以双酚A环氧丙烯酸酯为预聚物,制备了液态UV固化树脂,并将石墨烯分散于液态UV固化树脂中,研究了石墨烯对树脂性能的改进,同时与炭黑改性树脂进行了平行对比.结果表明:透射电镜观察到质量分数为0.025％的炭黑在液态UV固化树脂中发生团聚,炭黑改性后树脂拉伸强度下降了32.8％,弯曲模量下降了46.88％,改性效果差;而透射电镜显示石墨烯在液态UV固化树脂中的分散效果较好,经石墨烯改性后的UV固化树脂拉伸强度提高了8.39％,弯曲模量下降了46.79％,表明石墨烯对液态UV固化树脂具有增强增韧的作用.
参考文献
| [1] | 孟晓明;楼平;赵永生;王利民;陈思敏.碳纳米管、石墨烯在导电涂料中的应用研究进展[J].涂料工业,2015(5):82-87. |
| [2] | Phaedon Avouris;Christos Dimitrakopoulos.Graphene: synthesis and applications[J].Materials Today,20123(3):86-97. |
| [3] | 蔡文曦;盛鑫鑫;张心亚;钟理.石墨烯在功能涂料中的应用概述[J].涂料工业,2014(10):74-79. |
| [4] | 匡达;胡文彬.石墨烯复合材料的研究进展[J].无机材料学报,2013(03):235-246. |
| [5] | 孙艳红;赵家昌;唐博合金;唐敖民;廖晨敏;徐菁利.石墨烯复合材料的研究进展[J].上海工程技术大学学报,2011(3):252-257. |
| [6] | Ahmed S. Wajid;H. S. Tanvir Ahmed;Sriya Das.High-Performance Pristine Graphene/ipoxy Composites With Enhanced Mechanical and Electrical Properties[J].Macromolecular materials and engineering,20133(3):339-347. |
| [7] | Tapas Kuila;Saswata Bose;Ananta Kumar Mishra;Partha Khanra;Nam Hoon Kim;Joong Hee Lee.Chemical functionalization of graphene and its applications[J].Progress in materials science,20127(7):1061-1105. |
| [8] | Sajini VadukumpullyDepartment of Chemistry, National University of Singapore, 3 Science Driue 3, Singapore 117543, Singapore;Jinu PaulDepartment of Chemistry, National University of Singapore, 3 Science Driue 3, Singapore 117543, Singapore;Narahari Mahanta.Flexible conductive graphene/poly(vinyl chloride) composite thin films with high mechanical strength and thermal stability[J].Carbon: An International Journal Sponsored by the American Carbon Society,20111(1):198-205. |
| [9] | Yang, C.;Yang, Z.-G..Synthesis of low viscosity, fast UV curing solder resist based on epoxy resin for ink-jet printing[J].Journal of Applied Polymer Science,20131(1):187-192. |
| [10] | 景磊;朱楠;迟波;陈浩然;苏峰.石墨烯及其环氧树脂基复合材料的研究进展[J].纤维复合材料,2015(1):9-12. |
| [11] | 王学宝;李晋庆;罗运军.石墨烯/环氧树脂复合材料的制备及力学性能[J].高分子材料科学与工程,2013(7):161-165. |
| [12] | Zaman, I.;Phan, T.T.;Kuan, H.-C.;Meng, Q.;Bao La, L.T.;Luong, L.;Youssf, O.;Ma, J..Epoxy/graphene platelets nanocomposites with two levels of interface strength[J].Polymer: The International Journal for the Science and Technology of Polymers,20117(7):1603-1611. |
| [13] | Bortz, D.R.;Heras, E.G.;Martin-Gullon, I..Impressive fatigue life and fracture toughness improvements in graphene oxide/epoxy composites[J].Macromolecules,20121(1):238-245. |
| [14] | 陈建剑;俞科静;钱坤;曹海建;郏余晨.石墨烯改性环氧树脂/碳纤维复合材料拉伸性能的研究[J].化工新型材料,2012(9):63-65,71. |
| [15] | Li, Y.;Zhu, J.;Wei, S.;Ryu, J.;Sun, L.;Guo, Z..Poly(propylene)/graphene nanoplatelet nanocomposites: Melt rheological behavior and thermal, electrical, and electronic properties[J].Macromolecular chemistry and physics,201118(18):1951-1959. |
| [16] | 巩娜娟;吕永根;杨常玲;陆叶涛.氧化石墨烯对丙烯腈聚合及溶液流变性能的影响[J].高科技纤维与应用,2013(2):20-24,42. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%