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本文研究了在O2/CO2气氛下石灰石的煅烧和烧结特性.结果表明,空气气氛下煅烧所得CaO的孔隙率和比表面积均较O2/CO2气氛下的大,但O2/CO2气氛下煅烧所得CaO具有更大的最可几孔径.石灰石在O2/CO2气氛下1000℃煅烧时的产物具有最大的比孔容积和比表面积,且石灰石煅烧产物CaO的比孔容积和比表面积均随气氛中CO2浓度的增加而下降,在低CO2浓度下下降较为迅速,而在高CO2浓度下下降逐渐趋于平缓.在延长相同烧结时间的情况下,O2/CO2气氛下CaO孔结构受烧结影响的程度要比空气气氛下轻微.

参考文献

[1] Fuertes A B;Alvarez D;Rubiera F et al.Simultaneous Calcination and Sintering Model for Limestone Particles Decomposition[J].Transactions of the Institution of Chemical Engineers,1993,71(A):69-76.
[2] Sasaoka E;Uddin M A;Nojima S .Novel Preparation Method of Macroporous Lime from Limestone for HighTemperature Desulfurizaiton[J].Industrial and Engineering Chemistry Research,1997,36(09):3639-3646.
[3] S.-H.Wei;S.K.Mahuli;R.Agnihorti .High surface area calcium carbonate: pore structural properties and sulfation characteristics[J].Industrial & Engineering Chemistry Research,1997(6):2141-2148.
[4] J. Agnew;E. Hampartsoumian;J.M. Jones .The simultaneous calcination and sintering of calcium based sorbents under a combustion atmosphere[J].Fuel,2000(12):1515-1523.
[5] Hanson C;Tullin C .Sintering of Calcium Carbonate and Lime Mud in a Carbon Dioxide Atmosphere[J].Journal of Pulp and Paper Science,1996,22(09):327-331.
[6] Borgwardt R H .Calcium Oxide Sintering in Atmospheres Containing Water and Carbon Dioxide[J].Industrial and Engineering Chemistry Research,1989,28(04):493-500.
[7] Beruto D;Searcy A W .CO2 Catalyzed Surface Area and Porosity Changes in High-Surface Area CaO Aggregates[J].Journal of the American Ceramic Society,1984,67:512-515.
[8] Milne C R;Silcox G D;Pershing D W et al.High Temperature,Short-Time Sulfation of Calcium-Based Sorbents.2.Experimental Data andTheoretical Model Predictions[J].Industrial and Engineering Chemistry Research,1990,29(11):2201-2214.
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