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本文介绍了氮掺杂TiO2纳米球的制备方法,并对TiO2纳米球的超声催化性能进行改进,提高它的超声催化活性.改变方法是利用原位聚合法对TiO2纳米球进行聚吡咯(PPy)包覆来制备TiO2@PPy纳米球,并且在制备TiO2纳米球的过程中引入N离子,以此来提高它的催化效率(本实验超声催化降解罗丹明B),通过透射电镜(TEM)、红外光谱(FT-IR)、X射线衍射(XRD)和热重分析(TGA)对其结构和形貌进行了表征,并利用紫外可见光谱(UV-VIS)表征了其在超声条件下对罗丹明B的超声催化降解性能.结果表明:氮掺杂TiO2@PPy纳米球对罗丹明B有很好的超声催化降解性能.

参考文献

[1] 蔡本慧,曹雷,王肇君.导电聚合物聚吡咯的制备、性质及其应用[J].化工科技市场,2010(05):11-16.
[2] Moser J;Gratzel M;Gallay R .Inhibition of electron-hole recombination in substitutionally doped colloidal semiconductor crystallites[J].Helvetica Chimica Acta,1987,70(06):1596.
[3] Dong S B;Kyong S H;Sang H C .Preparation and thermal stability of doped TiO2 composite membranes by the sol gel process[J].Solid State Ionics,1998,109(3-4):239.
[4] Nathalie K.Guimard;Natalia Gomez;Christine E.Schmidt .Conducting polymers in biomedical engineering[J].Progress in Polymer Science,2007(8/9):876-921.
[5] Kwon JD;Kim PH;Keum JH;Kim JS .Polypyrrole/titania hybrids: synthetic variation and test for the photovoltaic materials[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2004(2/3):311-321.
[6] Luo, Qingzhi;Li, XY;Wang, DS;Wang, YH;An, J .Photocatalytic activity of polypyrrole/TiO(2) nanocomposites under visible and UV light[J].Journal of Materials Science,2011(6):1646-1654.
[7] 张霞,赵岩,张彩碚,孟皓.低温水热合成异形TiO2纳米晶及其表征[J].物理化学学报,2007(06):856-860.
[8] 扈玫珑,徐盛明,白晨光,徐刚,吕学伟.水解制备球形TiO2及其水解过程动力学[J].物理化学学报,2009(08):1511-1516.
[9] 王西奎,陈贯虹,国伟林.水溶液中甲基橙的超声化学降解动力学研究[J].环境污染与防治,2004(01):6-7,13.
[10] Watanabe T;Takizawa T;Honda K .Photocatalysis through excitation of adsorbates.1.Highly efficient N-deethylation of rhodamine B adsorbed to cadmium sulfide[J].Journal of Physical Chemistry,1977,81(19):1845-1851.
[11] Jin-Ming Wu;Tian-Wei Zhang .Photodegradation of rhodamine B in water assisted by titania films prepared through a novel procedure[J].Journal of Photochemistry and Photobiology, A. Chemistry,2004(1):171-177.
[12] 周华军,王大志,刘金华.纳米二氧化钛的量子尺寸效应及掺杂氧化锡对其光吸收的影响[J].化学物理学报,2002(01):61-64.
[13] Wang, J;Tafen, DN;Lewis, JP;Hong, ZL;Manivannan, A;Zhi, MJ;Li, M;Wu, NQ .Origin of Photocatalytic Activity of Nitrogen-Doped TiO2 Nanobelts[J].Journal of the American Chemical Society,2009(34):12290-12297.
[14] Asahi R;Morikawa T;Ohwaki T;Aoki K Tags Y .Visible Light Photocatalysis in Nitrogen-Doped Titanium Oxides[J].Science,2001,293(13):269-271.
[15] 翟晓辉,龙绘锦,董江舟,曹亚安.N-TiO_2/ZnO复合纳米管阵列的掺杂机理及其光催化活性[J].物理化学学报,2010(03):663-668.
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