欢迎登录材料期刊网

材料期刊网

高级检索

通过嫁接的方法合成了Al-SBA-15介孔分子筛,用X射线衍射、透射电子显微镜、低温N2吸附和NH3程序升温脱附等方法进行了表征,并研究了其在苯酚叔丁基化反应中的催化性能. 结果表明, Al-SBA-15保持了母体SBA-15高度有序的六方介孔结构,具有较强的酸性,且在苯酚叔丁基化反应中表现出比Al-MCM-41更好的催化活性和2,4-二叔丁基苯酚选择性.

参考文献

[1] Kresge C T;Leonowicz M E;Roth W J;Vartuli J C,Beck J S .[J].Nature,1992,359(6397):710.
[2] Beck J S;Vartuli J C;Roth W J;Leonowicz M E,Kresge C T,Schmitt K D,Chu C T W,Olson D H,Sheppard E W,McCullen S B,Higgins J B,Schlenker J L .[J].Journal of the American Chemical Society,1992,114(27):10834.
[3] Zhao D Y;Feng J L;Huo Q S;Melosh N,Fredrickson G H,Chmelka B F,Stucky G D .[J].Science,1998,279(5350):548.
[4] Zhao DY.;Feng JL.;Chmelka BF.;Stucky GD.;Huo QS. .Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures[J].Journal of the American Chemical Society,1998(24):6024-6036.
[5] Luan Zh H;Cheng Ch F;Zhou W Z;Klinowski J .[J].Journal of Physical Chemistry,1995,99(03):1018.
[6] Mokaya R;Jones W.[J].Chemical Communications,1997(22):2185.
[7] Luan Z;Hartmann M;Zhao D;Zhou W,Kevan L .[J].CHEMISTRY OF MATERIALS,1999,11(06):1621.
[8] Sartori G;Bigi F;Casiraghi G;Gasnati G,Chiesi L,Arduini A .[J].Chemica Industry,1985,22:762.
[9] Carlton A S Jr .[J].Journal of Organic Chemistry,1948,13(01):120.
[10] Chandra K G;Sharma M M .[J].Catalysis Letters,1993,19(04):309.
[11] Sakthivel A;Badamali S K;Selvam P .[J].Microporous and Mesoporous Materials,2000,39(03):457.
[12] Zhang K;Zhang H B;Xu G H;Xiang S H,Xu D,Liu S Y,Li H X .[J].Applied Catalysis A:General,2001,207(1-2):183.
[13] Kosslick H;Landmesser H;Fricke R .[J].Journal of the Chemical Society,Faraday Transactions,1997,93(09):1849.
[14] Kosslick H;Lischke G;Parlitz B;Storek W,Fricke R .[J].Applied Catalysis A:General,1999,184(01):49.
[15] Karge H G;Dondur V;Weitkamp J .[J].Journal of Physical Chemistry,1991,95(01):283.
[16] Badamali SK.;Selvam P.;Sakthivel A. .Tertiary butylation of phenol over mesoporous H-FeMCM-41[J].Catalysis Letters,2000(1/3):153-157.
[17] Sakthivel A;Dapurkar S E;Gupta N M;Kulshreshtha S K,Selvam P .[J].Microporous and Mesoporous Materials,2003,65(2-3):177.
[18] Huang JH;Li G;Wu SJ;Wang HS;Xing LH;Song K;Wu TH;Kan QB .Synthesis, characterization and catalytic activity of cubic Ia3d and hexagonal p6mm mesoporous aluminosilicates with enhanced acidity[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(10):1055-1060.
[19] Li G;Kan Q B;Wu T H;Hou C M,Xiao F Sh,Huang J H .[J].Studies in Surface Science and Catalysis,2003,146:149.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%