本文采用水热法成功的合成了纯ZnO和ZnO: Cd纳米棒.借助扫描电子显微镜、X射线衍射仪等研究了纯ZnO和ZnO: Cd的形貌、结构及性质.结果表明,合成的纯ZnO和ZnO: Cd均呈六角纤锌矿纳米棒结构,Cd的掺入使得纳米棒尺寸减小、品格发生膨胀.合成材料制成的薄膜型气敏传感器对氢气的敏感性研究表明,纯ZnO薄膜器件对氢气几乎不敏感,而ZnO: Cd薄膜器件灵敏度较高.当工作温度为220℃时,ZnO: Cd薄膜器件对浓度为250ppm的氢气灵敏度达到3.95,且具有良好的可重复性.
参考文献
| [1] | J. M. Bian;X. M. Li;X. D. Gao;W. D. Yu;L. D. Chen.Deposition and electrical properties of N-In codoped p-type ZnO films by ultrasonic spray pyrolysis[J].Applied physics letters,20044(4):541-543. |
| [2] | Huijuan Zhou;Markus Wissinger;Johannes Fallert;Robert Hauschild;Felix Stelzl;Claus Klingshirn;Heinz Kalt.Ordered, uniform-sized ZnO nanolaser arrays[J].Applied physics letters,200718(18):181112-1-181112-3-0. |
| [3] | 金晶;张新夷;周映雪.Mn掺杂ZnO薄膜的软X射线发射光谱研究[J].无机材料学报,2012(3):296-300. |
| [4] | Chen, R.;Zou, C.;Bian, J.;Sandhu, A.;Gao, W..Microstructure and optical properties of Ag-doped ZnO nanostructures prepared by a wet oxidation doping process[J].Nanotechnology,201110(10):105706-1-105706-8. |
| [5] | Wang, MS;Cheng, XN;Yang, J.Controlled visible photoluminescence of ZnO thin films prepared by RF magnetron sputtering[J].Applied physics, A. Materials science & processing,20093(3):783-787. |
| [6] | A. Hosseinmardi;N. Shojaee;M. Keyanpour-Rad.A study on the photoluminescence properties of electrospray deposited amorphous and crystalline nanostructured ZnO thin films[J].CERAMICS INTERNATIONAL,20123(3):1975-1980. |
| [7] | 郑志远;陈铁锌;曹亮;韩玉岩;徐法强.MBE法生长ZnO纳米线阵列的结构和光学性能[J].无机材料学报,2012(3):301-304. |
| [8] | Rai, P.;Kim, Y.-S.;Song, H.-M.;Song, M.-K.;Yu, Y.-T..The role of gold catalyst on the sensing behavior of ZnO nanorods for CO and NO _2 gases[J].Sensors and Actuators, B. Chemical,20121(1):133-142. |
| [9] | Pandya, H.J.;Chandra, S.;Vyas, A.L..Integration of ZnO nanostructures with MEMS for ethanol sensor[J].Sensors and Actuators, B. Chemical,20121(1):923-928. |
| [10] | 陈同云;朱小华;储向峰;葛秀涛;董永平;叶明富.Cu2+掺杂ZnO纳米棒的制备及气敏性能研究[J].无机材料学报,2012(10):1089-1094. |
| [11] | 唐鑫;吕海峰;马春雨;赵纪军;张庆瑜.Cd掺杂纤锌矿ZnO电子结构的第一性原理研究[J].物理学报,2008(2):1066-1072. |
| [12] | Phan, D.-T.;Chung, G.-S..Surface acoustic wave hydrogen sensors based on ZnO nanoparticles incorporated with a Pt catalyst[J].Sensors and Actuators, B. Chemical,20121(1):341-348. |
| [13] | Chai, G.Y.;Lupan, O.;Rusu, E.V.;Stratan, G.I.;Ursaki, V.V.;Ontea, V.;Khallaf, H.;Chow, L..Functionalized individual ZnO microwire for natural gas detection[J].Sensors and Actuators, A. Physical,20121(1):64-71. |
| [14] | Karunakaran, C.;Vijayabalan, A.;Manikandan, G..Photocatalytic and bactericidal activities of hydrothermally synthesized nanocrystalline Cd-doped ZnO[J].Superlattices and microstructures,20123(3):443-453. |
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