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通过XRD、SEM/EDS及PCT测试研究了由FeV80合金制备的V28Ti32Cr28Mn6Fe6合金的组织结构及吸放氢特性.该合金由bcc相和C14 Laves第二相构成.由于合金中氧含量(0.83%,质量分数)较高,因而吸放氢容晕较低,动力学性能较差.通过添加一定景的稀土元素La(1%~10%,质量分数),可显著降低合金中的氧含量,从而提高其动力学性能和吸放氢容量.当La的添加量达到4.0%时,合金具有最佳的吸放氢性能,吸氢量达到3.62%,放氢量达到2.13%;合金氢化物的生成焓为(-40.0±1)kJ/mol·H2.

参考文献

[1] Akiba E et al.[J].Intermetallics,1998,6:461.
[2] Okada M et al.[J].Journal of Alloys and Compounds,2002,330-332:511.
[3] Yu XB et al.[J].Journal of Alloys and Compounds,2004,372:272.
[4] Iwakura C et al.[J].Journal of the Electrochemical Society,2000,147(07):133.
[5] 严义刚,陈云贵,梁浩,梁洁,吴朝玲.V-Ti-Cr-Fe合金的储氢性能研究[J].稀有金属材料与工程,2006(05):686-689.
[6] Nomura K et al.[J].Journal of Alloys and Compounds,1995,231:513.
[7] Yan Y et al.[J].Journal of Alloys and Compounds,2006,426:253.
[8] Yan Y et al.[J].Journal of Alloys and Compounds,2007,441:297.
[9] Yah Y et al.[J].Journal of Power Sources,2007,164:799.
[10] 廖世明;柏谈论.国外钒冶金[M].北京:冶金工业出版社,1985:113.
[11] Cho S W et al.[J].Journal of Alloys and Compounds,1999,288:294.
[12] Tsukahara M.;Isomura A.;Sakai T.;Takahashi K. .Influence of oxygen on hydrogen storage and electrode properties for micro-designed V-based battery alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):257-263.
[13] Kawabata A et al.[J].Materials Transactions,2001,42(08):1974.
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