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对不饱和聚酯树脂粘合的人造石英石板材进行了人工紫外加速老化试验,通过显微观察其表面形态,比较色差值,并采用红外谱图分析,研究石英石板材的紫外老化情况。试验结果表明,四种类型的不饱和聚酯树脂石英石在经过500 h紫外照射后,表层都会出现不同程度的粉化现象。而FTIR谱图显示,树脂并没有出现明显的链降解,石英石板面的粉化应是石英粉与树脂的接合面在老化试验中发生分离,导致石英粉脱落。

The unsaturated polyester resin( UPR) artificial quartz stones were accelerated aging by UV radiation in this study. The microexamination was performed to observe the surface and compare the chromatisms. Further-more,infrared spectra analysis was carried out to investigate the degree of aging. Results showed that the surfaces of four types of UPR stones were efflorescent in different degrees after 500 h of UV irradiation. And FTIR spectrograms indicated that there is no obvious chain degradation of resins,the efflorescence of stones was due to that the quartz powder and resin were separated in the adjoining plane during aging test,leading to the falling out of quartz powder.

参考文献

[1] 黄杏芳,吴华忠.不饱和树脂人造石英石性能的研究[J].闽江学院学报,2012(05):120-123.
[2] 张小苹,周祝林.不饱和聚酯树脂在复合材料中的应用[J].纤维复合材料,2008(01):28-31.
[3] 张琦,黄故.不饱和聚酯基玻璃钢材料的紫外线老化研究[J].天津工业大学学报,2007(03):14-16.
[4] 沈开猷. 不饱和聚酯树脂及其应用[M]. 北京:化学工业出版社,2005:436-448.,2005.
[5] 国家技术监督局. GB/T 14522-2008机械工业产品用塑料、涂料、橡胶材料人工气候老化试验方法荧光紫外灯[S]. 北京:中国标准出版社,2008.,2008.
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