机械合金化制备Mg-Ni合金氢化物电极材料的研究进展

无机材料学报, 2005, 20(1): 33-41.

机械合金化制备Mg-Ni合金氢化物电极材料的研究进展

乔玉卿 , 赵敏寿 , 朱新坚 , 曹广益

1.1. 燕山大学环境与化学工程系, 秦皇岛 066004

2. 2. 上海交通大学燃料电池研究室, 上海 200030

1.1. Department of Chemistry, Yanshan University, Qinhuangdao 066004, China

2. 2. Shanghai Jiaotong University, Shanghai 200030, China

关键词：机械合金化 , Mg-Ni based alloy , amorphous , nickel-metal hydride battery

Progress of Research on Preparation of Mg-Ni Based Alloy by Mechanical Alloying for Hydride Electrode Materials

QIAO Yu-Qing , ZHAO Min-Shou , ZHU Xin-Jian , CAO Guang-Yi

Keywords： mechanical alloying , Mg-Ni系合金 , 非晶态 , Ni/MH电池

Mg-Ni系合金作为一种重要的Ni/MH电池负极材料, 一直受到电池工作者的广泛重视. 本文对机械合金化方法制备Mg-Ni系合金作为Ni/MH电池氢化物电极材料的研究现状进行了全面介绍, 综述了Mg-Ni系合金的电化学性能、微观结构、吸放氢机理以及合金的制备方法, 如二元合金化、多元合金化、复合合金化、表面改性等, 并就机械合金化方法制备Mg-Ni系合金作为Ni/MH电池负极材料的研究前景进行了分析和展望.

Mg-Ni based alloy has always been paid much attention as important negative electrode materials for Ni/MH battery. Recent research progress in Mg-Ni based alloy by mechanical
alloying for Ni/MH battery hydride electrode materials was reviewed with its focus on the electrochemical performance, micro-structural
characteristics, mechanism of hydriding and dehydriding and the main methods in preparation and modification of Mg-Ni based alloy electrodes such as
Mg-Ni based binary alloys, ternary alloys, composite alloying and surface modifications. Also the main direction of studies on Mg-Ni based alloy by
mechanical alloying for Ni/MH battery negative electrode materials was proposed.

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