation of Amines to Carbamates, Ureas, and 2-Oxazolidinones

采用Pd(Oac)2/[mmim]I催化体系,在不同反应条件下可以将烷基胺、芳香胺及氨基醇(酚)一步转化为氨基甲酸酯、脲和 2-口恶唑啉酮. N-苯基氨基甲酸甲酯、二苯基脲及苯并-2-口恶唑酮的催化转化频率分别为 12 417, 17 638 和 4 114 h-1.

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Pd(Oac)2/[mmim]I催化体系胺氨化羰化合成氨基甲酸酯、脲和 2-(噁)唑啉酮

A Pd(OAc)2/[mmim]I Catalyst System for Oxidative Carbonylation of Amines to Carbamates, Ureas, and 2-Oxazolidinones

参考文献