以氮掺杂为代表的非金属掺杂TiO2光催化剂被誉为“第二代光催化材料”.首先系统评述了氮掺杂二氧化钛的制备方法.N掺杂TiO2粉体的制备方法主要有高温焙烧法、水解沉淀法、有机前驱体热解法、溶胶-凝胶法以及机械化学法等；N掺杂TiO2薄膜的制备方法主要包括磁控溅射法、脉冲激光沉积法以及金属有机化学气相沉积法等.综述了近年来国内外通过氮掺杂改进二氧化钛光催化剂的性能、提高可见光利用效率的最新研究进展,指出了在氮掺杂TiO2催化剂研究中有待解决的问题及今后可能的发展方向.
参考文献
| [1] | Fujishima A;Honda K .Electrochemical photolysis of water at a semi conductor electrode[J].Nature,1972,238(5358):37. |
| [2] | Tomkiewicz M .Scaling properties in photocatalysis[J].Catalysis Today,2000,58(2-3):115. |
| [3] | ShiJW;CuiHJ;ZongX et al.Facileone-pot synthesis of Eu,N-codoped mesoporous titania microspheres with yolkshell structure and high visible-light induced photocatalytic performance[J].Applied Catalysis A:General,2012,435:86. |
| [4] | Ranjith G. Nair;A.M. Tripathi;S.K. Samdarshi .Photocatalytic activity of predominantly rutile mixed phase Ag/TiV oxide nanoparticles under visible light irradiation[J].Energy,2011(5):3342-3347. |
| [5] | Nair, R.G.;Roy, J.K.;Samdarshi, S.K.;Mukherjee, A.K. .Enhanced visible light photocatalytic disinfection of gram negative, pathogenic Escherichia coli bacteria with Ag/TiV oxide nanoparticles[J].Colloids and Surfaces, B. Biointerfaces,2011(1):7-13. |
| [6] | Ranjith G N;Tripathi A M;Samdarshi S K .Impact of TiV ratio on the crystalline phase/visible light activity of TiVoxide photocatalyst[J].Environ Prog Sustain Energy,2012,31(01):107. |
| [7] | Xue X X;Wang Y Z;Yang H .Preparation and characterization of boron-doped titania nano-materials with antibacterial activity[J].Applied Surface Science,2013,264:94. |
| [8] | Akhavan O;Azimirad R .Photocatalytic property of Fe2O3 nanograin chains coated by TiO2 nanolayer in visible light irradiation[J].Applied Catalysis A:General,2009,369(1-2):77. |
| [9] | Rico, A.;Poza, P.;Rodríguez, J..High temperature tribological behavior of nanostructured and conventional plasma sprayed alumina-titania coatings[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2013:149-154. |
| [10] | Asahi R;Morikawa T;Ohwaki T et al.Visible-light photocatalysis in nitrogen-doped titanium oxides[J].Science,2001,293(5528):269. |
| [11] | Hong Zhu;Jie Tao;Tao Wang;Jie Deng .Growth of branched rutile TiO_2 nanorod arrays on F-doped tin oxide substrate[J].Applied Surface Science,2011(24):10494-10498. |
| [12] | Guidong Yang;Zifeng Yan;Tiancun Xiao .Low-temperature solvothermal synthesis of visible-light-responsive S-doped TiO_2 nanocrystal[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2012(8):4016-4022. |
| [13] | Titania deposited on soft magnetic activated carbon as a magnetically separable photocatalyst with enhanced activity[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2010(21):P.6191. |
| [14] | Silveyra R;Saenz L D T;Flores W A et al.Doping of TiO2 with nitrogen to modify the interval of photocatalytic activation towards visible radiation[J].Catalysis Today,2005,107-108:602. |
| [15] | Fang XM;Zhang ZG;Chen QL;Ji HB;Gao XN .Dependence of nitrogen doping on TiO2 precursor annealed under NH3 flow[J].International Journal of Quantum Chemistry,2007(4):1325-1332. |
| [16] | Chen CC;Bai HL;Changt CL .Effect of plasma processing gas composition on the nitrogen-doping status and visible light photocatalysis of TiO2[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2007(42):15228-15235. |
| [17] | Sun J H;Qiao L P;Sun S P et al.Photocatalytic degradation of orange G on nitrogen-doped TiO2 catalysts under visible light and sunlight irradiation[J].Journal of Hazardous Materials,2008,155(1-2):312. |
| [18] | Pradeepan Periyat;Declan E.McCormack;Steven J.Hinder .One-Pot Synthesis of Anionic(Nitrogen)and Cationic(Sulfur)Codoped High-Temperature Stable,Visible Light Active,Anatase Photocatalysts[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(8):3246-3253. |
| [19] | Ao Y H;Xu J J;Zhang S H et al.A one-pot method to prepare N-doped titania hollow spheres with high photocatalytic activity under visible light[J].Applied Surface Science,2010,256(09):2754. |
| [20] | Sano T.;Negishi N.;Koike K.;Takeuchi K.;Matsuzawa S. .Preparation of a visible light-responsive photocatalyst from a complex of Ti4+ with a nitrogen-containing ligand[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2004(3):380-384. |
| [21] | Meenal M. Joshi;Nitin K. Labhsetwar;Priti A. Mangrulkar .Visible light induced photoreduction of methyl orange by N-doped mesoporous titania[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2009(1):26-33. |
| [22] | Qin H L;Gu G B;Liu S .Preparation of nitrogen-doped titania using sol-gel technique and its photocatalytic activity[J].Materials Chemistry and Physics,2008,112(02):346. |
| [23] | Jagadale T C;Takale S P;Sonawane R S et al.N-doped TiO2 nanoparticle based visible light photocatalyst by modified peroxide sol-gel method[J].Journal of Physical Chemistry C,2008,112(07):14595. |
| [24] | Spadavecchia F;Cappelletti G;Ardizzone S et al.Solar photoactivity of nano-N-TiO2 from tertiary amine:Role of defects and paramagnetic species[J].Applied Catalysis B:Environmental,2010,96(3-4):314. |
| [25] | Tang Y C;Huang X H;Yu H Q.Nitrogen-doped TiO2 photocatalyst prepared by mechanochemical method:Doping mechanisms and visible photoactivity of pollutant degradation[J].International Journal of Photoenergy |
| [26] | Rojas-Blanco L;Espinoza-Beltran F J;Mani-Gonzalez P G et al.Photocatalytic activity in the visible region of high energy milled TiO2:N nanopowders[J].Revista Mexicana De Fisica,2011,57(02):36. |
| [27] | Lindgren T;Mwabora J M;Avendano E et al.Photoelectrochemical and optical properties of nitrogen doped tita-nium dioxide films prepared by reactive DC magnetron sputtering[J].Journal of Physical Chemistry,2003,107:5709. |
| [28] | Brudnik A;Bucko M;Radecka M;Trenczek-Zajac A;Zakrzewska K .Microstructure and optical properties of photoactive TiO2 : N thin films[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2008(10):936-941. |
| [29] | Rahman M;Dang B H Q;McDonnell K et al.Effect of doping (C or N) and co-doping (C plus N) on the photoactive properties of magnetron sputtered titania coatings for the application of solar water-splitting[J].J Nanosci Nanotechn,2012,12(06):4729. |
| [30] | Zhao L;Jiang Q;Lian J S .Visible-light photocatalytic activity of nitrogen-doped TiO2 thin film prepared by pulsed laser deposition[J].Applied Surface Science,2008,254:4620. |
| [31] | Photocatalytic activity of pulsed laser deposited TiO_2 thin films in N_2, O_2 and CH_4[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2010(16):P.4648. |
| [32] | Edusi C;Hyett G;Sankar G et al.Aerosol-assisted CVD of titanium dioxide thin films from methanolic solutions of titanium tetraisopropoxide;Substrate and aerosol-selective deposition of futile or anatase[J].Chem Vapor Deposit,2011,17(1-3):30. |
| [33] | Nolan MG;Pemble ME;Sheel DW;Yates HM;Yates HM .One step process for chemical vapour deposition of titanium dioxide thin films incorporating controlled structure nanoparticles[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(4):1956-1962. |
| [34] | Berger, T.;Monllor-Satoca, D.;Jankulovska, M.;Lana-Villarreal, T.;Gómez, R. .The electrochemistry of nanostructured titanium dioxide electrodes[J].Chemphyschem: A European journal of chemical physics and physical chemistry,2012(12):2824-2875. |
| [35] | Georgieva J;Valova E;Armyanov S et al.Bi-component semiconductor oxide photoanodes for the photoelectrocatalytic oxidation of organic solutes and vapours:A short review with emphasis to TiO2-WO3 photoanodes[J].Journal of Hazardous Materials,2012,211:30. |
| [36] | Qin G H;Wu Q P;Sun Z et al.Enhanced photoelectrocatalytic degradation of phenols with bifunctionalized dye-sensitized TiO2 film[J].Journal of Hazardous Materials,2012,199:226. |
| [37] | Pankaj Chowdhury;Jesus Moreira;Hassan Gomaa .Visible-Solar-Light-Driven Photocatalytic Degradation of Phenol with Dye-Sensitized TiO2: Parametric and Kinetic Study[J].Industrial & Engineering Chemistry Research,2012(12):4523-4532. |
| [38] | Ochiai, T.;Fujishima, A. .Photoelectrochemical properties of TiO_2 photocatalyst and its applications for environmental purification[J].Journal of photochemistry and photobiology, C. Photochemistry reviews,2012(4):247-262. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%