三氧化钨(WO3)以其较窄的带隙,成为继二氧化钛(TiO2)之后颇具发展潜力的n型半导体光催化剂.本文采用水热合成法,通过调控反应参数,如原料组成、沉淀时间等,合成了不同形貌和晶型的WO3;采用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、傅里叶变换红外光谱(FT-IR)、氮气吸附-脱附(N2 adsorption-desorption)等表征了所合成的WO3产品,发现原料组成、沉淀时间等条件对WO3的晶型和形貌都有影响;研究了所合成的WO3产品去除水中亚甲基蓝染料污染物的性能,结果表明,所制备的WO3对水中亚甲基蓝具有较好的去除效果,去除率可达97%.
参考文献
[1] | Wold A .Photocatalytic properties of TiO2[J].Chemistry of Materials,1993,5(03):280-230. |
[2] | Gouvēa C A K;Wypycha F;Moraes S G et al.Semiconductor-assisted photocatalytic degradation of reactive dyes in aqueous solution[J].Chemosphere,2000,40(04):433-440. |
[3] | Wang Q;Chen CC;Zhao D;Ma WH;Zhao JC .Change of adsorption modes of dyes on fluorinated TiO2 and its effect on photocatalytic degradation of dyes under visible irradiation[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(14):7338-7345. |
[4] | Lu, F;Cai, WP;Zhang, YG .ZnO hierarchical micro/nanoarchitectures: Solvothermal synthesis and structurally enhanced photocatalytic performance[J].Advanced Functional Materials,2008(7):1047-1056. |
[5] | Clara Santato;Martine Ulmann;Jan Augustynski .Photoelectrochemical Properties of Nanostructured Tungsten Trioxide Films[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2001(5):936-940. |
[6] | Improved electrochromical properties of sol-gel WO_3 thin films by doping gold nanocrystals[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2010(8):2250. |
[7] | Zheng H D;Tachibana Y;Kalantar-zadeh K .Dye-sensitized solar cells based on WOs[J].Langmuir,2010,26(24):19148-19152. |
[8] | Luo J Y;Deng S Z;Tao Y T et al.Evidence of localized water molecules and their role in the gasochromic effect of WO3nanowire films[J].Journal of Physical Chemistry C,2009,113(36):15877-15881. |
[9] | Yingqiang Zhao;Junhui He;Mingqing Yang .Single crystal WO3 nanoflakes as quartz crystal microbalance sensing layer for ultrafast detection of trace sarin simulant[J].Analytica chimica acta,2009(2):120-126. |
[10] | Marco Righettoni;Antonio Tricoli;Sotiris E. Pratsinis .Si:WO_(3) Sensors for Highly Selective Detection of Acetone for Easy Diagnosis of Diabetes by Breath Analysis[J].Analytical chemistry,2010(9):3581-3587. |
[11] | Zhang, X.;Lu, X.;Shen, Y.;Han, J.;Yuan, L.;Gong, L.;Xu, Z.;Bai, X.;Wei, M.;Tong, Y.;Gao, Y.;Chen, J.;Zhou, J.;Wang, Z.L. .Three-dimensional WO_3 nanostructures on carbon paper: Photoelectrochemical property and visible light driven photocatalysis[J].Chemical communications,2011(20):5804-5806. |
[12] | R.S. Vemuri;K. Kamala Bharathi;S.K. Gullapalli .Effect of Structure and Size on the Electrical Properties of Nanocrystalline WO3 Films[J].ACS applied materials & interfaces,2010(9):2623-2628. |
[13] | Zhi-Gang Zhao;Masahiro Miyauchi .Nanoporous-Walled Tungsten Oxide Nanotubes as Highly Active Visible-Light-Driven Photocatalysts[J].Angewandte Chemie,2008(37):7051-7055. |
[14] | JUNGWON KIM;CHUL WEE LEE;WONYONG CHOI .Platinized WO3 as an Environmental Photocatalyst that Generates OH Radicals under Visible light[J].Environmental Science & Technology: ES&T,2010(17):6849-6854. |
[15] | Seongho Jeon;Kijung Yong .Morphology-controlled synthesis of highly adsorptive tungsten oxide nanostructures and their application to water treatment[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(45):10146-10151. |
[16] | Zhi-Gang Zhao;Zhi-Fu Liu;Masahiro Miyauchi .Nature-inspired construction, characterization, and photocatalytic properties of single-crystalline tungsten oxide octahedra[J].Chemical communications,2010(19):3321-3323. |
[17] | Riegel G;Bolton J R .Photocatalytic efficiency variability in TiO2 particles[J].Journal of Physical Chemistry,1995,99(12):4215-4224. |
[18] | Lee K;Seo W S;Park J T .Synthesis and optical properties of colloidal tungsten oxide nanorods[J].Journal of the American Chemical Society,2003,125(12):3408-3409. |
[19] | Shibuya M;Miyauchi M .Site-selective deposition of metal nanoparticles on aligned WO3 nanotrees for superhydrophilic thin films[J].Advanced Materials,2009,21(13):1373-1376. |
[20] | Xiaoying Wang .Flower-like tungsten oxide particles: Synthesis, characterization and dimethyl methylphosphonate sensing properties[J].Analytica chimica acta,2010(1):36-41. |
[21] | Xiufeng Zhao;Teresa L. Y. Cheung;Xitian Zhang .Facile Preparation of Strontium Tungstate and Tungsten Trioxide Hollow Spheres[J].Journal of the American Ceramic Society,2006(9):2960-2963. |
[22] | Zhenxuan Wang;Shuxue Zhou;Limin Wu .Preparation of Rectangular WO_3·H_2O Nanotubes Under Mild Conditions[J].Advanced functional materials,2007(11):1790-1794. |
[23] | Lu XF;Liu XC;Zhang WJ;Wang C;Wei Y .Large-scale synthesis of tungsten oxide nanofibers by electrospinning[J].Journal of Colloid and Interface Science,2006(2):996-999. |
[24] | Choi, HG;Jung, YH;Kim, DK .Solvothermal synthesis of tungsten oxide nanorod/nanowire/nanosheet[J].Journal of the American Ceramic Society,2005(6):1684-1686. |
[25] | Zhou L;Zou J;Yu MM;Lu P;Wei J;Qian YQ;Wang YH;Yu CZ .Green Synthesis of Hexagonal-Shaped WO3 center dot 0.33H(2)O Nanodiscs Composed of Nanosheets[J].Crystal growth & design,2008(11):3993-3998. |
[26] | Fernando C;Carlos F;Enrique L et al.Preparation of self-organized porous tungsten oxide using HFCVD technique[J].Materials Chemistry and Physics,2010,120(01):36-41. |
[27] | Zhu, J.;Wang, S.;Xie, S.;Li, H. .Hexagonal single crystal growth of WO_3 nanorods along a [110] axis with enhanced adsorption capacity[J].Chemical communications,2011(15):4403-4405. |
[28] | Julien Polleux;Alexander Gurlo;Nicolae Barsan;Udo Weimar;Markus Antonietti;Markus Niederberger .Template-Free Synthesis and Assembly of Single-Crystalline Tungsten Oxide Nanowires and their Gas-Sensing Properties[J].Angewandte Chemie,2006(2):261-265. |
[29] | Jinmin Wang;Eugene Khoo;Pooi See Lee .Synthesis, Assembly, and Electrochromic Properties of Uniform Crystalline WO3 Nanorods[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(37):14306-14312. |
[30] | Gu Z J;Zhai T Y;Gap B F et al.Controllable assembly of WO3 nanorods/nanowires into hierarchical nanostructures[J].Journal of Physical Chemistry B,2006,110(47):23829-23836. |
[31] | Lou XW.;Zeng HC. .An inorganic route for controlled synthesis of W18O49 nanorods and nanofibers in solution[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2003(20):6169-6171. |
[32] | Qin, Y.;Hu, M.;Zhang, J. .Microstructure characterization and NO_2-sensing properties of tungsten oxide nanostructures[J].Sensors and Actuators, B. Chemical,2010(1):339-345. |
[33] | Salmaoui, S;Sediri, F;Gharbi, N .Characterization of h-WO3 nanorods synthesized by hydrothermal process[J].Polyhedron: The International Journal for Inorganic and Organometallic Chemistry,2010(7):1771-1775. |
[34] | Han Y;Ying J Y .Generalized fluorocarbon-surfactant-mediated synthesis of nanoparticles with various mcsoporous structures[J].Angewandte Chemie International Edition,2005,44(02):288292. |
[35] | Zhang W X;Yang Z H;Wang X et al.Large-scale synthesis of b-MnO2 nanorods and their rapid and efficient catalytic oxidation of methylene blue dye[J].Catalysis Communications,2006,7(06):408-412. |
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