欢迎登录材料期刊网

材料期刊网

高级检索

通过添加聚乙烯醇( PVA)、二氧化硅( SiO2)到木薯淀粉中,采用熔融密炼法制备热塑性木薯淀粉( TPS)/PVA/SiO2共混材料,研究共混材料的吸水性、生物降解与熔融行为。研究结果表明:随着SiO2用量的增加, TPS/PVA/SiO2共混体系的吸水率增加, TPS/PVA (1799)/SiO2共混材料的吸水率高于 TPS/PVA (1788)/SiO2共混物。表面改性后SiO2的TPS/PVA/SiO2共混物的吸水率低于未改性SiO2。随着SiO2用量的增加,TPS/PVA/SiO2共混物的生物降解降低,共混物的熔融峰增高,而熔融焓降低。

The thermoplastic tapioca starch( TPS)/PVA/SiO2 blends were prepared through melt mixing meth-od,by adding polyvinyl alcohol(PVA),silica(SiO2)into cassava starch,and the water absorption,biodegradation, and melting behavior of the blends were investigated. The research results indicated that with the increase of SiO2 content,the water absorption of TPS/PVA/SiO2 blends increased,and the water absorption of TPS/PVA(1799)/SiO2 blends was higher than that of TPS/PVA(1788)/SiO2 blends. The water absorption of TPS/PVA/SiO2 blends with SiO2 surface treated was lower than that of the untreated SiO2. With the increase of the SiO2 content,the bio-degradation of TPS/PVA/SiO2 blends decreased,the melting peak of the blends increased,however the melting en-thalpy decreased.

参考文献

[1] 邱威扬,王飞镝,邱贤华,喻继文,陈云.淀粉塑料现状及发展前景[J].高分子通报,2000(04):77-82,95.
[2] Jong-Whan Rhim;Hwan-Man Park;Chang-Sik Ha .Bio-nanocomposites for food packaging applications[J].Progress in Polymer Science,2013(10/11):1629-1652.
[3] 纪敏,雷春堂,潘晓勇,王炼,周刚,陈伟,张亚萍,林晓艳.淀粉/PVA可生物降解塑料的研究进展[J].塑料工业,2012(07):5-8,43.
[4] A Study of Dynamic Mechanical and Thermal Behavior of Starch/Poly(vinylalcohol) Based Films[J].Journal of polymers and the environment,2009(1):49-55.
[5] 石璞,晋刚,吴宏武,瞿金平,何和智.纳米SiO2增强增韧聚丙烯的研究[J].中国塑料,2002(01):37-40.
[6] 张咏春;田明;张立群.二氧化硅制备改性应用进展[J].现代化工,1998(4):11-13.
[7] 郑贤,陈弦,何波兵.纳米SiO2对聚乙烯醇/淀粉熔融吹塑薄膜性能的影响[J].塑料科技,2012(05):77-80.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%