本文探讨了采用硬、软模板以及单分散HAP纳米晶组装制备介孔HAP的工艺、方法及材料的表征与分析方法;展望了通过优化合成工艺,制备孔径在数纳米至数十纳米范围可调,孔径分布窄、周期性好的三维孔道HAP介孔材料的最佳策略及其潜在的应用.
参考文献
| [1] | 刘羽,彭明生.磷灰石结构替换的研究进展[J].岩石矿物学杂志,2003(04):413-415. |
| [2] | Vecchio KS;Zhang X;Massie JB;Wang M;Kim CW .Conversion of bulk seashells to biocompatible hydroxyapatite for bone implants.[J].Acta biomaterialia,2007(6):910-918. |
| [3] | 牛宗伟,张建华,任升峰,李丽,徐明刚.羟基磷灰石人工骨研究进展与展望[J].硅酸盐通报,2004(06):71-74. |
| [4] | 曹献英,李世普,任卫,江昕,王友法,闫玉华.纳米羟基磷灰石的表征及其对肝癌抑制作用的研究[J].硅酸盐通报,2003(04):21-24. |
| [5] | 马鸿文.工业矿物与岩石[M].北京:化学工业出版社,2005:257-259. |
| [6] | Shen, SC;Chen, FX;Chow, PS;Phanapavudhikul, P;Zhu, KW;Tan, RBH .Synthesis of SBA-15 mesoporous silica via dry-gel conversion route[J].Microporous and Mesoporous Materials,2006(1/3):300-308. |
| [7] | Jianguo He;Kun Ma;Jun Jin .Preparation and characterization of octyl-modified ordered mesoporous carbon CMK-3 for phenol adsorption[J].Microporous and Mesoporous Materials,2009(1/3):173-177. |
| [8] | 刘超,成国祥.模板法制备介孔材料的研究进展[J].离子交换与吸附,2003(04):374-384. |
| [9] | 姜治平,江东亮,张景贤,林庆玲.非硅体系介孔材料的合成[J].化学进展,2008(10):1465-1473. |
| [10] | Díaz A;López T;Manjarrez J .Growth of hydroxyapatite in a biocompatible mesoporous ordered silica[J].Acta Materials,2006,2:173-179. |
| [11] | Zhou HS;Zhu SM;Honma I;Seki K .Methane gas storage in self-ordered mesoporous carbon (CMK-3)[J].Chemical Physics Letters,2004(4-6):252-255. |
| [12] | Fang B;Zhou H;Horuna I .Ordered porous carbon with tailored pore size for electrochemical hydrogen storage application[J].Journal of Physical Chemistry B,2006,110:4875-4880. |
| [13] | Jie Fan;Jie Lei;Chengzhong Yu;Bo Tu;Dongyuan Zhao .Hard-templating synthesis of a novel rod-like nanoporous calcium phosphate bioceramics and their capacity as antibiotic carriers[J].Materials Chemistry and Physics,2007(2/3):489-493. |
| [14] | Zhiguo Xia;Libing Liao;Senlin Zhao .Synthesis of mesoporous hydroxyapatite using a modified hard-templating route[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2009(8):1687-1691. |
| [15] | Jiang P;Bertone J F;Vicki L C et al.A lost-wax approach to monodisperse colloids and their crystals[J].Science,2001,291:453-457. |
| [16] | YueJun Tang;YueFeng Tang;ChunTang Lv;ZhongHua Zhou .Preparation Of Uniform Porous Hydroxyapatite Biomaterials By A New Method[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2008(17):5359-5362. |
| [17] | Xiaoming Sun;Yadong Li .Colloidal Carbon spheres and Their Core/Shell Structures with Noble-Metal Nanoparticles[J].Angewandte Chemie,2004(5):597-601. |
| [18] | Xiaoming Sun;Yadong Li .Ga_2O_3 and GaN Semiconductor Hollow Spheres[J].Angewandte Chemie,2004(29):3827-3831. |
| [19] | Xiao-Lin Li;Xiao-Ming Sun .Highly Sensitive W0_3 Hollow-Sphere Gas Sensors[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2004(17):5442-5449. |
| [20] | Mingbo Zheng;Jieming Cao;Xin Chang .Preparation of oxide hollow spheres by colloidal carbon spheres[J].Materials Letters,2006(24):2991-2993. |
| [21] | Xiaoming Sun;Junfeng Liu;Yadong Li .Use of Carbonaceous Polysaccharide Microspheres as Templates for Fabricating Metal Oxide Hollow Spheres[J].Chemistry: A European journal,2006(7):2039-2047. |
| [22] | 秦振平,郭红霞.模板法合成有序多孔材料研究进展[J].化工进展,2002(05):323-327. |
| [23] | Kresge C T;Leonowicz M E;Roth W J et al.Ordered mesoporous molecular sieves synthesized by a liquid crystal template mechanism[J].Nature,1992,359:710-712. |
| [24] | Jia Yao;Wiliana Tiandra;Yun Z.Chen;Kam C.Tam;Jan Ma;Bernard Soh .Hydroxyapatite nanostructure material derived using cationic surfactant as a template[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(12):3053-3057. |
| [25] | Hualin Wang;Linfeng Zhai;Yanhong Li;Tiejun Shi .Preparation of irregular mesoporous hydroxyapatite[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2008(6):1607-1614. |
| [26] | Li Y B;Wiliana Tjandra;Kam C Tam .Synthesis and characterization of nanoporous hydroxyapatite using cationic surfactants as templates[J].Materials Research Bulletin,2007,42:820-827. |
| [27] | Chao Liu;Xiujie Ji;Guoxiang Cheng .Template synthesis and characterization of highly ordered lamellar hydroxyapatite[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(16):6840-6843. |
| [28] | 高晓慧,杨儒,李敏.孔径可调的介孔磷酸铈的合成[J].北京化工大学学报（自然科学版）,2007(z2):65-68. |
| [29] | Yang Liu;Yan Li;YuntaoWang;Lei Xie;Jie Zheng;Xingguo Li .Sonochemical synthesis and photocatalytic activity of meso- and macro-porous TiO_2 for oxidation of toluene[J].Journal of hazardous materials,2008(1):153-157. |
| [30] | 王定胜,彭卿,李亚栋.单分散纳米晶的合成、组装及其介孔材料的制备[J].中国科学G辑,2008(11):1434-1454. |
| [31] | Murray C B;Norris D J;Bawendi M G .Synthesis and characterization of nearly monodisperse CdE (E = sulfur,selenium,tellurium) semiconductor nanocrystallites[J].Journal of the American Chemical Society,1993,115(19):8706-8715. |
| [32] | Xun Wang;Jing Zhuang;Qing Peng;Yadong Li .A general strategy for nanocrystal synthesis[J].Nature,2005(7055):121-124. |
| [33] | Xun Wang;Jing Zhuang;Qing Peng;Yadong Li .Liquid-Solid-Solution Synthesis of Biomedical Hydroxyapatite Nanorods[J].Advanced Materials,2006(15):2031-2034. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%