功能材料, 2012, 43(5): 590-594.
掺钽TiO2薄膜的生物活性研究
翟瑞 1, , 邵红红 2, , 丁红燕 3, , 于春杭 钛锆转化膜层,利用正交试验确定了组分为六氟钛酸、六氟锆酸、含锰成膜剂和有机酸的6063铝合金转化处理液的较佳配方,并分析了转化膜的表面形貌、成分及耐蚀性能.分析结果表明:生成的转化膜为淡黄色,且均匀、连续;转化膜中含有钛、锆元素,其腐蚀电位和腐蚀电流密度比裸6063铝合金明显降低,说明钛锆转化膜可以更好地抑制铝合金的阴极反应,从而更有效地提高铝合金的耐蚀性能.","authors":[{"authorName":"刘宁华","id":"13789af8-e71d-46d2-bcc7-af1ed402ddcd","originalAuthorName":"刘宁华"},{"authorName":"李文芳","id":"e27ee54f-5183-485d-83e6-38574f7771fe","originalAuthorName":"李文芳"},{"authorName":"杜军","id":"a63db902-e36f-45ab-884a-c7dcc7c55f08","originalAuthorName":"杜军"}],"doi":"10.3969/j.issn.1001-3660.2010.05.014","fpage":"45","id":"aec2cd41-3f2a-4287-a0ae-5be42a8b5541","issue":"5","journal":{"abbrevTitle":"BMJS","coverImgSrc":"journal/img/cover/BMJS.jpg","id":"3","issnPpub":"1001-3660","publisherId":"BMJS","title":"表面技术 "},"keywords":[{"id":"c679394f-1489-4e72-bc7e-f2bf126d79bb","keyword":"铝合金","originalKeyword":"铝合金"},{"id":"d615f630-b163-4b3d-aa5d-30bf8f9f390a","keyword":"钛锆","originalKeyword":"钛锆"},{"id":"68be2911-4c48-4714-a8ed-df88df7a4255","keyword":"转化膜","originalKeyword":"转化膜"},{"id":"2f167639-4b30-45f8-b97b-db030cf7889d","keyword":"耐蚀性","originalKeyword":"耐蚀性"}],"language":"zh","publisherId":"bmjs201005014","title":"6063铝合金着色钛锆转化膜结构和耐蚀性能的研究","volume":"39","year":"2010"},{"abstractinfo":"近年来,新型钛基无镍合金以其良好的生物相容性、耐腐蚀性、低弹性模量、高相变温度等特性成为了形状记忆合金领域的研究重点.采用X射线衍射(XRD)、金相光学显微镜(OM)、透射电镜(TEM)、差示扫描量热分析(DSC)、压缩应力-应变实验等方法系统研究了TixZr100-x(x=20,30,50,70,80)合金的微观组织结构、相变特性、力学性能及形状记忆效应.结果表明:二元钛锆合金是一种典型的高温形状记忆合金,室温下为具有孪晶结构的单一hcp-α'马氏体相,晶格常数和晶胞体积都会随Zr原子含量增加而增大;合金具有从△母相到hcp-α'马氏体的可逆相变,相变温度随Zr原子含量增加先降低后增大,在Zr含量50％附近,马氏体相变开始温度最低,约为520 ℃;合金的屈服强度随Zr原子含量增加而增大,在Zr含量50％附近达到最大值(955 MPa),然后随Zr含量增加而下降;不同成分合金均具有形状记忆效应,其中Ti70 Zr30合金的记忆效应最大,为1.7％.","authors":[{"authorName":"李岩","id":"18dea6cc-91e6-4ce7-b8e9-196e13f96909","originalAuthorName":"李岩"},{"authorName":"姚礼","id":"84cb9285-7451-4cf8-a4a2-1ba6b916969e","originalAuthorName":"姚礼"},{"authorName":"崔晓龙","id":"99c0a884-6428-4c2a-a99c-c0da51c387a8","originalAuthorName":"崔晓龙"},{"authorName":"崔琰","id":"ce6c6f28-893b-43ea-8aa7-27be57b48901","originalAuthorName":"崔琰"}],"doi":"10.13373/j.cnki.cjrm.2015.08.001","fpage":"673","id":"024d7df9-9a6a-43e2-906f-e0eb099a1803","issue":"8","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"4c3315e0-7dab-4e15-b127-c202626708a0","keyword":"形状记忆合金","originalKeyword":"形状记忆合金"},{"id":"f5239c08-740b-465f-8db9-30987466cf10","keyword":"钛锆","originalKeyword":"钛锆"},{"id":"2bd9f98d-237c-4773-8bc2-57836b6e16cd","keyword":"马氏体相变","originalKeyword":"马氏体相变"},{"id":"99ee4b1f-faed-4b4e-865e-d3ac5f214f42","keyword":"微观结构","originalKeyword":"微观结构"}],"language":"zh","publisherId":"xyjs201508001","title":"二元Ti-Zr合金微观结构和形状记忆效应","volume":"39","year":"2015"},{"abstractinfo":"纳米钛-锆二元合金为固溶体合金,平均晶粒度为6～7nm,晶格类型为面心立方晶格(fcc),相对于钛和锆元素的密排六方晶格(hcp)结构稳定性更高.综合评述了采用机械合金化技术制备纳米钛-锆合金在国内外所取得的主要研究成果,并展望了其发展方向.","authors":[{"authorName":"李成清","id":"680fa79a-8925-4d77-8879-33b59744de71","originalAuthorName":"李成清"},{"authorName":"王树林","id":"536d29dc-e1df-477f-93a4-a6900649cca6","originalAuthorName":"王树林"}],"doi":"","fpage":"9","id":"13a7385b-e9dc-42ef-8ecc-e6e3b7137b77","issue":"z2","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"ebe9093a-62ff-4c9b-bf4e-868cf375070c","keyword":"纳米晶","originalKeyword":"纳米晶"},{"id":"f3d6a455-200a-46ff-92c5-ef3d795080f6","keyword":"钛-锆合金","originalKeyword":"钛-锆合金"},{"id":"6359a8f4-3c9f-4f75-a542-ccd1cb7ebb28","keyword":"机械合金化","originalKeyword":"机械合金化"}],"language":"zh","publisherId":"cldb2009z2003","title":"纳米钛-锆合金制备技术的研究进展","volume":"23","year":"2009"},{"abstractinfo":"研究了锆、钛砂矿的矿石工艺矿物学特征,根据矿石性质,确定了独居石选别工艺流程,并采用一次一因素析因试验、正交试验及工业试验进行了Φ576干式强磁场双盘磁选机、DSG-6高压双辊电选机和6-S摇床的最佳操作条件,获得了品位为(REO+ThO2)64.78%、回收率为80.56%的独居石精矿.","authors":[{"authorName":"王占岐","id":"de09e017-21bc-45b6-bd12-811a57142830","originalAuthorName":"王占岐"},{"authorName":"朱明","id":"93ae7e65-acbb-477a-b784-23458b789279","originalAuthorName":"朱明"}],"doi":"10.3969/j.issn.0258-7076.1999.04.008","fpage":"269","id":"638a367c-f58e-4132-8831-12f883157cc4","issue":"4","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"a6d95142-538a-4d02-b7c0-c3fc81bdd521","keyword":"独居石","originalKeyword":"独居石"},{"id":"5801ad82-0db9-4312-b5ef-f3c56d05af3b","keyword":"联合工艺流程","originalKeyword":"联合工艺流程"},{"id":"d7a4e761-f20e-4dcf-882d-edcca0c0717a","keyword":"试验研究","originalKeyword":"试验研究"},{"id":"4d236dd7-2d17-4e8f-830f-2b4196618f02","keyword":"工业试验","originalKeyword":"工业试验"}],"language":"zh","publisherId":"xyjs199904008","title":"锆钛砂矿中稀土的综合回收研究","volume":"23","year":"1999"},{"abstractinfo":"研究了溶胶-凝胶浸渍阳极氧化三氧化二铝(AAO)模板法制备Pb(zr<0.52>Ti0.48)O3(PZT)一维纳米结构的工艺方法.试验结果表明,以硝酸氧锆、醋酸铅、钛酸丁酯(按0.52∶1∶0.48的摩尔配比)为原料,以乙二醇为溶剂,可获得稳定的PZT溶胶,通过反复滴加浸渍氧化铝模扳,最终经650℃晶化处理和腐蚀AAO后得到PZT纳米管.样品表征结果说明,制得的PZT纳米管为钙钛矿相,表面结构完整、孔径均一、排列均匀整齐,长50μm、管径300 nm、壁厚40 nm.","authors":[{"authorName":"李晓鹏","id":"314df5b2-2bf2-46c1-aa33-1a2fbcf3ea06","originalAuthorName":"李晓鹏"},{"authorName":"王文","id":"d62b608c-e541-4b81-8fff-e1c73bf3fc59","originalAuthorName":"王文"},{"authorName":"冯金彪","id":"aa62eec2-685e-4972-8d1f-1a9f63d229f8","originalAuthorName":"冯金彪"},{"authorName":"贾德昌","id":"176fbdf1-166e-4229-8298-d3686a5ddfeb","originalAuthorName":"贾德昌"},{"authorName":"周玉","id":"96ac3bdb-fc8f-45c1-adb2-52a28ee8e1b4","originalAuthorName":"周玉"}],"doi":"","fpage":"2035","id":"c0c65b06-4568-4beb-9f79-07fb3d79f244","issue":"11","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"1ea28f46-2a05-44c6-ad82-42c03a19614c","keyword":"锖钛酸铅(PZT)","originalKeyword":"锖钛酸铅(PZT)"},{"id":"a9ce76c4-0fc5-45fc-9c6c-5dbc047448f6","keyword":"纳米管","originalKeyword":"纳米管"},{"id":"908be4f3-a733-41d9-9bf0-0afc9902f8b7","keyword":"AAO模板","originalKeyword":"AAO模板"},{"id":"16b6fc36-cad8-42bc-bff2-091470aff17d","keyword":"溶胶-凝胶法","originalKeyword":"溶胶-凝胶法"}],"language":"zh","publisherId":"xyjsclygc201011034","title":"锆钛酸铅纳米管制备工艺研究","volume":"39","year":"2010"},{"abstractinfo":"探讨了电感耦合等离子体原子发射光谱法(ICP-AES)测定锆及锆合金中钛的条件并建立了测定方法.采用盐酸、氢氟酸和硝酸溶解试样,选择波长339.4 nm(样品不含铌时)和338.3 nm(样品含铌时)的谱线作为钛分析线,在选定的仪器工作条件下对试液中钛进行测定.锡、铁、铬、镍对钛的测定无影响,基体元素锆和合金元素铌对钛测定的影响可以分别采用基体匹配和选择不同波长谱线作为钛分析线的方法克服.在选定的仪器工作条件下,对锆及锆合金试样中钛含量进行多次测定,结果与分光光度法(GB/T13747.1992)、直流电弧原子发射光谱法的测定结果基本一致,相对标准偏差(n=9)均小于15％.方法的精密度和准确度均满足科研生产的检测要求.","authors":[{"authorName":"李波","id":"11e2e4f3-2243-403a-9684-cb9ceaa8d4b3","originalAuthorName":"李波"},{"authorName":"禄妮","id":"ad86390f-fce7-4f32-8f20-1b21df9df052","originalAuthorName":"禄妮"}],"doi":"10.13228/j.issn.1000-7571.2014.01.011","fpage":"63","id":"d604bb6e-550d-4da8-8d65-ba96cdf10758","issue":"1","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析 "},"keywords":[{"id":"08736a16-35c7-405b-af9f-1573e523056c","keyword":"锆","originalKeyword":"锆"},{"id":"c55cad59-2311-41c1-ae83-c013d563cb24","keyword":"锆合金","originalKeyword":"锆合金"},{"id":"f5a5253f-e547-4ee6-bb4b-9bd486e4663a","keyword":"钛","originalKeyword":"钛"},{"id":"41e2babd-b78f-4d9d-9968-fb75452d2277","keyword":"电感耦合等离子体原子发射光谱法(ICP-AES)","originalKeyword":"电感耦合等离子体原子发射光谱法(ICP-AES)"}],"language":"zh","publisherId":"yjfx201401011","title":"电感耦合等离子体原子发射光谱法测定锆及锆合金中钛","volume":"34","year":"2014"},{"abstractinfo":" 在AA6061铝合金表面形成了钛锆膜。用SEM/EDX和XPS分析了钛锆膜的表面形貌及成分.采用电化学测试和中性盐雾测试研究了钛锆膜的耐蚀性能.结果表明，钛锆膜是由Zr-Ti-F-O-Al等元素组成的复合物；钛锆膜的耐蚀性能与基体相比有明显的提高，但不及六价铬酸盐膜；经72小时中性盐雾腐蚀，腐蚀面积小于10%.","authors":[{"authorName":"王双红刘常升单凤君齐国超","id":"32a50d2c-c380-4901-a742-1c8aff56cd9e","originalAuthorName":"王双红刘常升单凤君齐国超"}],"categoryName":"|","doi":"","fpage":"420","id":"ee42b0e4-879a-4e43-af2e-2bd08e22fa7b","issue":"6","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"f5196035-41c3-4d8c-80a1-6b121099fb06","keyword":"铝合金","originalKeyword":"铝合金"},{"id":"b2bade4b-cc1c-420b-b983-164ec97eac64","keyword":"Zr-Ti films","originalKeyword":"Zr-Ti films"},{"id":"a3181bec-b5c2-4731-8c39-080e593d8140","keyword":"passivation films","originalKeyword":"passivation films"},{"id":"14ac9aad-8fa4-4d4f-b590-8bb600c859b0","keyword":"corrosion resistance","originalKeyword":"corrosion resistance"}],"language":"zh","publisherId":"1002-6495_2008_6_13","title":"AA6061铝合金表面钛锆膜的结构及性能研究","volume":"20","year":"2008"},{"abstractinfo":"采用力学性能试验和组织观察的方法,研究了焊丝中添加钛和锆对2219铝铜合金惰性气体保护焊焊接接头显微组织和性能的影响.结果表明:钛和锆的组织细化作用是相容的,增加焊丝中钛和锆的含量,可促使焊缝中的粗大、方向性很强的柱状晶转变为细小的等轴晶;钛和锆同时改善了沿晶界和枝晶间分布的α(Al)-CuAl2共晶分布形态,使其均匀分布;钛和锆可显著提高焊接接头的硬度、抗拉强度和伸长率.","authors":[{"authorName":"杨成刚","id":"3cff0685-50c9-4385-b22e-c7f2e29abeb3","originalAuthorName":"杨成刚"},{"authorName":"吴辉明","id":"56028340-d8e4-4e60-95a9-19542188610d","originalAuthorName":"吴辉明"},{"authorName":"陈玉华","id":"889a98b9-dd8f-443d-a899-185ab873d204","originalAuthorName":"陈玉华"},{"authorName":"钱百年","id":"a01a7c17-228b-4cba-802c-3ae63af5b408","originalAuthorName":"钱百年"}],"doi":"","fpage":"24","id":"f99db759-dfbc-4a4d-8467-ec0234079536","issue":"3","journal":{"abbrevTitle":"JXGCCL","coverImgSrc":"journal/img/cover/JXGCCL.jpg","id":"45","issnPpub":"1000-3738","publisherId":"JXGCCL","title":"机械工程材料"},"keywords":[{"id":"ba18f62d-7311-49e7-a725-07772b7c7134","keyword":"钛","originalKeyword":"钛"},{"id":"fbb3de84-8efc-4e3e-9c95-af26de8cfed5","keyword":"锆","originalKeyword":"锆"},{"id":"bd8581a0-9be8-42f6-8804-7d9acfb15598","keyword":"2219铝铜合金","originalKeyword":"2219铝铜合金"},{"id":"32f6b5c6-fb03-40cd-9b4b-fc450878eb48","keyword":"焊接接头","originalKeyword":"焊接接头"}],"language":"zh","publisherId":"jxgccl200903007","title":"钛和锆对2219铝铜合金焊接接头组织和性能的影响","volume":"33","year":"2009"},{"abstractinfo":"在AA6061铝合金表面形成了钛锆膜.用SEM/EDX和XPS分析了钛锆膜的表面形貌及成分.采用电化学测试和中性盐雾测试研究了钛锆膜的耐蚀性能.结果表明,钛锆膜是由Zn-Ti-F-O-Al等元素组成的复合物;钛锆膜的耐蚀性能与基体相比有明显的提高,但不及六价铬酸盐膜;经72小时中性盐雾腐蚀,腐蚀面积小于10%.","authors":[{"authorName":"王双红","id":"7f3a0c3f-9a19-44c3-a845-3c25ac011f12","originalAuthorName":"王双红"},{"authorName":"刘常升","id":"88b66d9f-4af1-49ce-8f7c-7a3c2c36c719","originalAuthorName":"刘常升"},{"authorName":"单凤君","id":"e980a125-6402-4f57-af49-0ecb77ed4829","originalAuthorName":"单凤君"},{"authorName":"齐国超","id":"d66153fa-d2d5-4f9b-b710-74f709f1395e","originalAuthorName":"齐国超"}],"doi":"10.3969/j.issn.1002-6495.2008.06.008","fpage":"420","id":"989951ff-8644-4df1-a6e3-2c85177cc6b4","issue":"6","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"cde608e0-f221-44e7-8625-53a0f30d34c2","keyword":"铝合金","originalKeyword":"铝合金"},{"id":"4e477f3c-256e-472e-83bf-714906b30076","keyword":"钛锆膜","originalKeyword":"钛锆膜"},{"id":"9b6611b4-6420-4c6d-9022-32aeb985d2f6","keyword":"钝化膜","originalKeyword":"钝化膜"},{"id":"9ad3cceb-0612-4d5d-8771-2ff9d96f0fb8","keyword":"防腐蚀","originalKeyword":"防腐蚀"}],"language":"zh","publisherId":"fskxyfhjs200806008","title":"AA6061铝合金表面钛锆膜的结构及性能研究","volume":"20","year":"2008"},{"abstractinfo":"采用机械合金化技术制备纳米晶材料,操作简单,生产效率高.纳米钛-锆合金为固溶体,平均晶粒度为6～7nm,晶格类型为面心立方(fcc),这种晶型相对于钛和锆元素的密排六方晶格(hcp)稳定性更高.综合评述了在纳米钛-锆合金的机械合金化方面国内外所取得的主要研究成果,并对其发展方向作了展望.","authors":[{"authorName":"李成清","id":"45dc2fd3-1fda-4f9f-8de3-87fb7ec5cc37","originalAuthorName":"李成清"},{"authorName":"王树林","id":"a370313a-13cd-4510-8217-744d49e751b6","originalAuthorName":"王树林"}],"doi":"","fpage":"67","id":"062f12b3-9f1b-4069-b012-aa1356b453e9","issue":"7","journal":{"abbrevTitle":"ZGCLJZ","coverImgSrc":"journal/img/cover/中国材料进展.jpg","id":"80","issnPpub":"1674-3962","publisherId":"ZGCLJZ","title":"中国材料进展"},"keywords":[{"id":"7ad9f818-10b1-4244-9bc6-bc2d647026b5","keyword":"机械合金化","originalKeyword":"机械合金化"},{"id":"cae1e2c4-6cc5-4105-9ca8-a746d3e8e11a","keyword":"纳米晶","originalKeyword":"纳米晶"},{"id":"b7a0c3a2-ecf2-4240-95d0-df13891ebd2b","keyword":"钛-锆合金","originalKeyword":"钛-锆合金"}],"language":"zh","publisherId":"zgcljz200907009","title":"机械合金化制备纳米钛-锆合金的研究进展","volume":"28","year":"2009"}],"totalpage":1195,"totalrecord":11946}