{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以5-<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span>、<span style=\"color:red\">乙醇胺</span>和氯化铜为原料,在微波作用下合成了5-<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span><span style=\"color:red\">乙醇胺</span><span style=\"color:red\">合</span><span style=\"color:red\">铜</span>(Ⅱ)配合物.利用红外光谱、元素分析和单晶X射线衍射方法对目标化合物进行了表征,标题配合物为单斜晶系,P21/n空间群.晶胞参数:a =0.49793(6) nm,b=1.7037(2) nm,c=1.07120(12) nm,β=94.579(3)°,F(000) =470,Z=2,V=0.905(8) nm3,Dc=1.689 mg/m3,R[I＞2σ(I)],R1=0.0624,ωR2 =0.1555.配合物分子中,2种Schiff碱配体中的2个O原子和2个N原子参与配位,Cu(Ⅱ)处于四边形配位中心.用MTT法测得标题配合物对6种革兰氏细菌(B.subtilis、S.aureus、S.faecalis、P.aeruginosa、E.coli和Ecloacae)的最小抑制浓度分别为12.25、25、12.5、12.5、6.25和6.25 mg/L.","authors":[{"authorName":"徐锁平","id":"6c223683-c8fb-4da8-929f-98d5aef212aa","originalAuthorName":"徐锁平"},{"authorName":"卢晗","id":"4350ac17-b4c7-4679-a520-ecba1993e398","originalAuthorName":"卢晗"},{"authorName":"徐进红","id":"fb227e3c-f02c-4da3-8ae8-bd3184e524e1","originalAuthorName":"徐进红"}],"doi":"10.3724/SP.J.1095.2013.20150","fpage":"295","id":"7140fe7c-db10-4a2e-935e-e2d48949b67f","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"074d6553-29d5-421e-bd1d-2f01a778f40a","keyword":"<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span><span style=\"color:red\">乙醇胺</span><span style=\"color:red\">合</span><span style=\"color:red\">铜</span>(Ⅱ)","originalKeyword":"氯水杨醛缩乙醇胺合铜(Ⅱ)"},{"id":"6dc72e75-82fa-4f45-ade4-9835f9a420a3","keyword":"微波合成","originalKeyword":"微波合成"},{"id":"b8018ad8-d63f-418f-9e8c-aa70438f94af","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"b9ec1933-5680-4f59-89ee-8810d9e7c549","keyword":"抑菌活性","originalKeyword":"抑菌活性"}],"language":"zh","publisherId":"yyhx201303009","title":"5-<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span><span style=\"color:red\">乙醇胺</span><span style=\"color:red\">合</span><span style=\"color:red\">铜</span>(Ⅱ)的微波直接合成、晶体结构及抑菌活性","volume":"30","year":"2013"},{"abstractinfo":"合成了3,5-二<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>邻苯二<span style=\"color:red\">胺</span><span style=\"color:red\">铜</span>配合物[Cu(C20H10Cl4O2N2)]·DMF. 通过元素分析、红外光谱、热重测试技术对其进行了表征,同时用X射线单晶衍射确定了其晶体结构;利用紫外-可见光吸收光谱、荧光激发和发射光谱研究了该配合物的光物理性能. 结果表明,该晶体属于单斜晶系,空间群为P2(1)/n,a=0.81316(8) nm,b=1.53101(18) nm,c=1.87819(19) nm,β=92.4530(10)°,Z=4,最终偏差因子R1=0.0584,ωR2=0.1482,配合物的中心<span style=\"color:red\">铜</span>离子与席夫碱的2个O和2个N配位,形成1个五元环和2个六元环,从而构成了1个四配位的平面构型;配合物的热分解温度为384 ℃,具有很好的热稳定性;在DMF溶液体系中,配合物的荧光激发带位于360～480 nm,荧光发射峰在507 nm处,为蓝绿色荧光,最佳激发波长为440 nm,禁带宽度2.59 eV.","authors":[{"authorName":"张晓松","id":"b372c0fc-376d-4880-b9f7-6b81a04ac10a","originalAuthorName":"张晓松"},{"authorName":"丁国华","id":"a65737ea-01d7-4879-b92e-7e289da0b5ef","originalAuthorName":"丁国华"},{"authorName":"齐巧珍","id":"0e0c4a4b-9e44-4268-a213-b26a9734f1b0","originalAuthorName":"齐巧珍"}],"doi":"10.3724/SP.J.1095.2010.00034","fpage":"1334","id":"6a9eb540-f4e1-4640-ac3e-425234e923fb","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"24cd629b-af25-4009-93bf-baeb4b911b05","keyword":"二<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span>","originalKeyword":"二氯水杨醛"},{"id":"8a8891e1-9c4d-4b2d-8f18-5d4cd69950ad","keyword":"<span style=\"color:red\">铜</span>(Ⅱ)配合物","originalKeyword":"铜(Ⅱ)配合物"},{"id":"abede433-c528-499f-a194-c0b52e780fc7","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"2adf54d3-1b54-4255-8918-860294654a2a","keyword":"光谱特性","originalKeyword":"光谱特性"}],"language":"zh","publisherId":"yyhx201011018","title":"3,5-二<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>邻苯二<span style=\"color:red\">胺</span><span style=\"color:red\">铜</span>配合物的合成、晶体结构及光谱学性质","volume":"27","year":"2010"},{"abstractinfo":"合成了双<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>乙二<span style=\"color:red\">胺</span><span style=\"color:red\">合</span><span style=\"color:red\">铜</span>(Ⅱ)[Cu(Ⅱ)-EDBSAD]席夫碱金属配合物,并以该配合物为中性载体制备PVC膜电极,该电极对SCN-具有优良的电位响应特性,在pH =5.5磷酸盐缓冲溶液中,SCN-浓度在1.0 ×10-1～1.0×10-7 mol/L之间具有能斯特响应,校准曲线方程为E(mV)=-51.75lg CSCN--255.29,检测下限为5.6×10-8 mol/L.将电极用于废水中硫氰酸盐含量的测定,结果与高效液相色谱法基本一致.","authors":[{"authorName":"徐刚","id":"0e0ea651-3565-4602-a202-fbb171b12d34","originalAuthorName":"徐刚"},{"authorName":"董文丽","id":"3a2b68d5-e28a-46d2-96bf-be3e746fca97","originalAuthorName":"董文丽"},{"authorName":"任凌燕","id":"97be123d-e20b-4d58-9388-ac3c2c431a70","originalAuthorName":"任凌燕"},{"authorName":"刘火安","id":"6c14539e-3aa6-4791-a428-39d2c84d6d41","originalAuthorName":"刘火安"}],"doi":"10.3724/SP.J.1095.2013.20024","fpage":"88","id":"280c72bf-8bcd-4d3c-9d2b-094d517ea974","issue":"1","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"b25ced72-c3d1-44a7-8ba5-096879b6d5f0","keyword":"<span style=\"color:red\">铜</span>(Ⅱ)配合物","originalKeyword":"铜(Ⅱ)配合物"},{"id":"65563f84-e760-4829-9249-5390993d7d51","keyword":"离子选择电极","originalKeyword":"离子选择电极"},{"id":"a661f454-7f1a-4bb9-a867-dd7449e57dbd","keyword":"硫氰酸根","originalKeyword":"硫氰酸根"},{"id":"7f0aa46e-2584-4639-971b-8185db1499a2","keyword":"废水","originalKeyword":"废水"}],"language":"zh","publisherId":"yyhx201301015","title":"双<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>乙二<span style=\"color:red\">胺</span><span style=\"color:red\">合</span><span style=\"color:red\">铜</span>(Ⅱ)席夫碱金属配合物的合成及应用","volume":"30","year":"2013"},{"abstractinfo":"采用分步溶液法,在碱性条件下合成出了3,5-二<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>异亮氨酸邻菲啰啉<span style=\"color:red\">铜</span>(Ⅱ)三元配合物,并培养出[Cu3L3(Phen)3].5H2O单晶(其中H2L=3,5-二<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span>席夫碱<span style=\"color:red\">缩</span>异亮氨酸),其晶体结构经元素分析,红外光谱及X射线单晶衍射表征.","authors":[{"authorName":"刘峥","id":"14d5315e-6753-4958-95e2-a92cd5da039a","originalAuthorName":"刘峥"},{"authorName":"夏金虹","id":"5f0872f2-28f3-45bb-8b54-1926fecde8c0","originalAuthorName":"夏金虹"},{"authorName":"王永燎","id":"59a89acf-9aef-4777-a58d-1b8a1b192023","originalAuthorName":"王永燎"},{"authorName":"韦春","id":"1d441e6e-e120-4235-a199-ce6f6395ddf3","originalAuthorName":"韦春"}],"doi":"","fpage":"1542","id":"34046864-9abb-48f0-9999-eb1f4ce8ad5a","issue":"6","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"26ab6da0-d198-4b30-af9e-2dd000be43e6","keyword":"氨基酸席夫碱","originalKeyword":"氨基酸席夫碱"},{"id":"44a54302-fd6d-4a6e-911e-54fa498b8c3e","keyword":"合成","originalKeyword":"合成"},{"id":"347ff975-21ab-4770-9a78-987eda1ddbeb","keyword":"晶体结构","originalKeyword":"晶体结构"}],"language":"zh","publisherId":"rgjtxb98200806048","title":"3,5-二<span style=\"color:red\">氯水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>异亮氨酸邻菲啰啉<span style=\"color:red\">铜</span>(Ⅱ)三元配合物的合成与晶体结构表征","volume":"37","year":"2008"},{"abstractinfo":"用红外光谱、X射线衍射谱及扫描电镜分析研究了合成温度对<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>乙二<span style=\"color:red\">胺</span>锌荧光性能的影响,结果表明,低温下合成的<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>乙二<span style=\"color:red\">胺</span>锌主要以单体形式存在,合成温度提高,通过酚氧桥键形成低聚体,合成温度提高,聚集程度增加,聚集状态不同,导致晶体结构及电子结构变化,从而引起荧光性能的变化.","authors":[{"authorName":"郝玉英","id":"8e042c6b-d2a0-4ef1-a923-cd2e1347d27f","originalAuthorName":"郝玉英"},{"authorName":"高志翔","id":"c5dd703d-b3c8-4caa-9df0-feb7213483bf","originalAuthorName":"高志翔"},{"authorName":"王华","id":"71ba6c67-7107-4cee-8321-a1210c3c4f43","originalAuthorName":"王华"},{"authorName":"周禾丰","id":"313b3c24-e8d3-4f54-a4f6-f4bb66f4dfab","originalAuthorName":"周禾丰"}],"doi":"10.3969/j.issn.1009-6264.2005.03.026","fpage":"82","id":"a3499f12-fd12-40eb-a627-f799fc7c4f09","issue":"3","journal":{"abbrevTitle":"CLRCLXB","coverImgSrc":"journal/img/cover/CLRCLXB.jpg","id":"15","issnPpub":"1009-6264","publisherId":"CLRCLXB","title":"材料热处理学报"},"keywords":[{"id":"d6d13495-19de-4da3-b184-a4b91ebbec27","keyword":"<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>乙二<span style=\"color:red\">胺</span>锌","originalKeyword":"水杨醛缩乙二胺锌"},{"id":"67c48965-6bb6-4ac6-b826-ca2e9fbb7f3c","keyword":"荧光性能","originalKeyword":"荧光性能"},{"id":"4a60dbf0-921e-4497-9a6b-0078154652e3","keyword":"合成","originalKeyword":"合成"},{"id":"6803dbc8-0e3c-49a0-89a0-b431fbb27167","keyword":"聚集体","originalKeyword":"聚集体"}],"language":"zh","publisherId":"jsrclxb200503026","title":"合成温度对<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>乙二<span style=\"color:red\">胺</span>锌荧光性能的影响","volume":"26","year":"2005"},{"abstractinfo":"为了开发一种新型碱性蚀刻液以代替传统的氨类蚀刻液,该蚀刻液的组成特点是以<span style=\"color:red\">铜</span>-<span style=\"color:red\">乙醇胺</span>络合物、氯离子和碱性pH缓冲液作为主要成分.分别采用静态吊片蚀刻法和动态喷淋蚀刻研究方法探索了其最佳配方和操作条件,结果表明在<span style=\"color:red\">铜</span>离子浓度为85～95g/L,氯离子浓度3.5～4.5mol/L,<span style=\"color:red\">乙醇胺</span>浓度4.5～5mol/L,添加剂浓度0.5～1.5g/L,pH为8.5～9.0,操作温度为55～60℃时,其蚀刻状态最佳,相应的静态和动态蚀刻速率分别达61μm/min和20μm/min,与氨类蚀刻液的对应指标相当,且防侧蚀指标更高.结论是该碱性蚀刻液在生产配制、使用和再生循环过程中无废气排放,技术指标优越,具有良好的工业应用前景.","authors":[{"authorName":"李德良","id":"cee6509c-6ac2-4f79-ba2e-ec169347c94e","originalAuthorName":"李德良"},{"authorName":"王丹","id":"fbeb6a8a-5b14-4139-b6c0-5bd57b75e74b","originalAuthorName":"王丹"},{"authorName":"罗洁","id":"b949e574-8abc-4b05-b3bf-0c943262c19c","originalAuthorName":"罗洁"},{"authorName":"龙丽娟","id":"f741a4c8-be3e-44c5-93e7-b48bcf3063b2","originalAuthorName":"龙丽娟"},{"authorName":"彭芸","id":"d7288689-db24-4646-96e9-b79513896f1b","originalAuthorName":"彭芸"}],"doi":"10.3969/j.issn.1001-3660.2008.01.010","fpage":"28","id":"7652d42a-890a-46ca-a373-ef5d14666ab7","issue":"1","journal":{"abbrevTitle":"BMJS","coverImgSrc":"journal/img/cover/BMJS.jpg","id":"3","issnPpub":"1001-3660","publisherId":"BMJS","title":"表面技术   "},"keywords":[{"id":"db3377a9-7a50-450c-96d9-3e4346fc3c54","keyword":"蚀<span style=\"color:red\">铜</span>液","originalKeyword":"蚀铜液"},{"id":"996e3d0a-036d-4304-bcf5-6c580b358ca5","keyword":"<span style=\"color:red\">乙醇胺</span>","originalKeyword":"乙醇胺"},{"id":"df8f3839-094e-4da4-aad8-84fa0f49f874","keyword":"蚀刻速率","originalKeyword":"蚀刻速率"},{"id":"68e43dc1-d5e1-4464-bfab-5e2735ff06d3","keyword":"侧蚀因子","originalKeyword":"侧蚀因子"}],"language":"zh","publisherId":"bmjs200801010","title":"<span style=\"color:red\">乙醇胺</span>碱性蚀<span style=\"color:red\">铜</span>液的研究","volume":"37","year":"2008"},{"abstractinfo":"利用极化曲线法研究了钼酸钠以及钼酸钠和三<span style=\"color:red\">乙醇胺</span>以特定的配比形成的复合缓蚀剂对<span style=\"color:red\">铜</span>的缓蚀作用.结果发现：单独使用钼酸钠时，缓蚀效果不明显;钼酸钠与三<span style=\"color:red\">乙醇胺</span>的协同作用时，钝化区显著增宽，缓蚀效果提高，且所需剂量更少，表明钼酸钠和三<span style=\"color:red\">乙醇胺</span>共同作用在去离子水中及在含5×10-3 g/L Cl-的去离子中对<span style=\"color:red\">铜</span>具有明显的协同缓蚀作用.且当钼酸钠为300 mg/L，三<span style=\"color:red\">乙醇胺</span>也为300 mg/L时，协同缓蚀效率最高.\n","authors":[{"authorName":"王昕","id":"a27343f7-6c5e-49dc-9ec7-2f49c6db402d","originalAuthorName":"王昕"},{"authorName":"张春丽","id":"f739a8cf-9662-4607-bf14-71a8345bf6c2","originalAuthorName":"张春丽"}],"categoryName":"|","doi":"","fpage":"44","id":"84b46347-ceaa-4410-9380-02ba0dae505b","issue":"1","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"81eec3c6-738e-4ee0-a470-c205ab74606a","keyword":"triethanolamine","originalKeyword":"triethanolamine"},{"id":"07f0e960-7b49-4037-a56a-d95f9d2906dc","keyword":"\ncorrosion inhibition","originalKeyword":"\ncorrosion inhibition"},{"id":"7ed6748b-5add-4de7-93f4-95438289e620","keyword":"\nsynegetic effect","originalKeyword":"\nsynegetic effect"}],"language":"zh","publisherId":"1002-6495_2004_1_5","title":"钼酸钠和三<span style=\"color:red\">乙醇胺</span>对<span style=\"color:red\">铜</span>的缓蚀作用","volume":"16","year":"2004"},{"abstractinfo":"利用极化曲线法研究了钼酸钠以及钼酸钠和三<span style=\"color:red\">乙醇胺</span>以特定的配比形成的复合缓蚀剂对<span style=\"color:red\">铜</span>的缓蚀作用.结果发现:单独使用钼酸钠时,缓蚀效果不明显;钼酸钠与三<span style=\"color:red\">乙醇胺</span>的协同作用时,钝化区显著增宽,缓蚀效果提高,且所需剂量更少,表明钼酸钠和三<span style=\"color:red\">乙醇胺</span>共同作用在去离子水中及在含5×10-3 g/L Cl-的去离子中对<span style=\"color:red\">铜</span>具有明显的协同缓蚀作用.且当钼酸钠为300 mg/L,三<span style=\"color:red\">乙醇胺</span>也为300 mg/L时,协同缓蚀效率最高.","authors":[{"authorName":"王昕","id":"4b1213af-aa20-49bf-88c1-1f45ae0cfb8a","originalAuthorName":"王昕"},{"authorName":"张春丽","id":"a195f5e0-c7d2-425b-b60b-a01b0d785a10","originalAuthorName":"张春丽"}],"doi":"10.3969/j.issn.1002-6495.2004.01.012","fpage":"44","id":"fe77b57c-92cf-4340-a915-f594ed2fb4dc","issue":"1","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"9b8cd78f-6224-40e4-9f02-61774d889308","keyword":"钼酸钠","originalKeyword":"钼酸钠"},{"id":"559e75a2-677f-4f08-a881-85e8146995bc","keyword":"三<span style=\"color:red\">乙醇胺</span>","originalKeyword":"三乙醇胺"},{"id":"eef9c109-e18e-4f1a-ae76-13d34e2c1754","keyword":"缓蚀剂","originalKeyword":"缓蚀剂"},{"id":"27b570ee-3f05-4dc4-94b8-2cf0433be2bd","keyword":"协同作用","originalKeyword":"协同作用"}],"language":"zh","publisherId":"fskxyfhjs200401012","title":"钼酸钠和三<span style=\"color:red\">乙醇胺</span>对<span style=\"color:red\">铜</span>的缓蚀作用","volume":"16","year":"2004"},{"abstractinfo":"合成了3,5-二碘<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>邻苯二<span style=\"color:red\">胺</span>席夫碱<span style=\"color:red\">合</span>镍(Ⅱ)配合物.通过核磁共振、元素分析、紫外光谱、红外光谱及摩尔电导对结构进行了表征,用Gaussian03程序优化计算,确定配合物的结构为Ni(Ⅱ)L.通过紫外光谱、粘度法及与溴化乙锭(EB)的竞争实验,研究了配合物与小牛胸腺DNA(ct-DNA)的作用情况.结果显示,配合物与DNA作用时,紫外吸收发生明显的减色效应,其结合常数为Kb=1.129×105 L/mol;EB-DNA体系的荧光强度随配合物的加入迅速减弱；配合物的加入使ct-DNA的粘度增加.这些结果表明,该化合物以插入式与ct-DNA键<span style=\"color:red\">合</span>.并用打孔法测试了配合物对藤黄微球菌(M.luteus)的抑制作用.","authors":[{"authorName":"李晓红","id":"093cd608-3f26-45cb-85d9-49fbc9b51100","originalAuthorName":"李晓红"},{"authorName":"杨天林","id":"cace100c-509e-432d-99eb-bc5becc93eaa","originalAuthorName":"杨天林"},{"authorName":"王敏","id":"1948c7d8-b89b-4189-88ce-176b8ce4eb98","originalAuthorName":"王敏"},{"authorName":"霍丽娜","id":"a9a81bb4-d9c0-402f-9a3c-f63b2d6efce1","originalAuthorName":"霍丽娜"},{"authorName":"李艳萍","id":"325cb4f6-4010-49fa-85dd-6f0ece1d9e57","originalAuthorName":"李艳萍"}],"doi":"10.3724/SP.J.1095.2013.20021","fpage":"43","id":"981a90e8-56c5-4cab-a89b-552d417f44de","issue":"1","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"58b72b4e-7dde-4fa9-8c06-37549b2fe19b","keyword":"含碘席夫碱","originalKeyword":"含碘席夫碱"},{"id":"ee9a6f7b-ff4f-43a5-8de0-8d55be8f8786","keyword":"Ni(Ⅱ)配合物","originalKeyword":"Ni(Ⅱ)配合物"},{"id":"34cf0a3f-87be-4f03-abac-7decddaa58f6","keyword":"光谱性质","originalKeyword":"光谱性质"},{"id":"843ca780-27de-4cb0-8cac-b924160ade02","keyword":"DNA插入作用","originalKeyword":"DNA插入作用"},{"id":"7f4a5032-fd9b-4bfe-ae45-66527a9d56c6","keyword":"抑菌活性","originalKeyword":"抑菌活性"}],"language":"zh","publisherId":"yyhx201301008","title":"3,5-二碘<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>邻苯二<span style=\"color:red\">胺</span>Ni(Ⅱ)配合物的合成及生物活性","volume":"30","year":"2013"},{"abstractinfo":"用<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span>和邻苯二<span style=\"color:red\">胺</span>合成了<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>邻苯二<span style=\"color:red\">胺</span>双席夫碱(SPS),将其作为中性载体与碳粉混合,以液体石蜡为粘合剂,制备出能斯特响应<span style=\"color:red\">铜</span>(Ⅱ)离子选择性电极,应用于SCN-的测定. SCN-浓度在1.0×10-6～1.0×10-2 mol/L之间时该电极对其具有能斯特响应,检测下限为4.0×10-7 mol/L. 在pH值为3.5～4.6的SCN-溶液中,电极的响应时间均小于30 s. 电极的稳定性好,灵敏度高,使用寿命长,已用于废水中SCN-的分析.","authors":[{"authorName":"巩春侠","id":"289ee785-51de-4c95-a588-9336085318a4","originalAuthorName":"巩春侠"},{"authorName":"魏小平","id":"09355eea-492a-448d-a651-352f6a42d13b","originalAuthorName":"魏小平"},{"authorName":"李建平","id":"a34ba9d9-0055-4c3b-a932-c71202c1a418","originalAuthorName":"李建平"}],"doi":"10.3724/SP.J.1095.2010.90737","fpage":"950","id":"973a0a68-b918-4f7a-88ac-4a4faf1e4007","issue":"8","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"127eeef2-06eb-480d-97cb-b086ce169a1d","keyword":"SCN-","originalKeyword":"SCN-"},{"id":"6c643c07-a309-4f0d-9f8c-013fa8e24445","keyword":"离子选择性电极","originalKeyword":"离子选择性电极"},{"id":"6e1753e2-fd10-44f5-bc4f-81dac2a65d3a","keyword":"<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>邻苯二<span style=\"color:red\">胺</span>双席夫碱","originalKeyword":"水杨醛缩邻苯二胺双席夫碱"},{"id":"79338e26-a9b8-4375-9b4d-1eda02f91a8f","keyword":"碳糊","originalKeyword":"碳糊"}],"language":"zh","publisherId":"yyhx201008016","title":"<span style=\"color:red\">水杨</span><span style=\"color:red\">醛</span><span style=\"color:red\">缩</span>邻苯二<span style=\"color:red\">胺</span>双席夫碱敏感膜Cu( Ⅱ )离子选择性电极及SCN-的测定","volume":"27","year":"2010"}],"totalpage":1455,"totalrecord":14549}