本文提出一种利用150～300℃中低温太阳能驱动的甲醇-水重整反应制氢的新方法,该方法操作温度远低于其他太阳能热化学制氢方式.在5kW抛物槽式太阳能集热器.吸收/反应器上对制氢关键过程进行了实验研究.实验结果表明:甲醇转化率可达90%以上,产物氢气浓度为66%～74%;1mol甲醇制氢量可达2.90mol,接近理想状态3mol;基于能量品位的概念,深入分析了这一过程的能量转换机理;并对制氢成本进行了初步分析.本文的研究成果为高效利用中低温太阳热能与低能耗、低成本制氢提供一条新途径.
参考文献
| [1] | Edward A. Fletcher .Solarthermal Processing: A Review[J].Journal of Solar Energy Engineering,2001(2):63-74. |
| [2] | Aldo Steinfeld .Solar thermochemical production of hydrogen-a review[J].Solar Energy,2005(5):603-615. |
| [3] | Stephan Moller;Dario Kaucic;Christian Sattler .Hydrogen Production by Solar Reforming of Natural Gas: A Comparison Study of Two Possible Process Configurations[J].Journal of Solar Energy Engineering,2006(1):16-23. |
| [4] | D. Trommer;F. Noembrini;M. Fasciana;D. Rodriguez;A. Morales;M. Romero;A. Steinfeld .Hydrogen production by steam-gasification of petroleum coke using concentrated solar power-I. Thermodynamic and kinetic analyses[J].International journal of hydrogen energy,2005(6):605-618. |
| [5] | Z Graggen A;Haueter P;Trommer D et al.Hydrogen Production by Steam-Gasification of Petroleum Coke Using Concentrated Solar Power-II Reactor Design,Testing,and Modeling[J].International Journal of Hydrogen Energy,2006,31:797-811. |
| [6] | Tatsuya Kodama;Yumiko Nakamuro;Takayuki Mizuno .A Two-Step Thermochemical Water Splitting by Iron-Oxide on Stabilized Zirconia[J].Journal of Solar Energy Engineering,2006(1):3-7. |
| [7] | Faungnawakij K;Kikuchi R;Eguchi K .Thermodynamic Evaluation of Methanol Steam Reforming for Hydrogen Production[J].Journal of Power Sources,2006,161:87-94. |
| [8] | 刘启斌,洪慧,金红光,蔡睿贤.中低温太阳热能的甲醇重整制氢能量转换机理研究[J].工程热物理学报,2007(05):729-732. |
| [9] | Sargent & Lundy Counting Group.Assessment of Parabolic Trough and Power Tower Solar Technology Cost and Performance Forecasts[M].Prepared for Department of Energy National Renewable Energy Laboratory,2003 |
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