己内酰胺水解聚合过程存在3个主要反应:水解开环、缩聚和加聚,环状二聚体的水解与加聚反应和(单官能团酸)相对分子质量调节剂的反应等.对包括上述6个反应的聚合过程动力学模型用文献实验数据进行了验证,然后考察了各影响因素对数均聚合度和多分散性指数的影响.
参考文献
| [1] | Kumar A;Gupta S K .[J].Journal of Macromolecular Science:Reviews in Macromolecular Chemistry and Physics,1986,26(02):183-247. |
| [2] | Ahn YC .Effects of diffusional water removal and heat transfer in nylon 6 reactors[J].Polymer engineering and science,1997(2):484-493. |
| [3] | Tai K;Teranishi H;Arai Y et al.[J].Journal of Applied Polymer Science,1980,25:77-87. |
| [4] | Arai Y;Tai K;Teranishi H et al.[J].Polymer,1981,22(01):273. |
| [5] | Tai K;Arai Y;Tagawa T .[J].Journal of Applied Polymer Science,1982,27:731-736. |
| [6] | Tai K;Arai Y;Teranishi H et al.[J].Journal of Applied Polymer Science,1980,25:1789-1792. |
| [7] | 周美华;唐志廉;黄南熏 等.[J].化工学报,1992,43(03):376-383. |
| [8] | 林健 .[D].中国纺织大学,1996. |
| [9] | 谢建军;黄南熏;唐志廉.[J].合成纤维工业,1998(05):31. |
| [10] | Kruissink Ch A;Want G M;Staverman A J .[J].Journal of Polymer Science,1958,30:67-80; 81-104. |
| [11] | TANG Z L;LIN J;HUANG N X et al.[J].Die Angewandte Makromolekulare Chemie,1997,250:1-14. |
| [12] | Schaefgen J R;Flory P J .[J].Journal of the American Chemical Society,1948,70:2709-2718. |
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