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Phase equilibria at Fe-Mn side of isothermal section at 1000 and 1100℃ in Fe-Mn- Al system have been determined using the diffusion couple technique and metallography. A three-phase,α+γ+β,region was found at 1000℃.The method of solid/gas diffusion couple used to determine equilibrium phase composition is believed to be feasible for the system containing volatile component.

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