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由于酸性溶液的强腐蚀性和阳极放氧的强氧化性,使得钛基氧化铅涂层电极的钛基体在使用过程中易发生钝化,氧化铅活性层易脱落,导致电极的电催化活性低、使用寿命短等问题.在钛基体和活性层之间加入中间层不仅能与二者形成固溶体,提高电极的导电性;而且中间层的晶粒均匀细小,能有效阻止酸性溶液经活性层表面空隙到达钛基体表面发生钝化,延长电极的使用寿命.综述了国内外钛基氧化铅涂层电极中间层的选配、在电极中的作用以及对电极电化学性能的影响,并指出未来中间层研究中需要注意的问题和发展趋势.

参考文献

[1] 陈家镛.湿法冶金手册[M].北京:冶金工业出版社,2005
[2] Trasatti S .Electrocatalysis in the anodic evolution of oxygen and chlorine[J].Electrochimica Acta,1984,29(11):1503.
[3] Li Xiaoyan;Cui Yuhong;Feng Yujie et al.Reaction pathways and mechanisms of the electrochemical degradation of phenol on different electrodes[J].Water Research,2005,39:1972.
[4] Beer H B .The invention and industrial development of metal anodes[J].Journal of the Electrochemical Society,1980,127(08):303c.
[5] U. Casellato;S. Cattarin;M. Musiani .Preparation of porous PbO{sub}2 electrodes by electrochemical deposition of composites[J].Electrochimica Acta,2003(27):3991-3998.
[6] Velichenko A B;Baranova E A;Girank D V et al.Mechanism of electrodeposition of lead dioxide from nitrate solutions[J].Russian J Electrochem,2003,39(06):615.
[7] 梁镇海;王森;孙彦平 等.Ti/SnO2+ SbO2+ RuO2/Pb2 O4 阳极研究[J].无机材料学报,1995,10(03):381.
[8] Poinsignon C;Berthome G;Prelot B;Thomas F;Villieras F .Manganese dioxides surface properties studied by XPS and gas adsorption[J].Journal of the Electrochemical Society,2004(10):A1611-A1616.
[9] He Deliang;Mho Sun-l .Electrocatalytic reactions of phenolic compounds at ferric ion co-doped SnO2,Sb5+ electrodes[J].Journal of Electroanalytical Chemistry,2004,568(1-2):19.
[10] Jirkovsky J;Hoffmannov'a M;Krtil P J .Nickel surface anodic oxidation and electrocatalysis of oxygen evolution[J].Journal of the Electrochemical Society,2006,153:E111.
[11] Gorodetskii V V;Neburchilov V A .Titanium anodes with active coatings based on iridium oxides:A sublayer between the active coating and titanium[J].Russian J Electrochem,2003,39(10):1111.
[12] 朱承飞,高红,解瑞,王晓钧.热处理温度对Ti/SnO2+SbOx/MnOx阳极析氧催化性能的影响[J].热加工工艺,2010(24):116-118.
[13] 曾人杰.无机材料化学[M].西安:西安大学出版社,2001:187.
[14] 杨建广;唐谟堂;唐朝波 等.配合-共沉淀法制备锑掺杂二氧化锡(ATO)粉[D].长沙:中南大学,2000.
[15] 刘杏芹,朱海宁,沈瑜生.SbxSn1-xO2固溶体系电学性能与导电机制研究[J].无机化学学报,1996(02):130-134.
[16] Kotz R;Stucki S;Carcer B .Electrochemical waste water treatment using high overvoltage anodes.Part Ⅰ:Physical and electrochemical properties of SnO2 anodes[J].Journal of Applied Electrochemistry,1991,21(01):14.
[17] Udea M;Wanatabe A .Lead oxide-coated electrode for use in electrolysis and process for produing the same[P].US,4822 429,1989.
[18] Udea M;Wanatabe A;Kameyama T et al.Preformance characteristics of a new type of lead dioxide-coated titanium anode[J].Journal of Applied Electrochemistry,1995,25(09):817.
[19] 孙凤梅,潘建跃,罗启富.含铂中间层二氧化铅阳极的制备及其性能[J].材料保护,2006(01):53-54.
[20] Devilliers D;Thi M T D;Mahé E et al.Cr(111) oxidation with lead dioxide-based anodes[J].Electrochimica Acta,2003,48(28):4301.
[21] 陶自春,潘建跃,罗启富.铂中间层的制备及对铱钽涂层钛阳极性能的影响[J].材料科学与工程学报,2004(02):240-244.
[22] 曹梅 .Al基SnO<,2>+Sb<,2>O<,3>、SnO<,2>+Sb<,2>O<,3>+MnO<,2>涂层二氧化铅电极的制备及其应用[D].昆明理工大学,2005.
[23] Munichandraiah N .Insoluble anode of porous lead dioxide for electro-synthesis:Preparation and characterization[J].Journal of Applied Electrochemistry,1987,17:22.
[24] Comninellis Ch;Plattner E .The preparation and behaviour of Ti/Au/PbO2 anodes[J].Journal of Applied Electrochemistry,1982,12:399.
[25] 石绍渊,孔江涛,朱秀萍,倪晋仁.钛基Sn或Pb 氧化物涂层电极的制备与表征[J].环境化学,2006(04):429-434.
[26] 罗文秀;任鹏程;谭忠恪 .SnO2薄层晶体的结构与透明导电性研究[J].功能材料,1993,24(02):129.
[27] 梁镇海,孙彦平.Ti/SnO2+Sb2O3+MnO2/PbO2阳极的性能研究[J].无机材料学报,2001(01):183-187.
[28] 薄占满 .掺Sb二氧化锡半导体导电机理的实验探讨[J].无机非金属学报,1990,5(04):324.
[29] Meguru Inai;Chiaki Iuarura;Hideo Tamura .The cause of activity loss of titanium-supported ruthenium dioxide electrodes during the anodic evolution of oxyen[J].电气化学预工业物理化学 (日 文),1980,48(07):384.
[30] 薛彩霞,梁镇海.Ti/SnO2+Sb2O4+CF/PbOx电极的制备及其性能研究[J].太原理工大学学报,2007(05):431-434.
[31] Yang L X;Allen R G;Scott K et al.A study of PtRuO2 catalysts thermally formed on titanium mesh for methanol oxidation[J].Electrochimica Acta,2005,50(05):1217.
[32] Foti G;Mousty C;Reid V et al.Characterisation of DSA type electrodes prepared by rapid thermal decomposition of the metal precursor[J].Electrochimica Acta,1998,44(05):813.
[33] Chang J K;Chen Y L;Tsai W T .Effect of heat treatment on material characteristics and pseudo-capacitive properties of manganese oxide prepared by anodic deposition[J].Journal of Power Sources,2004,135(1-2):344.
[34] Forti J C;Olivi P;de Andrade A R .Characterisation of DSA.-type coatings with nominal composition Ti/Ru0.3-Ti(0.7-x) SnxO2 prepared via a polymeric precursor[J].Electrochimica Acta,2001,47(06):913.
[35] Velichenko A B;Amadelli R;Baranova E A et al.Electrodeposition of Co-doped lead dioxide and its physicochemical properties[J].Journal of Electroanalytical Chemistry,2002,527(1-2):56.
[36] Amadelli R;Maldotti A;Molinari A et al.Influence of the electrode history and effects of the electrolyte composition and temperature on O2 evolution β-PbO2 anodes in acid media[J].Journal of Electroanalytical Chemistry,2002,534(01):1.
[37] Yang Liu;Zhiying Li;Jinghong Li .IrO_2/SnO_2 electrodes: prepared by sol-gel process and their electrocatalytic for pyrocatechol[J].Acta materialia,2004(3):721-727.
[38] Terezo Ailton J;Pereira Ernesto C .Preparation and characterisation of Ti/RuO2 anodes obtained by sol-gel and conventional routes[J].Materials Letters,2002,53(4-5):339.
[39] 张丽丽,姚军,袁小玉.Sol-gel法镁合金表面制备SiO2涂层及其腐蚀性能研究[J].热加工工艺,2011(06):134-136.
[40] 夏熙,龚良玉.PbO2纳米粉体的固相合成及其对MnO2电极材料的改性作用[J].化学学报,2002(01):87-92.
[41] Jingsi Yang;Jun John Xu .Influence of synthesis conditions on the electrochemical properties of nanostructured amorphous manganese oxide cryogels[J].Journal of Power Sources,2003(2):181-187.
[42] Feng Li;Xianghua Yu .Syntheses of MO_2 (M = Si, Ce, Sn) nanoparticles by solid-state reactions at ambient temperature[J].Solid state sciences,2000(8):767-772.
[43] Duverneuil P.;Maury F.;Pebere N.;Senocq F.;Vergnes H. .Chemical vapor deposition of SnO2 coatings on Ti plates for the preparation of electrocatalytic anodes[J].Surface & Coatings Technology,2002(0):9-13.
[44] I.K.Igumenov;N.V.Gelfond;P.S.Galkin;N.B.Morozova;N.E.Fedotova;G.I.Zharkova;V.I.Shiachev;E.F.Reznikova;A.D.Ryabtsev;N.P.Kotsupalo;V.I.Titarenko .Corrosion testing of platinum metals CVD coated titanium anodes in seawater-simulated solutions[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2001(1/3):273-280.
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