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采用一种活化赤泥吸附剂用于水溶液中亚甲基蓝的吸附净化.考察吸附剂用量、pH值、亚甲基蓝浓度、吸附温度和吸附时间对活化赤泥吸附性能的影响规律.结果表明:采用稀柠檬酸活化处理可显著提高赤泥对染料分子的吸附效率;吸附率随吸附剂用量增加而增加,随初始亚甲基蓝浓度和温度升高而降低;测得活化赤泥对亚甲基蓝的最大吸附容量为30 mg/g,吸附过程符合Langmuir等温吸附模型;吸附动力学过程可用准二级动力学方程描述,计算出吸附过程的表观活化能为9.88 kJ/mol.对吸附过程焓和熵值的计算结果表明,活化赤泥对水溶液中亚甲基蓝染料的吸附是一个自发的放热过程.

参考文献

[1] 朱新锋,杨珊姣,焦桂枝.赤泥在水处理中的应用与研究进展[J].无机盐工业,2010(02):5-8.
[2] 王克勤,于永波,王皓,陈津.赤泥盐酸浸出提取钪的试验研究[J].稀土,2010(01):95-98.
[3] 姜平国,梁勇,王鸿振.赤泥中回收稀有金属[J].上海有色金属,2006(01):36-39.
[4] 齐建召,杨家宽,王梅,肖波,侯健.赤泥做道路基层材料的试验研究[J].公路交通科技,2005(06):30-33.
[5] 吴建锋,王东斌,徐晓虹,钟文波,潘长学,贾元平,卢家喜,邓琦.利用工业废渣制备艺术型清水砖的研究[J].武汉理工大学学报,2005(05):46-49.
[6] 张培新,林荣毅,阎加强.赤泥微晶玻璃的研究[J].有色金属,2000(04):77-79.
[7] Kubilay Guclu;Resat Apak .Modeling the adsorption of free and heavy metal complex-bound EDTA onto red mud by a nonelectrostatic surface complexation model[J].Journal of Colloid and Interface Science,2003(2):280-290.
[8] Garau Giovanni;Castaldi Paola;Santona Laura;Deiana Pietrino;Melis Pietro .Influence of red mud, zeolite and lime on heavy metal immobilization, culturable heterotrophic microbial populations and enzyme activities in a contaminated soil[J].Geoderma: An International Journal of Soil Science,2007(1/2):47-57.
[9] Gray CW;Dunham SJ;Dennis PG;Zhao EJ;McGrath SP .Field evaluation of in situ remediation of a heavy metal contaminated soil using lime and red-mud[J].Environmental Pollution,2006(3):530-539.
[10] Hayrunnisa Nadaroglu;Ekrem Kalkan;Nazan Demir .Removal of copper from aqueous solution using red mud[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2010(1/3):90-95.
[11] Shaobin Wang;Y. Boyjoo;A. Choueib;Z.H. Zhu .Removal of dyes from aqueous solution using fly ash and red mud[J].Water research: A journal of the international water association,2005(1):129-138.
[12] The color removal of dye wastewater by magnesium chloride/red mud (MRM) from aqueous solution[J].Journal of hazardous materials,2009(2/3):690.
[13] NAMASIVAYAM C;ARASI D J .Removal of congo red from wastewater by adsorption onto waste red mud[J].Chemosphere,1997,34(02):401-417.
[14] Ali Tor;Yunus Cengeloglu .Removal of congo red from aqueous solution by adsorption onto acid activated red mud[J].Journal of hazardous materials,2006(2):409-415.
[15] 成功,夏东升,曾庆福.微波活化赤泥对分散艳蓝E-4R的吸附去除研究[J].工业用水与废水,2008(04):43-46.
[16] 孙恒虎,冯向鹏,刘晓明,白雪,牛雪莲.机械力化学效应对赤泥结构特性和胶凝性能的影响[J].稀有金属材料与工程,2007(z2):568-570.
[17] B.H. Hameed;A.A. Ahmad .Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass[J].Journal of hazardous materials,2009(2/3):870-875.
[18] Almeida CAP;Debacher NA;Downs AJ;Cottet L;Mello CAD .Removal of methylene blue from colored effluents by adsorption on montmorillonite clay[J].Journal of Colloid and Interface Science,2009(1):46-53.
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