欢迎登录材料期刊网

材料期刊网

高级检索

在自制的公斤级高温流化床中研究了CO还原1~3 mm矿粉的还原行为.随着时间的增加,样品的还原率增加,气体利用率却在下降,说明还原前期反应速度快,后期反应慢;温度越高,样品的还原率越大,气体的利用率越高,但随着还原时间的增加,差距在逐步缩小.当还原温度为850 ℃时,前20 min的还原率为80%,气体利用率为8%左右,这说明高温下,CO还原1~3 mm铁矿粉的反应速度是很快的.温度越高,表观反应速率常数越大,而且增加的幅度也越来越大;随着气速的增加,铁矿粉的还原率增加,并且几乎成线性关系,表明高温下,使用CO气体作为还原剂时,可以允许更高的气速,从而可以提高设备的生产效率.随着料层高度的增加,金属化率与还原率不断下降,然而气体利用率却在不断升高.试验中CO还原1~3 mm铁矿粉时的表观活化能为59.11 kJ/mol.

参考文献

[1] R. J. Fruehan;Y. Li;L. Brabie .Final stage of reduction of iron ores by hydrogen[J].Scandinavian Journal of Metallurgy,2005(3):205-212.
[2] El-geassy A A;Nasr M I .Influence of original structure on the kinetics and mechanisms of carbon monoxide reduction of hematite compacts[J].ISIJ International,1990,30(06):417-425.
[3] Sujoy K;Ahindra ghosh .Kinetics of gaseous reduction of iron ore fines[J].ISIJ International,1993,33(11):1168-1173.
[4] Pourghahramani P;Forssberg E .Reduction kinetics of mechanically activated hematite concentrate with hydrogen gas using nonisothermal methods[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2007(2):69-77.
[5] Pineau A;Kanari N;Gaballah I .Kinetics of reduction of iron oxides by H-2 - Part I: Low temperature reduction of hematite[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2006(1):89-100.
[6] Unal A;Bradshaw A V .Rate processes and structural changes in gaseous reduction of hematite particles to magnetite[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1983,14B(12):743-752.
[7] Farren M;Matthew S P;Hayes P C .Reduction of solid wustite in H2/H2O/CO/CO2 gas mixtures[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1990,21B(02):135-139.
[8] R.A.D. Rodriguez;A.N. Conejo;E.B. Bedolla .Kinetics of Reduction of Fe_2O_3 Particles with H_2-CO Mixtures at Low Temperatures[J].Iron & Steelmaker,2003(1):25-33.
[9] 郭培民,赵沛,张殿伟.低温下碳还原氧化铁的催化机理研究[J].钢铁钒钛,2006(04):1-5.
[10] 赵沛,郭培民.纳米冶金技术的研究及前景[C].2005中国钢铁年会论文集,2005:677-681.
[11] 赵沛,郭培民.利用粉体纳米晶化促进低温冶金反应的研究[J].钢铁,2005(06):6-9.
[12] 曹朝真,郭培民,赵沛,庞建明.流化床低温氢冶金技术分析[J].钢铁钒钛,2008(04):1-6.
[13] 郭培民,张殿伟,赵沛.氧化铁还原率及金属化率的测量新方法[J].光谱学与光谱分析,2007(04):816-818.
[14] 华一新.冶金过程动力学导论[M].北京:冶金工业出版社,2004
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%