以天然石墨为原料,采用改进的Hummers法合成含Mn的氧化石墨;400℃条件下氢气还原制备了锰氧化物/石墨烯复合材料。利用XRD、SEM和TEM对所制备的复合材料进行了表征。结果表明锰氧化物(MnOx)颗粒均匀地分布在石墨烯片层表面。将复合材料作为锂离子电池负极进行研究,在50mA/g电流密度下,首次库伦效率为70.4%,可逆容量达876mAh/g,并且具有良好的循环性能,在30次循环后仍保持在700mAh/g以上。
The precursor of Mn hybrid material was synthesized by a modified Hummers method and MnOx/graphene composites were obtained through a reduction in nitrogen and hydrogen atmosphere at 400℃.The composite material was investigated as anode materials for lithium ion batteries via scanning and transmission electron microscopy(TEM),X-ray diffraction(XRD) and a variety of electrochemical testing techniques.Experimental results showed that nano-particles of manganese oxide were well dispersed on the surface of graphene sheets.The first reversible capacity of the prepared composite was as high as 876mAh/g at current density of 50mA/g.After 30 cycles,the reversible specific capacity was still maintain at more than 700mAh/g.
参考文献
[1] | Tarascon J M;Armand M .[J].Nature,2001,414:359-367. |
[2] | Fergus J W .[J].Journal of Power Sources,2010,195:939-954. |
[3] | Kganyago KR.;Ngoepe PE.;Catlow CRA. .Ab initio calculation of the voltage profile for LiC6[J].Solid state ionics,2003(1/2):21-23. |
[4] | Wang Zhong;Tian Wenhuai;Li Xingguo .[J].Journal of Functional Materials,2007,38(01):109-112. |
[5] | Beaulieu L Y;Beattie S D;Hatchard T D et al.[J].Journal of the Electrochemical Society,2003,150:419-424. |
[6] | Beaulieu L Y;Hatchard T D;Bonakdarpour A et al.[J].Journal of the Electrochemical Society,2003,150:1457-1464. |
[7] | Wang G X;Shen X P;Yao J et al.[J].Carbon,2009,47:2049-2053. |
[8] | Liang M H;Zhi L Z .[J].Journal of Materials Chemistry,2009,19:5871-5878. |
[9] | Yoo E J;Kim J;Hosono E et al.[J].Nano Letters,2008,8:2277-2282. |
[10] | Pan D;Wang S;Zhao B et al.[J].Chemistry of Materials,2009,21:3136-3142. |
[11] | Yao, J;Shen, XP;Wang, B;Liu, HK;Wang, GX .In situ chemical synthesis of SnO2-graphene nanocomposite as anode materials for lithium-ion batteries[J].Electrochemistry communications,2009(10):1849-1852. |
[12] | Wang H L;Cui L F;Yang Y et al.[J].Journal of the American Chemical Society,2010,132:13978-13980. |
[13] | Wang S Q;Zhang J Y;Chen C H .[J].Journal of Power Sources,2010,195:5379-5381. |
[14] | Lian P C;Zhu X F;Liang S Z et al.[J].Electrochimica Acta,2010,55:3909-3914. |
[15] | Guo P;Song H H;Chen X H .[J].Electrochemistry Communications,2009,11:1320-1324. |
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