欢迎登录材料期刊网

材料期刊网

高级检索

镁/铝合金表面转化膜在成膜过程中由于存在剧烈的析氢反应以及成膜结束后的失水收缩现象,导致该种转化膜存在结构疏松、连续性差、结合力低等缺点。从转化膜成膜机制角度出发结合3种主要的失效现象(局部损伤、失水收缩致开裂以及结构疏松导致的脱落),对其失效机理进行详细阐述。同时基于这3种失效机理,简明扼要地介绍目前针对这3个方面所采取的损伤修复、转化膜致密化以及界面结合力增强方面转化膜成膜工艺优化的研究进展,并对转化膜后续发展进行展望。

In the formation process of the conversion film on the surface of magnesium/aluminum alloy, severe hydrogen evolution reaction and water shrinkage at the end of the film formation, which leads to several disadvantages in the conversion coating such as loose structure, poor continuity and low adhesive force. From the perspective of conversion coating film formation mechanism, combining with three kinds of failure phenomenon (partial damage, conversion coating cracking and loose structure), these three failure mechanisms were reviewed. And the progresses of formation process optimization of conversion coating film including self-healing, densification of conversion coating and enhancement of interface binding force were presented briefly. The development trend of conversion coating was also discussed.

参考文献

[1] 金和喜;王日初;彭超群;冯艳;石凯;陈彬.镁合金表面化学转化膜研究进展[J].中国有色金属学报,2011(9):2049-2059.
[2] 曾荣昌;孔令鸿;陈君;崔洪芝;刘成龙.医用镁合金表面改性研究进展[J].中国有色金属学报,2011(1):35-43.
[3] 曾荣昌;兰自栋;陈君;莫鲜花;韩恩厚.镁合金表面化学转化膜的研究进展[J].中国有色金属学报,2009(3):397-404.
[4] X. B. Chen;N. Birbilis;T. B. Abbott.Review of Corrosion-Resistant Conversion Coatings for Magnesium and Its Alloys[J].Corrosion: The Journal of Science and Engineering,20113(3):035005:1-035005:16.
[5] Masanari Tomozawa;Sachiko Hiromoto.Microstructure of hydroxyapatite- and octacalcium phosphate-coatings formed on magnesium by a hydrothermal treatment at various pH values[J].Acta materialia,20111(1):355-363.
[6] Zhao M;Wu SS;Luo JR;Fukuda Y;Nakae H.A chromium-free conversion coating of magnesium alloy by a phosphate-permanganate solution[J].Surface & Coatings Technology,200618/19(18/19):5407-5412.
[7] 吴超云;张津.基于专利文献的镁合金腐蚀与防护技术的最新进展[J].中国有色金属学报(英文版),2011(4):892-902.
[8] 王昊;安成强;郝建军;林雪;陈梨.铝及铝合金无铬钝化的研究进展[J].电镀与环保,2014(1):1-3.
[9] Abdel Salam Hamdy;I. Doench;H. Moehwald.Intelligent self-healing corrosion resistant vanadia coating for AA2024[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,20115(5):1668-1678.
[10] Abdel Salam Hamdy;D. P. Butt.Novel anti-corrosion nano-sized vanadia-based thin films prepared by sol-gel method for aluminum alloys[J].Journal of Materials Processing Technology,200726(26):76-80.
[11] Abdel Salam Hamdy;I. Doench;H. Mohwald.Assessment of a one-step intelligent self-healing vanadia protective coatings for magnesium alloys in corrosive media[J].Electrochimica Acta,20115(5):2493-2502.
[12] Niu, Liyuan;Chang, Shiuan-Ho;Tong, Xian;Li, Guangyu;Shi, Zimu.Analysis of characteristics of vanadate conversion coating on the surface of magnesium alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2014:214-218.
[13] Livage J..SOL-GEL CHEMISTRY AND ELECTROCHEMICAL PROPERTIES OF VANADIUM OXIDE GELS[J].Solid state ionics,19962(2):935-942.
[14] Zhongli Zou;Ning Li;Deyu Li.A vanadium-based conversion coating as chromate replacement for electrogalvanized steel substrates[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20112(2):503-507.
[15] Dabala M.;Brunelli K.;Napolitani E.;Magrini M..Cerium-based chemical conversion coating on AZ63 magnesium alloy[J].Surface & Coatings Technology,20032/3(2/3):227-232.
[16] C. F. Malfatti;T. L. Menezes;C. Radtke;J. Esteban;F. Ansart;J. P. Bonino.The influence of cerium ion concentrations on the characteristics of hybrid films obtained on AA2024-T3 aluminum alloy[J].Materials and Corrosion,20129(9):819-827.
[17] KIYOTA Sayuri;VALDEZ Benjamin;STOYTCHEVA Margarita;ZLATEV Roumen;BASTIDAS Jose Maria.Anticorrosion behavior of conversion coatings obtained from unbuffered cerium salts solutions on AA6061-T6[J].稀土学报(英文版),2011(10):961-968.
[18] Yoganandan, G.;Premkumar, K. Pradeep;Balaraju, J. N..Evaluation of corrosion resistance and self-healing behavior of zirconium-cerium conversion coating developed on AA2024 alloy[J].Surface & Coatings Technology,2015:249-258.
[19] 雷黎;王昕;徐海港.镁合金铈转化膜在NaCl溶液中的腐蚀行为及腐蚀机理[J].中国有色金属学报,2015(1):125-132.
[20] F. Andreatta;H. Terryn;J. H. W. de Wit.Corrosion behaviour of different tempers of AA7075 aluminium alloy[J].Electrochimica Acta,200417/18(17/18):2851-2862.
[21] M.K. Cavanaugh;R.G. Buchheit;N. Birbilis.Evaluation of a simple microstructural-electrochemical model for corrosion damage accumulation in microstructurally complex aluminum alloys[J].Engineering Fracture Mechanics,20095(5):641-650.
[22] Amitha Rani;Durga Somaiah;Megha;Mitalee Poddar.Scratch Cell Test: A Simple, Cost Effective Screening Tool to Evaluate Self-Healing in Anti-Corrosion Coatings[J].Journal of Materials Engineering and Performance,20149(9):3328-3335.
[23] Wei, Huige;Wang, Yiran;Guo, Jiang;Shen, Nancy Z.;Jiang, Dawei;Zhang, Xi;Yan, Xingru;Zhu, Jiahua;Wang, Qiang;Shao, Lu;Lin, Hongfei;Wei, Suying;Guo, Zhanhu.Advanced micro/nanocapsules for self-healing smart anticorrosion coatings[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20152(2):469-480.
[24] 徐洛民;王昕;雷黎;左轲.AZ31镁铝合金铈盐转化膜的致密化处理[J].中国有色金属学报,2013(11):3135-3140.
[25] 张春艳;柳歆鹏;黄佳祈;刘成龙;杨惠;杨有利.镁合金表面氟转化层降解过程的电化学阻抗谱[J].中国有色金属学报,2015(2):401-407.
[26] 陈东初;吴建锋;梁奕清;叶树林;李文芳.添加剂作用下制备环境友好型铈基镁合金稀土转化膜[J].中国有色金属学报(英文版),2011(8):1905-1910.
[27] Cerium conversion coatings for AZ91D magnesium alloy in ethanol solution and its corrosion resistance[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,200912(12):2916.
[28] Corrosion behaviour of chemical conversion treatments on as-cast Mg-Al alloys: Electrochemical and non-electrochemical methods[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,20106(6):p.2172.
[29] Hassan H. Elsentriecy;Kazuhisa Azumi;Hidetaka Konno.Effects of pH and temperature on the deposition properties of stannate chemical conversion coatings formed by the potentiostatic technique on AZ91 D magnesium alloy[J].Electrochimica Acta,200812(12):4267-4275.
[30] Cui, Xiufang;Liu, Zhe;Lin, Lili;Jin, Guo;Wang, Haidou;Xu, Binshi.Investigation of Carboxylic Acid-Neodymium Conversion Films on Magnesium Alloy[J].Journal of Materials Engineering and Performance,20151(1):461-467.
[31] Guo Jin;Yuyun Yang;Xiufang Cui;Erbao Liu;Zhongyu Wang;Qingfen Li.Chrome-free neodymium-based protective coatings for magnesium alloys[J].Materials Letters,20118(8):1145-1147.
[32] D. Petrov;B. Angelov.Preparation and characterisation of NdAlO3 nanocrystals by modified sol-gel method[J].Journal of Sol-Gel Science and Technology,20102(2):227-231.
[33] Wojciech Simka.Preliminary investigations on the anodic oxidation of Ti-13Nb-13Zr alloy in a solution containing calcium and phosphorus[J].Electrochimica Acta,201127(27):9831-9837.
[34] Valanezhad, A.;Tsuru, K.;Maruta, M.;Kawachi, G.;Matsuya, S.;Ishikawa, K..A new biocompatible coating layer applied on titanium substrates using a modified zinc phosphatizing method[J].Surface & Coatings Technology,20128/9(8/9):2207-2212.
[35] Ming Zhao;Jianguo Li;Guangping He;Honglan Xie;Yanan Fu.An investigation of the effect of a magnetic field on the phosphate conversion coating formed on magnesium alloy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013Oct.1(Oct.1):499-505.
[36] Xuexin Wang;Shu Cai;Tielong Liu.Fabrication and corrosion resistance of calcium phosphate glass-ceramic coated Mg alloy via a PEG assisted sol-gel method[J].CERAMICS INTERNATIONAL,20142(2):3389-3398.
[37] Ren, M.;Cai, S.;Xu, G.;Ye, X.;Dou, Y.;Huang, K.;Wang, X..Influence of heat treatment on crystallization and corrosion behavior of calcium phosphate glass coated AZ31 magnesium alloy by sol-gel method[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2013:69-75.
[38] C.T. Dervos;J. Novakovic;P. Vassiliou.Vacuum heat treatment of electroless Ni-B coatings[J].Materials Letters,20045(5):619-623.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%