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为开发新型缓蚀剂,拓展O,O’-二烃基二硫代磷酸盐的应用领域,合成了O,O’-二苯基二硫代磷酸-N,N-二乙铵(DEDBDP),采用失重试验和电化学方法研究了DEDBDP在HCl介质中对Q235钢的缓蚀性能,结果表明:DEDBDP是一种优良缓蚀剂,(25±1)℃,5%HCl溶液中,DEDBDP浓度为120mg/L时,缓蚀率达85.23%;DEDBDP属阳阴极混合型缓蚀剂,适用于低温、较高酸度环境,具有持久的缓蚀性能;DEDBDP在QZ35钢表面吸附符合Langmuir吸附等温式,为自发的物理和化学吸附。

参考文献

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