在273.15～353.15K范围内测定了[BMIM]ClO4离子液体的密度和表面张力.根据Glasser理论讨论了该离子液体的热力学性质,估算出其晶格能和标准熵.根据离子液体的空隙模型计算了离子液体的恒压热膨胀系数α=6.27×l0-4K-1,与实验值α=5.46×10-4K-1基本一致.
参考文献
| [1] | Yang JZ;Lu XM;Gui JS;Xu WG .A new theory for ionic liquids - the Interstice Model Part 1. The density and surface tension of ionic liquid EMISE[J].Green chemistry,2004(11):541-543. |
| [2] | Maciej Galinski;Andrzej Lewandowski;Izabela Stepniak .Ionic liquids as electrolytes[J].Electrochimica Acta,2006(26):5567-5580. |
| [3] | 柳泉,刘奎仁,韩庆,涂赣峰.苯基TMPAC-AlCl3离子液体电镀铝研究[J].东北大学学报（自然科学版）,2010(08):1149-1152. |
| [4] | Gao, H.;Zhang, Y.;Wang, H.-J.;Liu, J.;Chen, J. .Theoretical study on the structure and cation-anion interaction of amino acid cation based amino acid ionic liquid [Pro]~+[NO_3] ~-[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2010(37):10243-10252. |
| [5] | Bandrés I;Pera G;Martín S et al.Thermophysical study of 1-butyl-2-methylpyridinium tetrafluoroborate ionic liquid[J].Journal of Physical Chemistry B,2009,113(35):11936. |
| [6] | Jing Tong;Qing-Shan Liu;Wei Guan .Studies on Volumetric Properties of Concentrated Aqueous Amino Acid Ionic Liquid [C3mim][Glu][J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2009(3):1110-1114. |
| [7] | Qing-Guo Zhang;Ke-Di Cai;Zhcn-Xing Jin .Enthalpy of Solution of the Amino Acid Ionic Liquid 1-Butyl-3-methylimidazolium Glutamine[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2010(9):4044-4047. |
| [8] | Krossing I et al.Semi-empirical methods to predict the physical properties of ionic liquids:An overview of recent developments[J].Physical Chemistry,2006,220(10-11):1343. |
| [9] | Yang JZ;Zhang QG;Wang B;Tong J .Study on the properties of amino acid ionic liquid EMIGly[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(45):22521-22524. |
| [10] | Wei Guan;Jing Tong;San-Ping Chen .Density and Surface Tension of Amino Acid Ionic Liquid 1-Alkyl-3-methylimidazolium Glutamate[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2010(9):4075-4079. |
| [11] | WANG Xiao-dan,WU Wen-yuan,TU Gan-feng,JIANG Kai-xi.Synthesis and physico-chemical properties of new green electrolyte 1-butyl-3-methylimidazolium perchlorate[J].中国有色金属学报（英文版）,2010(10):2032-2036. |
| [12] | Lide D R.Handbook of chemistry and physics[M].Boca Raton:crc Press,2001:6. |
| [13] | 魏颖,张庆国.锌基离子液体BMIZn2Cl5的性质研究[J].化学学报,2008(16):1879-1883. |
| [14] | Zhang QG;Wei Y .Study on properties of ionic liquid based on ZnCl2 with 1-butyl-3-methylimidazolium chloride[J].The Journal of Chemical Thermodynamics,2008(4):640-644. |
| [15] | 杨家振,桂劲松,吕兴梅,张庆国,李华为.离子液体BMIBF4性质的研究[J].化学学报,2005(07):577-580. |
| [16] | 佟静,张庆国,洪梅,杨家振.铝基离子液体BMIAlCl4的热力学性质[J].物理化学学报,2006(01):71-75. |
| [17] | Glasser L .Lattice and phase transition thermodynamics of ionic liquids[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2004(1/2):87-93. |
| [18] | Adamson A W.Physical chemistry of surfaces[M].New York:John Wiley and Sons,Inc,1976:57. |
| [19] | 黄子卿.电解质溶液理论导论[M].北京:科学出版社,1983:40. |
| [20] | Rebelo L P N;Canongia L;Esperanca J et al.On the critical temperature,normal boiling point,and vapor pressure of ionic liquids[J].Journal of Physical Chemistry B,2005,109(13):6040. |
| [21] | Zhang Q G;Yang J Z;Lu X M et al.Studies on an ionic liquid based on FeCl3 and its properties[J].Fluid Phase Equilibria,2004,226(10):207. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%