本研究中,以石油焦为造孔剂、Y2O3-Al2O3为烧结助剂,通过注浆成型制备出多孔氮化硅陶瓷.研究石油焦的加入量对多孔氮化硅陶瓷微观结构、力学性能及气体透气性的影响.结果表明:多孔氮化硅陶瓷的微孔是由长棒状的β-Si3N4晶粒互相搭接而成,大孔是由石油焦燃烧而成.随着石油焦加入量的增加,气孔率及达西渗透系数(μ)增大,但试样的抗弯强度降低.在起始α-Si3N4粉末中添加10wt％～50wt％石油焦、5wt％ Y2O3-3wt％Al2O3 1800℃下保温2h制备出气孔率为37.08％～59.40％、抗弯强度为52.00～154.27 MPa、μ值为(3.04 ～6.87)×10-13m2的多孔氮化硅陶瓷.
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