The deformation behaviours of Ni_3Al alloys with various chemical compositions and subjected to different heat treatments were in situ observed under SEM. Moreover,in situ observations of slip trace were supplemented by the direct observation of dislocation arrangements under TEM.In B-doped Ni_3Al alloys it is shown that close to the grain boundary there exists a thin slip transition region,within which slip lines are reoriented or other slip systems are operated to produce a local strain accommodation and to relax the stress concentration at grain bound- aries.Boron seems to lower the stress for dislocation generation from the grain boundaries or to ease the cross-slip close to the boundaries,and also to increase the number of dislocation sources.However,B-enhenced ductility is seriously affected by stoichiometry,the addition of a tertiary alloy element and heat treatment,etc..
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