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采用可溶性盐复分解法进行碳酸钙合成影响因素及其机理的研究.以正交试验法对合成温度、pH值、反应物浓度在碳酸钙合成中的影响进行探索,验证了温度以及pH值在合成反应中对产物晶型、形貌以及尺度有显著影响;使用周期键链理论(PBC)讨论了碳酸钙晶体方解石/文石共生现象;研究观察Mg2+对碳酸钙合成的影响,Mg2+作为能够稳定无定形碳酸钙前驱体(ACC)的金属离子,大量存在时碳酸钙形貌随nMg/nCa增大而变化,同时颗粒尺度变小.

参考文献

[1] 刘飞生,曹清.纳米碳酸钙的制备及用途[J].科技创新导报,2009(07):56-56.
[2] 杨小红,陈建兵,盛敏钢.纳米碳酸钙的生产和用途[J].化学教育,2007(10):5-7.
[3] 魏绍东,李全伟,王玉倩.纳米碳酸钙的制备技术与工业生产[J].化工中间体,2007(02):14-19.
[4] Grassmann O;Lobmann P .Biomimetic nucleation and growth of CaCO(3) in hydrogels incorporating carboxylate groups.[J].Biomaterials,2004(2):277-282.
[5] Wang Z;Li X;Li .Effects of inorganic polyphosphate on bone sialoprotein gene expression.[J].Gene: An International Journal Focusing on Gene Cloning and Gene Structure and Function,2010(2):79-86.
[6] Hong Xu;Binrui Cao;Anne George .Self-Assembly and Mineralization of Genetically Modifiable Biological Nanofibers Driven by β-Structure Formation[J].Biomacromolecules,2011(6):2193-2199.
[7] Singh, V.;Singh, S.K.;Pandey, S.;Sanghi, R. .Synthesis and characterization of guar gum templated hybrid nano silica[J].International Journal of Biological Macromolecules: Structure, Function and Interactions,2011(2):233-240.
[8] Katta J Reddy;Sanil John;Hollis Weber et al.Simultaneous capture and mineralization of coal combustion flue gas carbon dioxide (CO2)[J].Energy Procedia,2011,27(02):1574.
[9] Mignardi S;De Vito C;Ferrini V et al.The efficiency of CO2 sequestration via carbonate mineralization with simulated wastewaters of high salinity[J].J Hazardo Mater,2011,191(03):49.
[10] 胡克伟 .文石型碳酸钙晶须制备工艺及其形成机理研究[D].成都理工大学,2006.
[11] 岳林海,金达莱.两亲PS-b-PAA共聚物水溶液中球形碳酸钙复合物的合成及其热分解性质[J].科学通报,2004(01):61-64.
[12] 岳林海,金达莱,徐铸德.共沉淀法合成复合碳酸钙及其形貌和晶型的研究[J].化学学报,2003(10):1587-1591.
[13] 聂秋林,郑遗凡,岳林海,李国华,马坚祥,徐铸德.PVP为模板控制合成球形碳酸钙[J].无机化学学报,2003(04):445-448.
[14] Stashans, A.;Chamba, G. .A new insight on the role of Mg in calcite[J].International Journal of Quantum Chemistry,2011(10):2436-2443.
[15] 蒋良俊.矿物学(下册)[M].北京:冶金工业出版社,1960:317.
[16] 赵春霞,满瑞林,余嘉耕,陈爱四,王华苗.纳米碳酸钙的晶形控制及机理研究[J].中国粉体技术,2003(02):34-37.
[17] Roberto, M.F.;Marco, B.;Dino, A. .Effect of the surface relaxation on the theoretical equilibrium shape of calcite. 1. the [001] zone[J].Crystal growth & design,2010(9):4096-4100.
[18] Aquilano D.;Catti M.;Pavese A.;Rubbo M. .THEORETICAL EQUILIBRIUM AND GROWTH MORPHOLOGY OF CACO3 POLYMORPHS .1. ARAGONITE[J].Journal of Crystal Growth,1997(1/2):168-184.
[19] Aquilano, D.;Bruno, M.;Massaro, F.R.;Rubbo, M. .Theoretical equilibrium shape of calcite. 2. [4?41] zone and its role in biomineralization[J].Crystal growth & design,2011(9):3985-3993.
[20] 陈华雄,宋永才.文石晶须制备中氯化镁的影响[J].硅酸盐学报,2003(10):940-944.
[21] 李纠,陈华雄.以氯化镁为晶型控制剂制备碳酸钙晶须[J].硅酸盐学报,2005(09):1153-1156.
[22] 马俊,刘华彦,陈银飞.针状碳酸钙制备中氯化镁晶型导向剂的套用研究[J].无机材料学报,2011(11):1199-1204.
[23] Lia Addadi;Sefi Raz;Steve Weiner .Taking Advantage of Disorder: Amorphous Calcium Carbonate and Its Roles in Biomineralization[J].Advanced Materials,2003(12):959-970.
[24] Aizenberg J.;Lambert G.;Weiner S.;Addadi L. .Factors involved in the formation of amorphous and crystalline calcium carbonate: A study of an ascidian skeleton[J].Journal of the American Chemical Society,2002(1):32-39.
[25] 官叶斌,姚奇志,周根陶.含水非晶碳酸钙的仿生矿化研究[J].高校地质学报,2011(01):46-52.
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