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采用电化学阻抗与能谱图研究了钼酸盐复合缓蚀剂在天然海水中的缓蚀机理。阻抗谱表明,该缓蚀剂通过增大金属表面的电荷转移电阻而降低电化学腐蚀速率;X射线光电子能谱(XPS)显示钼酸盐复合缓蚀剂在海水中的碳钢表面主要形成了Fe。O4、FezO3,以及三价铁与钼酸根和缓蚀剂中有机成分形成的有机铁络合物。能量谱(EDS)测试结果表明,添加了钼酸盐复合缓蚀剂的碳钢表面膜中钙元素含量很低(0.08%),表明缓蚀剂中具有阻垢性能的有机瞵酸盐(HEDP)和葡萄糖酸盐对海水中的Ca2+抖起络合分散作用,阻止了钙盐在金属表面的沉积,这也表明该缓蚀剂具有缓蚀性能的同时又具有良好的阻垢性能。

The corrosion inhibition mechanism of molybdate complex inhibition was studied in sea water by EIS and energy spectra. The results of electrochemical EIS testing showed that the corrosion rate decreased because the complex inhibitor increasing the charge transfer resistance of metal surface. The results of XPS showed that a compact protective passive film was formed on the surface of carbon steel in seawater. The main components of the film are FeaO4and Fe2Oa and a little Fe3+, MoO42- and organic substance. X-ray dispersive spectroscopy (EDS) testing showed that the calcium content in the film on carbon steel surface was very low when addintion of the compound inhibitor was only 0. 08%, indicating that the complexation and dispersion of organic phosphate (HEDP) and sodium gluconate on Ca2+ in seawater impeded the deposition of calcium on metal surface. It also showed that the complex corrosion inhibitor had ~:ood scale inhibition nerforrnance

参考文献

[1] 杜敏,高荣杰,公萍.海水介质中缓蚀剂研究的回顾和展望[J].材料保护,2002(03):7-10.
[2] 邵丽艳,周玉波,李言涛,侯保荣,于志刚.绿色海水缓蚀剂的研究进展[J].海洋科学,2005(07):84-86.
[3] 芮玉兰,路迈西,梁英华,魏应利.钼酸盐复合缓蚀剂对海水中碳钢的缓蚀作用[J].腐蚀与防护,2007(02):61-64.
[4] 郭新民.钼酸钠-葡萄糖酸钠协同缓蚀效应的研究[J].陕西化工,1991(04):14-16.
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