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在分析2024铝合金FSW焊缝表面组织及析出相种类的基础上,采用腐蚀类原位观察揭示了焊缝表面的腐蚀演变行为,结合透射电镜、示差扫描量热分析及电化学分析对焊缝接头的腐蚀机理进行了探索。结果表明:FSW后,焊缝区的耐蚀性能下降,SAZ腐蚀最严重,点蚀的起源为S相。焊缝区晶体缺陷增加,导致晶粒和晶界在电化学性能上的不均匀性增大。在FSW过程中SAZ的S相粒子被打碎,并发生部分回溶。当腐蚀发生时,被打碎的S相加大了SAZ的点蚀密度;溶入基体的Mg元素,提高了轴肩作用区的活性。

In this paper, based on the analysis to surface microstructure of FSW AA2024 joint, the corrosion evolution behavior was revealed by a quasi-in-situ observation method. Besides, the corrosion mechanism of the FSW joint was investigated by combining TEM, DSC and electrochemical analysis. The results show that FSW makes the corrosion resistance decrease, which is characterized by the facts that the most corrosion in the SAZ (shoulder active zone) and the pitting corrosion initially originates in dissolving of the S phase (A12CuMg). TEM observations indicate that crystal defects density increases in the welded joints causing the more different electrochemical properties between grains and grain boundaries. The S phase particles are broken and partially redissolved during the FSW process in the SAZ. When the corrosion happens, the broken S phase particles increase the pitting corrosion density of the SAZ. In addition, the activity of the SAZ is enhanced due to the doped Mg.

参考文献

[1] M. Ericsson;R. Sandstrom .Influence of welding speed on the fatigue of friction stir welds, and comparison with MIG and TIG[J].International Journal of Fatigue,2003(12):1379-1387.
[2] J.-Q. Su;T.W. Nelson;R. Mishra .Microstructural investigation of friction stir welded 7050-T651 aluminium[J].Acta materialia,2003(3):713-729.
[3] Hatamleh O .Effects of peening on mechanical properties in friction stir welded 2195 aluminum alloy joints[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2008(1/2):168-176.
[4] V.M. Linton;M.I. Ripley .Influence of time on residual stresses in friction stir welds in agehardenable 7xxx aluminium alloys[J].Acta Materialia,2008(16):4319-4327.
[5] Ying Li;l.E.Murr;j.c.McClure .SOLID-STATE FLOW VISUALIZATION IN THE FRICTION-STIR WELDING OF 2024 AL TO 6061AL[J].Scripta materialia,1999(9):1041-1046.
[6] 鄢东洋,史清宇,吴爱萍,Juergen Silvanus.搅拌头机械载荷在搅拌摩擦焊接中的作用的数值分析[J].金属学报,2009(08):994-999.
[7] M. Jariyaboon;A.J. Davenport;R. Ambat;B.J. Connolly;S.W. Williams;D.A. Price .The effect of welding parameters on the corrosion behaviour of friction stir welded AA2024-T351[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2007(2):877-909.
[8] 李劲风,郑子樵,张昭,张鉴清.铝合金剥蚀过程的电化学阻抗谱分析[J].中国腐蚀与防护学报,2005(01):48-52.
[9] 张丹峰,谭晓明,马力,陈跃良.服役环境条件下飞机结构铝合金材料孔蚀规律研究[J].中国腐蚀与防护学报,2010(01):93-96.
[10] Mishra RS;Ma ZY .Friction stir welding and processing[J].Materials Science & Engineering, R. Reports: A Review Journal,2005(1/2):III-0.
[11] 付瑞东,栾国红,董春林,何淼.酸性盐雾中7075铝合金搅拌摩擦焊接头的腐蚀行为[J].腐蚀科学与防护技术,2009(06):580-585.
[12] Buchheit RG.;Hlava PF.;Mckenzie B.;Zender GL.;Grant RP. .LOCAL DISSOLUTION PHENOMENA ASSOCIATED WITH S PHASE (AL2CUMG) PARTICLES IN ALUMINUM ALLOY 2024-T3[J].Journal of the Electrochemical Society,1997(8):2621-2628.
[13] 程英亮,张昭,曹发和,李劲风,张鉴清,王建明,曹楚南.Corrosion of LY12 aluminum alloy in sodium chloride solution[J].中国有色金属学会会刊(英文版),2003(03):617-621.
[14] 刘志义,李云涛,刘延斌,夏卿坤.Al-Cu-Mg-Ag合金析出相的研究进展[J].中国有色金属学报,2007(12):1905-1915.
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