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综述了自1988年以来中国科学院高温合金和金属间化合物研究组(郭建亭研究组)在高温结构金属间化合物NiAl及其合金、Ni3Al及其合金、FeAl和Fe3Al及其合金、TiAl合金以及金属间化合物环境脆性方面的主要研究成果:NiAl合金超塑性的发现及其机理研究;稀土元素改善NiAl合金的室温塑性和高温抗氧化性能;NiAl合金的韧脆转变行为及其机理;纳米晶NiAl合金及其复合材料的强韧化;内生颗粒增强NiAl基复合材料及强韧化机制;NiAl合金良好的耐高温摩擦磨损性能及自润滑机理的发现;NiAl中合金元素的作用与JJ-3合金的发展;在国际上首先发现适量Zr可韧化无硼Ni3Al合金;为使Ni3Al强韧化硼含量应加至溶解度附近;FeAl合金反常屈服峰的发现及其机理研究;微量Mg可明显改善FeAl和Fe3Al合金的室温塑性;TiAl-W-Si合金的组织、相转变和界面精细结构;金属间化合物的环境脆性实质是氢致脆性;在国际上首先用第一原理方法(DVM)研究了L12型CO3Ti的环境脆性.

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