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采用水溶液聚合法将丙烯酰氧乙基三甲基化铵(DAC)、丙烯酰胺(AM)、丙烯酸(AA)3种单体接枝到纤维素骨架中合成玉米秸秆基两性高吸水性树脂.研究单体用量、秸秆用量、交联剂用量、引发剂用量、反应温度、反应时间和中和度对高吸水性树脂吸液率的影响.通过扫描电镜图、红外光谱图对其形貌进行表征.实验结果表明,在秸秆、AA、AM、DAC的质量分别为1、5、1和0.5g,引发剂用量占单体比率为1.2%,交联剂用量占单体总量比率为0.1%,中和度为75%,反应时间为3h,反应温度为60℃的合成条件下,制备的高吸水性树脂(SAR)吸液率达最大,其吸水率为235.9g/g,0.9%NaCl溶液的吸收率为31.3g/g.

参考文献

[1] 徐晓秋;刘廷栋.高吸水性树脂的工业与配方[M].北京:化学工业出版社,2004:45-47.
[2] Zuoxin Liu;Yonggang Miao;Zhenying Wang .Synthesis and characterization of a novel super-absorbent based on chemically modified pulverized wheat straw and acrylic acid[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2009(1):131-135.
[3] Pratish V Dadhaniya;Manish P Patel;Ranjan G Patel .Swelling and dye adsorption study of novel superswelling [Acrylamide/N-vinylpyrrolidone/3(2-hydroxyethyl carbamoyl)acrylic acid]hydrogels[J].Polymer bulletin,2006(1):21-31.
[4] Kosemund K;Schlatter H;Ochsenhirt JL;Krause EL;Marsman DS;Erasala GN .Safety evaluation of superabsorbent baby diapers.[J].Regulatory Toxicology and Pharmacology: RTP,2009(2):81-89.
[5] 赫延龄,张东向,郑蔚虹.保水剂结合矿质元素对水稻幼苗生长发育的影响[J].西北植物学报,1997(01):124.
[6] 贾朝霞,郑焰.高吸水性树脂用于水土保持和节水农业的新思路[J].农业环境与发展,1999(03):38-41.
[7] 徐志良,范力仁,沈上越,许剑,凌辉.表面Ca2+交联对蒙脱石/聚丙烯酸(钠)吸水保水复合材料性能的影响[J].功能材料,2004(z1):2596-2598.
[8] 刘丽香,吴承祯,洪伟,李键,蔡冰玲,林淑伟.农作物秸秆综合利用的进展[J].亚热带农业研究,2006(01):75-80.
[9] 任广跃,毛志怀,李栋.秸秆饲用处理及其有效利用的研究进展[J].粮食与饲料工业,2004(07):29-30.
[10] 李静,杨红霞,杨勇,刘燕,魏世强.微波强化酸预处理玉米秸秆乙醇化工艺研究[J].农业工程学报,2007(06):199-202.
[11] 李旭东,王霞.玉米秸秆预处理研究[J].食品与发酵工业,2008(04):111-114.
[12] Lepourtre P;Hui S H;Robertson A A .The water absorbency of hydrolyzed polyacrylonitrile-grafted cellulose fibers[J].Journal of Applied Polymer Science,1973,17(10):3143-3156.
[13] Lokhande H T;Varadarajan P V .A new approach in the production of non-wood-based cellusic superabsorbents through the PAN grafting method[J].BioResource Technology,1993,45(03):161-165.
[14] Zhenbin Chen;Mingzhu Liu;Songmei Ma .Synthesis and modification of salt-resistant superabsorbent polymers[J].Reactive & functional polymers,2005(1):85-92.
[15] Raju M P;Raju K M .Design and synthesis of superab-sorbent polymers[J].Journal of Applied Polymer Science,2001,80(04):2635-2693.
[16] 张春晓,张万喜,刘健,白福臣,潘振远.丙烯酸和丙烯酰胺共聚合的竞聚率测定及其共聚物的吸湿性能研究[J].功能材料,2010(06):943-947.
[17] 张荣明,吴殿义,丁伟,于涛.耐盐性淀粉接枝型高吸水性树脂的制备及其性能[J].大庆石油学院学报,2002(01):108-110.
[18] Ma, Z.;Li, Q.;Yue, Q.;Gao, B.;Xu, X.;Zhong, Q. .Synthesis and characterization of a novel super-absorbent based on wheat straw[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2011(3):2853-2858.
[19] Junping Zhang;An Li;Aiqin Wang .Synthesis and characterization of multifunctional poly(acrylic acid-co-acrylamide)/sodium humate superabsorbent composite[J].Reactive & functional polymers,2006(7):747-756.
[20] 杨连利,梁国正.海藻酸钠/累托石插层复合高吸水性树脂制备及性能[J].功能材料,2008(10):1706-1709.
[21] 段漓童,刘正猛.红外光谱图的分区[J].华北煤炭医学院学报,2006(03):336-337.
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