Electrochemical Formation of Polypyrrole-carboxymethylcellulose Conducting Polymer Composite Films

材料科学技术（英文）, 2005, 21(5): 661-665.

^1, , ^2, , ^3, , ^4,

1.Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia

2.Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia

3.Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia

4.Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia

基金项目: The financial support for this work under the Intensified Research in Priority Areas(IRPA-8 fund , 09-02-0261-EA001) Ministry of Science and Technology, Malaysia, is acknowledged

Electrochemical Formation of Polypyrrole-carboxymethylcellulose Conducting Polymer Composite Films

Keywords： Conducting polymer

The electrochemical preparation of polypyrrole-carboxymethylcellulose (PPY-CMC) conducting polymer composite films on indium tin oxide (ITO) glass electrode from an aqueous solution containing pyrrole monomer, ptoluenesulfonate electrolyte and carboxymethylcellulose insulating polymer is reported. The characterization by Fourier transform infrared spectroscopy (FT-IR) shows that carboxymethylcellulose (CMC) has been successfully incorporated into polypyrrole structure forming PPY-CMC polymer composite films. The conductivity of the prepared composite films was found to increase with increaseing CMC concentration in pyrrole solution. The optical microscopic results show the influence of CMC concentration in the pyrrole solution over the morphological changes of the prepared films. The dynamic mechanical analysis (DMA) on the prepared PPY-CMC film reveals the higher plastic property of the PPY-CMC composite film.

参考文献

[1]	P Novak;K Muller;K S V Santhanam;O Haas .[J].Chemical Reviews,1997,97:207.
[2]	M Nicolas;B Fabre;J Simonet.[J].Journal of Electroanalytical Chemistry,2001:5091.
[3]	R S Potember;R C Hoffman;H S Hu;J E Cocchiaro,C A Vi s,R A Murphy,T O Poehler .[J].POLYMER JOURNAL,1987,28:574.
[4]	O Niwa;T Tamamura .[J].Journal of the Chemical Society,Chemical Communications,1984,470:817.
[5]	T F Otero;J M Sansinena .[J].Journal of Electroanalytical Chemistry,1996,412:109.
[6]	H L Wang;L Toppare;J E Fernez .[J].MACROMOLECULES,1990,23:1053.
[7]	J C Lacroix;A F Diaz .[J].Makromolekulare Chemie,Macromolecular Symposia,1987,8:17.
[8]	M Bardet;M Guinaudeu;C Bourgeoisat;H Cherin .[J].Synthetic Metals,1991,359:41.
[9]	J O Iroh;K Levine .[J].European Polymer Journal,2002,38:1547.
[10]	R Gangopadhyay;A De;Actuators B .[J].Sensors,2001,77:326.
[11]	J Y Ouyang;Y F Li .[J].Polymer Journal,1997,38:1971.
[12]	J Y Ouyang;Y F Li .[J].Polymer Journal,1997,38:3997.
[13]	Y F Li;J Y Ouyang .[J].Synthetic Metals,2000,113:23.
[14]	T F Otero;P Herrasti;P Ocó;C R Alves .[J].Electrochimica Acta,1998,43:1089.
[15]	C R Alves;P Herrasti;P Ocó;L A Avaca,T F Otero .[J].Polymer Journal,2001,33:255.
[16]	Y F Li .[J].Journal of Electroanalytical Chemistry,1997,433:181.
[17]	Y F Li;R Y Qian .[J].Electrochimica Acta,2000,45:1727.
[18]	M Omastova;M Trchova;J Kovarova;J Stejskal .[J].Synthetic Metals,2003,138:447.

上一张下一张

计量

下载量()
访问量()

作者相关

在本站搜索
在百度学术搜索
在万方数据库搜索
在CNKI搜索

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Electrochemical Formation of Polypyrrole-carboxymethylcellulose Conducting Polymer Composite Films

参考文献