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The microstructures of Fe-Mn-Ni-Cr steels with medium carbon and the effect of alloy ele- ments on them have been investigated by means of X-ray diffraction quantitative phase ana- lyses,metallography and hardness tests.The volume fraction of martensite in steels quenched at 1100℃ can be expressed as: f_M~(1100)=162.643-15.482Mn-7.36Ni-4.286(Cr+Mo+V) Based on this expression,the quasi-equilibrium microstructure diagram has been obtained.It is shown that the effect of Mn on the austenite stability is greater than that of Ni.The equiva- lent [Ni]=2.104Mn+Ni and equivalent [Cr]=Cr+Mo+V. The driving force for martensite transformation at M_s point has been calculated to he drastically decreased by element Mn.

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